• Journal of the Korean Geotechnical Society
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• v.29 no.5
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• pp.29-38
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• 2013

The G-class cement is commonly used in practice for geothermal well cementing in order to protect a steel casing that is designed to transport hot water/steam from deep subsurface to ground surface during operating a geothermal power plant. In order to maintain optimal performance of geothermal wells, physical properties of the cementing material should be satisfactory. In this paper, relevant factors (i.e., groutability, uniaxial compression strength, thermal conductivity and free fluid content) of the G-class cement were experimentally examined with consideration of various water-cement (w/c) ratios. Important findings through the experiments herein are as follows. (1) Groutability of the G-class cement increases by adding a small dose of retarder. (2) There would be a structural defect caused when the w/c ratio is kept higher in order to secure groutability. (3) Thermal conductivity of the G-class cement is small enough to prevent heat loss from hot steam or water to the outer ground formation during generating electricity. (4) The G-class cement does not form free water channel in cementing a geothermal well. (5) The Phenolphthalein indicator is applicable to the distinction of the G-class cement from the drilling mud.

• Journal of the Korean Chemical Society
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• v.62 no.4
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• pp.288-298
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• 2018

In this study, we surveyed pre- and post-perceptions of fourteen science teachers related to the atmosphere composition of molecules with different masses by the developed test. As a result of the test, the teachers were classified into two types of thoughts; One of them is considered the atmosphere to be a homogeneous solution, and the other is a thought that the composition ratio of the atmosphere was not homogeneous considering the different weights of particles. The two types were reclassified into three categories; one of them is considering large gravity effect, another is considering small gravity effect, and the other is considering medium scale gravity effect. Total six types of thoughts were found from the pre-test. After introducing crosscutting concepts which are related to the composition of atmosphere. The teachers discussed the phenomena with the molecular motion by weights of atoms and temperature, the homogeneity of the solution of air in chemistry domain. They also discussed with the relationship between mass and gravity and distance in physics domain. And the discussion included distribution of the atmosphere, convection phenomena, etc. After the discussion, the teachers changed their pre-conceptions to post-concoctions considering combined perspectives of gravity, mass, temperature, altitude etc. Through these changes, we are able to confirm the importance of crosscutting concepts covered in various disciplines. In the integrated science, we should help teachers to provide students with these types of thinking in order to form a coherent world-view and to carry out inquiry thinking as an intellectual tool.

• Journal of the Korea Institute of Building Construction
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• v.15 no.3
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• pp.265-271
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• 2015

This study is intended to produce a PC (Precast Concrete) member without a steam curing process in developing the high early strength concrete satisfying the condition of 10MPa in compressive strength at the age of 6 hours, and is intended to ensure economic feasibility by increasing the turnover rate of concrete form. Hence, high early strength cement with high $C_3S$ content and the hardening accelerator of powder type accelerating the hydration of $C_3S$ was used. And the properties of concrete were evaluated according to the hardening accelerator mixing ratio (0, 1.2, 1.6, 2.0). No big difference was found from the tests of both slump and air content. When 1.6 % or higher amounts of the hardening accelerator were mixed, the compressive strength of 10MPa was achieved at the age of 6 hours. From the test results of autogenous (drying) shrinkage and plastic shrinkage, it can be seen that there was a difference according to hydration reaction rate due to the addition of the hardening accelerator. However, it was shown that no problem arose with crack and durability. And it was shown that resistance to freezing-thawing, carbonation, and penetration were excellent.

• Journal of Navigation and Port Research
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• v.41 no.6
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• pp.451-466
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• 2017

Deep-sea fishing vessel No. 501 Oryong was fully flooded through its openings and sunk to the bottom of the sea due to the very rough sea weather on the way of evasion after a fishing operation in the Bearing Sea. As a result, many crew members died and/or were missing. In this study, a full-scale ship flooding sinking simulation was conducted, and the sinking process was analyzed for the precise and scientific investigation of the sinking accident using highly advanced Modeling & Simulation (M&S) system of Fluid-Structure Interaction (FSI) analysis technique. To objectively secure the weather and sea states during the sinking accident in the Bering Sea, time-based wind and wave simulation at the region of the sinking accident was carried out and analyzed, and the weather and sea states were realized by simulating the irregular strong wave and wind spectrums. Simulation scenarios were developed and full-scale ship and fluid (air & seawater) modeling was performed for the flooding sinking simulation, by investigating the hull form, structural arrangement & weight distribution, and exterior inflow openings and interior flooding paths through its drawings, and by estimating the main tank capacities and their loading status. It was confirmed that the flooding and sinking accident was slightly different from a general capsize and sinking accident according to the simple loss of stability.

