• Title/Summary/Keyword: aligned structure

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Effect of length of alkyl chain consisting of fluorine and carbon in self-assembled monolayers

  • Park, Sang-Geon;Lee, Won Jae;Lee, Won Jae;Kim, Tae Wan
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.361-368
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    • 2018
  • We investigated the interfacial properties of fluorocarbon self-assembled monolayers (FC-SAMs) with different alkyl chain lengths. It was found that the substrate characteristics were changed rapidly with the fabrication time and temperature of the SAM. FC-3SAM, which has the shortest alkyl chain in this study, showed a contact angle of $54.1^{\circ}$ when it was fabricated in an electric oven at $60^{\circ}C$ for the first minute. The FC-3SAM showed a contact angle of up to $76.9^{\circ}$ when it was fabricated in an electric oven at the same temperature condition for 180 minutes. FC-10SAM, which has the longest alkyl chain in this study, showed a contact angle of $64.7^{\circ}$ when it was fabricated at a temperature condition of $60^{\circ}C$ for 1 minute, and a contact angle of $98.7^{\circ}C$ at a temperature condition of $60^{\circ}C$ for 180 minutes. It was found that the FC-10SAM shows an increased contact angle and hydrophobic properties due to a well-aligned molecular structure resulting from a strong van der Waals force. In contrast, the FC-3SAM shows a small contact angle due to the intermolecular disorder resulting from a weak van der Waals force. The average roughness of FC-SAMs was investigated using AFM. The surface roughness of FC-SAMs, which verifies the results of contact angle, was confirmed. At a fabrication time of 120 minutes, the FC-10SAM showed an improvement in average roughness by 62% compared to that of FC-3SAM due to its good alignment.

Eyes and Vision of the Bumblebee: a Brief Review on how Bumblebees Detect and Perceive Flowers

  • Meyer-Rochow, V.B.
    • Journal of Apiculture
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    • v.34 no.2
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    • pp.107-115
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    • 2019
  • Bumblebees have apposition compound eyes (one on either side of the head) of about 6,000 ommatidia and three small single-lens ocelli on the frons of their head capsule. The surface of the eye is smooth and interommatidial hairs, as in the honeybee, are not developed. Each ommatidium (approx. 26 ㎛ in diameter) is capped by a hexagonal facet and contains in its centre a 3 ㎛ wide, columnar light-perceiving structure known as the rhabdom. Rhabdoms consist of thousands of regularly aligned, fingerlike microvilli, which in their membranes contain the photopigment molecules. Axons from each ommatidium transmit the information of their photic environment to the visual centres of the brain, where behavioural reactions may be initiated. Since bumblebee eyes possess three classes of spectrally different sensitivity peaks in a ratio of 1:1:6 (UV= 353 nm, blue= 430 nm and green=548 nm) per ommatidium, they use colour vision to find and select flower types that yield pollen and nectar. Ommatidial acceptance angles of at least 3° are used by the bumblebees to discriminate between different flower shapes and sizes, but their ability to detect polarized light appears to be used only for navigational purposes. A flicker fusion frequency of around 110Hz helps the fast flying bumblebee to avoid obstacles. The small ocelli are strongly sensitive to ultraviolet radiation and green wavelengths and appear to act as sensors for light levels akin to a photometer. Unlike the bumblebee's compound eyes, the ocelli would, however, be incapable of forming a useful image.

Effect of Freeze Drying Condition of WO3/Tert-Butyl Alcohol Slurry on the Microstructural Characteristics of Porous Body (WO3/tert-butyl alcohol 슬러리의 동결건조 조건이 다공체의 미세구조 특성에 미치는 영향)