• KIPS Transactions on Computer and Communication Systems
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• v.5 no.6
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• pp.135-142
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• 2016

We proposed the new method to estimate the blood pressure with the differential value of the digital arterial pulse waveform and BP relation equation. To get the digital arterial pulse waveform, we use the arterial pulse waveform measurement system that has digital air-pressure sensor device and smart phone. The acquired digital arterial pulse waveforms are classified as hypertension group, normal group, and hypotension group, and we can derive the average differential value between the highest point and lowest point of a single waveform of individuals along with the group. In this study, we found the functional correlation between the blood pressure and differential value as a form of BP relation equation through the regression process on the average of differential value and blood pressure value from a tonometer. The Experimental results show the BP relation equation can give easy blood pressure estimation method with a high accuracy. Although this estimation method has over 66 % error rate and does not give the high level of the accuracy for the diastolic compares to the commercial tonometer, the estimation results for the systolic show the high accuracy that has less than 10 % error rate.

• Journal of the Korea Institute of Building Construction
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• v.14 no.2
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• pp.156-162
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• 2014

This study aims to develop a rapidly hardening type of concrete to achieve the removal of form intensity (more than 10MPa) using the method of curing at room temperature in order to solve some economic environmental problems by omitting the steam curing process involved in producing PC (Precast Concrete). Therefore, this study evaluated a rapidly hardening cement containing a high amunt of C3S, which is very responsive in expressing early intensity, and a rapidly hardening type of concrete which uses some hardening accelerator to increase thehydration reaction of $C_3S$. The results of the experiment on concrete using some hardening accelerator are asfollows. In the slump flow experiment for identifying the liquidity and the air test, the desired values were met. The compression strength showed rapid expression response by 12 hours, and met the desired value within 6~9 hours. Its drying shrinkage value and Autogenous shrinkage value were measured as below ($-754.5{\times}10^{-6}$),and satisfied the requirements. In addition, in the Semi-Adiabatic Temperature Test, it was found that the concrete rose to its peak temperature within 24 hours and then its temperature dropped.

• Journal of Animal Environmental Science
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• v.18 no.sup
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• pp.73-80
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• 2012

Nitrogen included in animal manure can be used as organic fertilizer if it is treated properly but it may cause serious air and water pollution without proper management. Significant amount of nitrogen losses happen in the form of ammonia when the manure staying in animal house and storage facilities and being composted and applied to the field. In order to maximize the manure nitrogen utilization, it is important to understand the mechanisms of nitrogen loss during the diverse manure handling and treatment procedures. The plant available nitrogen portion of total nitrogen in excreted manure was evaluated based on animal type, animal manure collection system, manure treatment process, and application method. About 27% of nitrogen included in excreted pig manure could be plant available if it is applied to the filed after composting process. The plant available nitrogen portion varies from 29% (surface application) to 54% (solid injection) based on application method of digestated piggery slurry. Plant can use 18% of manure nitrogen if the composted cattle and poultry manure applied to the field using surface application method. Manure treatment and application methods need to be carefully selected to control and utilize the manure nitrogen properly.

• Bulletin of the Korean Chemical Society
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• v.14 no.4
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• pp.439-444
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• 1993