  • Lee, Eui Seon;Heo, Youn Ji;Suk, Myung-Jin;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.28 no.4
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    • pp.331-335
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    • 2021
  • The effects of drying temperature on the microstructure of porous W fabricated by the freeze-casting process of tert-butyl alcohol slurry with WO3 powder was investigated. Green bodies were hydrogen-reduced at 800℃ for 1 h and sintered at 1000℃ for 6 h. X-ray diffraction analysis revealed that WO3 powders were completely converted to W without any reaction phases by hydrogen reduction. The sintered body showed pores aligned in the direction of tert-butyl alcohol growth, and the porosity and pore size decreased as the amount of WO3 increased from 5 to 10vol%. As the drying temperature of the frozen body increased from -25℃ to -10℃, the pore size and thickness of the struts increased. The change in microstructural characteristics based on the amount of powder added and the drying temperature was explained by the growth behavior of the freezing agent and the degree of rearrangement of the solid powder during the solidification of the slurry.

Physical modeling of dust polarization spectrum by RAT alignment and disruption

  • Lee, Hyeseung;Hoang, Thiem
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.38.1-38.1
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    • 2021
  • Dust polarization depends on the physical and mechanical properties of dust, as well as the properties of local environments. To understand how dust polarization varies with grain mechanical properties and the local environment, in this paper, we model the wavelength-dependence polarization of starlight and polarized dust emission by aligned grains by simultaneously taking into account grain alignment and rotational disruption by radiative torques (RATs). We explore a wide range of the local radiation field and grain mechanical properties characterized by tensile strength. We find that the maximum polarization and the peak wavelength shift to shorter wavelengths as the radiation strength U increases due to the enhanced alignment of small grains. Grain rotational disruption by RATs tends to decrease the optical-near infrared polarization but increases the ultraviolet polarization of starlight due to the conversion of large grains into smaller ones. In particular, we find that the submillimeter (submm) polarization degree at 850㎛(P850) does not increase monotonically with the radiation strength or grain temperature (Td), but it depends on the tensile strength of grain materials. Our physical model of dust polarization can be tested with observations toward star-forming regions or molecular clouds irradiated by a nearby star, which have higher radiation intensity than the average interstellar radiation field. Finally, we compare our predictions of the P850-Td relationship with Planck data and find that the observed decrease of P850 with Td can be explained when grain disruption by RATs is accounted for, suggesting that interstellar grains unlikely to have a compact structure but perhaps a composite one. The variation of the submm polarization with U (or Td)can provide a valuable constraint on the internal structures of cosmic dust

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Effect of internal structures on the accuracy of 3D printed full-arch dentition preparation models in different printing systems

  • Teng Ma;Tiwu Peng;Yang Lin;Mindi Zhang;Guanghui Ren
    • The Journal of Advanced Prosthodontics
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    • v.15 no.3
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    • pp.145-154
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    • 2023
  • PURPOSE. The objective of this study was to investigate how internal structures influence the overall and marginal accuracy of full arch preparations fabricated through additive manufacturing in different printing systems. MATERIALS AND METHODS. A full-arch preparation digital model was set up with three internal designs, including solid, hollow, and grid. These were printed using three different resin printers with nine models in each group. After scanning, each data was imported into the 3D data processing software together with the master cast, aligned and trimmed, and then put into the 3D data analysis software again to compare the overall and marginal deviation whose results are expressed using root mean square values and color maps. To evaluate the trueness of the resin model, the test data and reference data were compared, and the precision was evaluated by comparing the test data sets. Color maps were observed for qualitative analysis. Data were statistically analyzed by one-way analysis of variance and Bonferroni method was used for post hoc comparison (α = .05). RESULTS. The influence of different internal structures on the accuracy of 3D printed resin models varied significantly (P < .05). Solid and grid models showed better accuracy, while the hollow model exhibited poor accuracy. The color maps show that the resin models have a tendency to shrink inwards. CONCLUSION. The internal structure design influences the accuracy of the 3D printing model, and the effect varies in different printing systems. Irrespective of the kind of printing system, the printing accuracy of hollow model was observed to be worse than those of solid and grid models.