The aerobic oxidation of the Fe(II) complex of 1,4,8,11-tetraazacyclotetradecane, [Fe(cyclam)$(CH_3CN)_2](ClO_4)_2$, in MeCN in the presence of a few drops of $HClO_4$ leads to low spin Fe(III) species [Fe(cyclam)$(CH_3CN)_2](ClO_4)_3$. The Fe(III) cyclam complex is further oxidized in the air in the presence of a trace of water to produce the deep green binuclear bismacrocyclic Fe(II) complex $[Fe_2(C_{20}H_{36}N_8)(CH_3CN)_4](ClO_4)_4{\cdot}2CH_3CN$. The Fe(II) ions of the complex are six-coordinated and the bismacrocyclic ligand is extensively unsaturated. $[Fe_2(C_{20}H_{36}N_8)(CH_3CN)_4](ClO_4)_4{\cdot}2CH_3CN$ crystallizes in the monoclinic space group $P2_1/n$ with a= 13.099 (1) ${\AA}$, b= 10.930 (1) ${\AA}$, c= 17.859 (1) ${\AA}$, ${\beta}$= 95.315 $(7)^{\circ}$, and Z= 2. The structure was solved by heavy atom methods and refined anisotropically to R values of R= 0.0633 and $R_w$= 0.0702 for 1819 observed reflections with F > $4{\sigma}$ (F) measured with Mo K${\alpha}$ radiation on a CAD-4 diffractometer. The two macrocyclic units are coupled through the bridgehead carbons of ${\beta}$-diimitie moieties by a double bond. The double bonds in each macrocycle unit are localized. The average bond distances of $Fe(II)-N_{imine}$, $Fe(II)-N_{amine}$, and $Fe(II)-N_{MeCN}$ are 1.890 (5), 2.001 (5), and 1.925 (6) ${\AA}$, respectively. The complex is diamagnetic, containing two low spin Fe(II) ions in the molecule. The complex shows extremely intense charge transfer band in the near infrared at 868 nm with ${\varepsilon}$= 25,000 $M^{-1}cm^{-1}$. The complex shows a one-electron oxidation wave at +0.83 volts and two one-electron reduction waves at -0.43 and-0.72 volts vs. Ag/AgCl reference electrode. The complex reacts with carbon monoxide in $MeNO_2$ to form carbonyl adducts, whose $v_{CO}$ value (2010 $cm^{-1}$) indicates the ${\pi}$-accepting property of the present bismacrocyclic ligand.

• Korean Journal of Environmental Agriculture
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• v.40 no.4
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• pp.330-334
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• 2021

BACKGROUND: More recently, it has been shown that atmospheric ammonia (NH₃) plays a primary role in the formation of secondary particulate matter by reacting with the acidic species, e.g. SO₂, NOx, to form PM2.5 aerosols in the atmosphere. The Jeonbuk region is an area with high concentration of particulate matter. Due to environmental changes in the Saemangeum reclaimed land with an area of 219 km², it is necessary to evaluate the impact of the particulate matter and atmospheric ammonia in the Jeonbuk region. METHODS AND RESULTS: Atmospheric ammonia concentrations were measured from June 2020 to May 2021 using a passive sampler and CRDS analyzer. Seasonal and annual atmospheric ammonia concentration measured using passive sampler was significantly lower in Jangjado (background concentration), and the concentration ranged from 11.4 ㎍/m³ to 18.2 ㎍/m³. Atmospheric ammonia concentrations in Buan, Gimje, Gunsan, and Wanju regions did not show a significant difference, although there was a slight seasonal difference. The maximum atmospheric ammonia concentration measured using the CRDS analyzer installed in the IAMS near the Saemangeum reclaimed land was 51.5 ㎍/m³ in autumn, 48.0 ㎍/m³ in summer, 37.6 ㎍/m³ in winter, and 32.7 ㎍/m³ in spring. The minimum concentration was 4.9 ㎍/m³ in spring, 4.2 ㎍/m³ in summer, and 3.5 ㎍/m³ in autumn and winter. The annual average concentration was 14.6 ㎍/m³. CONCLUSION(S): Long term monitoring of atmospheric ammonia in agricultural areas is required to evaluate the formation of fine particulate matter and its impact on the environment. In addition, continuous technology development is needed to reduce ammonia emitted from farmland.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.47 no.3
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• pp.227-235
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• 2021

In this study, we have prepared pure planar-type ZnO and calamine powder containing both ZnO and Fe₂O₃ components as a raw material for cosmetics with UV and blue band blocking functions. The planar-type ZnO ceramic powder having a high aspect ratio in the range of 20:1 to 50:1 was synthesized by precipitation method in a zinc acetate and sodium citrate mixed solution with the electrolyte obtained by power generation with a zinc-air battery. The content of Fe₂O₃ in the artificial calamine ceramic powder could be increased by increasing the amount of iron chloride solution added, and in this case, some of the blue region of visible light and ultraviolet light were remarkably absorbed. When potassium acetate was added, the decomposition of the Zn(OH)₄^2- anion in the solution was promoted to facilitate the growth of ZnO crystal in the form of a barrier wall in the vertical direction on the (0001) plane, which could increase UV absorption by providing more opportunities. By controlling the amount of iron chloride solution and potassium acetate solution added, the composition and shape of the thin film plate-shaped artificial calamine ceramic powder can be optimized, and when applied to cosmetic formulations, the light transmittance of the blue region can be greatly reduced.