DEVELOPMENT OF LIGHTWEIGHT OPTICAL TELESCOPE KIT USING ALUMINUM PROFILE AND ISOGRID STRUCTURE

  • Park, Woojin;Lee, Sunwoo;Han, Jimin;Ahn, Hojae;Ji, Tae-Geun;Kim, Changgon;Kim, Dohoon;Lee, Sumin;Kim, Young-Jae;Kim, Geon-Hee;Kim, Junghyun;Kim, Ilhoon;Pak, Soojong
    • Journal of The Korean Astronomical Society
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    • v.55 no.1
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    • pp.11-22
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    • 2022
  • We introduce the Transformable Reflective Telescope (TRT) kit that applies an aluminum profile as a base plate for precise, stable, and lightweight optical system. It has been utilized for optical surface measurements, developing alignment and baffle systems, observing celestial objects, and various educational purposes through Research & Education projects. We upgraded the TRT kit using the aluminum profile and truss and isogrid structures for a high-end optical test device that can be used for prototyping of precision telescopes or satellite optical systems. Thanks to the substantial aluminum profile and lightweight design, mechanical deformation by self-weight is reduced to maximum 67.5 ㎛, which is an acceptable misalignment error compared to its tolerance limits. From the analysis results of non-linear vibration simulations, we have verified that the kit survives in harsh vibration environments. The primary mirror and secondary mirror modules are precisely aligned within 50 ㎛ positioning error using the high accuracy surface finished aluminum profile and optomechanical parts. The cross laser module helps to align the secondary mirror to fine-tune the optical system. The TRT kit with the precision aluminum mirror guarantees high quality optical performance of 5.53 ㎛ Full Width at Half Maximum (FWHM) at the field center.

Edge perturbation on electronic properties of boron nitride nanoribbons

  • K.L. Wong;K.W. Lai;M.W. Chuan;Y. Wong;A. Hamzah;S. Rusli;N.E. Alias;S. Mohamed Sultan;C.S. Lim;M.L.P. Tan
    • Advances in nano research
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    • v.15 no.5
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    • pp.385-399
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    • 2023
  • Hexagonal boron nitride (h-BN), commonly referred to as Boron Nitride Nanoribbons (BNNRs), is an electrical insulator characterized by high thermal stability and a wide bandgap semiconductor property. This study delves into the electronic properties of two BNNR configurations: Armchair BNNRs (ABNNRs) and Zigzag BNNRs (ZBNNRs). Utilizing the nearest-neighbour tight-binding approach and numerical methods, the electronic properties of BNNRs were simulated. A simplifying assumption, the Hamiltonian matrix is used to compute the electronic properties by considering the self-interaction energy of a unit cell and the interaction energy between the unit cells. The edge perturbation is applied to the selected atoms of ABNNRs and ZBNNRs to simulate the electronic properties changes. This simulation work is done by generating a custom script using numerical computational methods in MATLAB software. When benchmarked against a reference study, our results aligned closely in terms of band structure and bandgap energy for ABNNRs. However, variations were observed in the peak values of the continuous curves for the local density of states. This discrepancy can be attributed to the use of numerical methods in our study, in contrast to the semi-analytical approach adopted in the reference work.

IFC Data Schema Extension for Railway Track Facility Management

  • Zeru Liu;Wuhao Huang;Hejun Xu;Sining Li;Jung In Kim
    • International conference on construction engineering and project management
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    • 2024.07a
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    • pp.550-557
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    • 2024
  • Railway track facility management (FM) is an intricate and multifaceted discipline that necessitates precise data management and scheduling for ensuring the safety and efficiency of railway operations. Although the Industry Foundation Classes (IFC) version 4.3 has incorporated railway infrastructure into its data schema, it still falls short in catering to the specialized needs of track FM. This paper presents an exhaustive extension to the IFC schema, specifically designed to address the challenges and complexities inherent in railway track FM. A two-step approach was employed in the development of this extension. The initial phase involves the development of a Unified Modeling Language (UML)-based conceptual model, encapsulating four pivotal elements: "component" for track asset and condition identification, "action" for the related tasks during track FM, "resource" for required materials and equipment as well as involved actors, and "operation" for track operation information capturing. This conceptual model serves as an intricate blueprint, offering a comprehensive structure for various FM facets. Thus, the proposed IFC extension is developed and aligned consistently with the conceptual model, forming an integrated, interoperable data management framework that can be easily adapted into the openBIM environment. The efficacy and applicability of the proposed extension are substantiated through real-world case studies, thereby demonstrating its capability to significantly enhance data visualization, interoperability, and overall decision-making in railway track FM.

Lattice Preferred Orientation(LPO) and Seismic Anisotropy of Amphibole in Gapyeong Amphibolites (경기육괴 북부 가평 지역에 분포하는 각섬암 내부 각섬석의 격자선호방향(LPO)과 지진파 비등방성)

  • Kim, Junha;Jung, Haemyeong
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.259-272
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    • 2020
  • The seismic properties in the crust are affected by the lattice preferred orientation(LPO) of major minerals in the crust. Therefore, in order to understand the internal structure of the crust using seismic data, information on the LPO of the major constituent minerals and the seismic properties of major rocks in a specific region are needed. However, there is little research on the LPOs of minerals in the crust in Korea. In this study, we collected amphibolites from two outcrops in Wigokri, Gapyeong, located in the nothern portion of Gyeonggi Massif, and we measured the LPOs of major minerals of amphibolite, especially amphibole and plagioclase through EBSD analysis, and calculated seismic properties of amphibolite. Two types of LPOs of amphibole, which are defined as type I and type IV, were observed in the two outcrops of Gapyeong amphibolites, respectively. In the case of amphibolites with the type I LPO of amphibole, large seismic anisotropy of both P- and S-wave was observed, while in the amphibolites with the type IV LPO of amphibole, small seismic anisotropy was observed. This is consistent with previous experimental results. The polarization direction of the fast S-wave was aligned subparallel to the lineation regardless of the LPO types of amphibole. The seismic anisotropy observed in Gapyeong is expected to be helpful to interpret the structure and seismic data within the crust in Gyeonggi Massif.

Performances and Electrical Properties of Vertically Aligned Nanorod Perovskite Solar Cell

  • Kwon, Hyeok-Chan;Kim, Areum;Lee, Hongseuk;Lee, Eunsong;Ma, Sunihl;Lee, Yung;Moon, Jooho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.429-429
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    • 2016
  • Organolead halide perovskite have attracted much attention over the past three years as the third generation photovoltaic due to simple fabrication process via solution process and their great photovoltaic properties. Many structures such as mesoporous scaffold, planar heterojunction or 1-D TiO2 or ZnO nanorod array structures have been studied to enhance performances. And the photovoltaic performances and carrier transport properties were studied depending on the cell structures and shape of perovskite film. For example, the perovskite cell based on TiO2/ZnO nanorod electron transport materials showed higher electron mobility than the mesoporous structured semiconductor layer due to 1-D direct pathway for electron transport. However, the reason for enhanced performance was not fully understood whether either the shape of perovskite or the structure of TiO2/ZnO nanorod scaffold play a dominant role. In this regard, for a clear understanding of the shape/structure of perovskite layer, we applied anodized aluminum oxide material which is good candidate as the inactive scaffold that does not influence the charge transport. We fabricated vertical one dimensional (1-D) nanostructured methylammonium lead mixed halide perovskite (CH3NH3PbI3-xClx) solar cell by infiltrating perovskite in the pore of anodized aluminum oxide (AAO). AAO template, one of the common nanostructured materials with one dimensional pore and controllable pore diameters, was successfully fabricated by anodizing and widening of the thermally evaporated Al film on the compact TiO2 layer. Using AAO as a scaffold for perovskite, we obtained 1-D shaped perovskite absorber, and over 15% photo conversion efficiency was obtained. I-V measurement, photoluminescence, impedance, and time-limited current collection were performed to determine vertically arrayed 1-D perovskite solar cells shaped in comparison with planar heterojunction and mesoporous alumina structured solar cells. Our findings lead to reveal the influence of the shape of perovskite layer on photoelectrical properties.

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