• Title/Summary/Keyword: air electrode

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Treatment of Nitrogen Oxides in Ambient Air using a Ion-Selective Electrode (대기중 질산화물의 이온 선택성 전극에 의한 처리)

  • 안형환;우인성;강안수;이영순;김윤선
    • Journal of the Korean Society of Safety
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    • v.5 no.2
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    • pp.40-49
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    • 1990
  • For the determination of polluant NOx in ambient air, nitrate ion-selective electrode(ISE) was made. To comparison of NOx in each method, the nitrate-ISE, NEBA, Orion electrode were used to determinee NOx in ambient air. In this work, the concentration of NOx in ambient air was average 0.06ppm. The results were good agreement with those obtained by each method within a relative error of 3%, Absorbing efficiency of nitrogen oxides in ambient air was good for Alkali solution. The determination of nitrogen oxides in ambient air using the Aliquat 336N-PVC membrane electrode was one of the useful method. The best characteristics of the Aliquat 336N-PVC me,mbrane electrode were obtained with the ion-exchanger concentration level of 6.5-9.1 percent by weight. The optimal membrane composition, was 9.09wt.% of ion-exchanger, 30.95wt.% of PVC, 60.6wt.% of plasticizer (DBP), and 0.5mm of thickness. Under the above condition, the electrode approached the Nernstian slope most closely, and the linear response ranges produced the best results.

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Fabrication of Electrochemical Sensor with Tunable Electrode Distance

  • Yi, Yu-Heon;Park, Je-Kyun
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.1
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    • pp.30-37
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    • 2005
  • We present an air bridge type electrode system with tunable electrode distance for detecting electroactive biomolecules. It is known that the narrower gap between electrode fingers, the higher sensitivity in IDA (interdigitated array) electrode. In previous researches on IDA electrode, narrower patterning required much precise and expensive equipment as the gap goes down to nanometer scale. In this paper, an improved method is suggested to replace nano gap pattering with downsizing electrode distance and showed that the patterning can be replaced by thickness control using metal deposition methods, such as electroplating or metal sputtering. The air bridge type electrode was completed by the following procedures: gold patterning for lower electrode, copper electroplating, gold deposition for upper electrode, photoresist patterning for gold film support, and copper etching for space formation. The thickness of copper electroplating is the distance between upper and lower electrodes. Because the growth rate of electroplating is $0.5{\mu}m\;min^{-1}$, the distance is tunable up to hundreds of nanometers. Completed electrodes on the same wafer had $5{\mu}m$ electrode distance. The gaps between fingers are 10, 20, 30, and $40{\mu}m$ and the widths of fingers are 10, 20, 30, 40, and $50{\mu}m$. The air bridge type electrode system showed better sensitivity than planar electrode.

Partial Discharge Characteristics of XLPE According to Electrode Shape and Void (전극형상 및 보이드에 따른 XLPE의 부분방전 특성)

  • Shin, Jong-Yeol;Kim, Guin-sik;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.1
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    • pp.50-57
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    • 2016
  • Transmission equipment is mainly used for the XLPE (cross-linked polyethylene) insulation cable for ultra high voltage power to minimize power loss. The experiment examined the partial discharge characteristics according to the insertion of the bar electrode and needle electrode into the XLPE specimen and the air voids. XLPE insulation cable manufactured by T. company and tungsten electrode material by K. company were used for specimens, by adhering conductive tape on the semi-conductive material of the lower electrode of XLPE specimen with the dimension of $16{\times}40{\times}30$ [mm] was used as negative electrode. In order to investigate the PD with ${\phi}$-q-n of XLPE specimen according to the electrode shape and the size of air voids. we examined the PD by varying the voltage after applying voltage of 3~20 kV on the electrode. Therefore, it was confirmed from the result of PD characteristics of specimen that the larger the air void than the gap between electrode (+) and electrode(-), the larger effect on the discharge when the bar electrode and needle electrode inserted into XLPE, and the closer the distance between the insulation and the needle electrode, the faster insulation breakdown.

Study on the Anode Electrode Reaction in the Metal-Air Cell (금속-공기전지의 Anode전극 반응에 관한 연구)

  • Kim, Yong-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.1002-1006
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    • 2010
  • In this study, magnesium (Mg), zinc (Zn) and aluminium (Al) as anode electrode and the solution of NaCl dissolved with 2~20 wt% as electrolytes were used for the metal-air cell. The open circuit voltage, short circuit current and I-V characteristics upon different kinds of anode electrode and electrolyte concentration were investigated. The open circuit voltage, initially about 1.45 V, rises to 1.6 V during the first 10 minutes indicating the necessity of an induction time to activate the catalyst on the air cathode. The short circuit current increases with an increased concentration of NaCl, causes an increase in the conductivity of the electrolyte solution, but the open circuit voltage did not under undergo influence of electrolyte. From NaCl 20 wt% electrolyte, the maximum output power of the magnesium electrode materials was measured with 177mW. It is found that the power characteristics of metal-air cell could be improved by using magnesium electrode materials in the NaCl electrolyte.

Synthesis of a new class of carbon nanomaterials by solution plasma processing for use as air cathodes in Li-Air batteries

  • Kang, Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.8
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    • pp.833-837
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    • 2015
  • Li-air batteries have a promising future for because of their high energy density, which could theoretically be equal to that of gasoline. However, substantial Li-air cell performance limitations exist, which are related to the air cathode. The cell discharge products are deposited on the surfaces of the porous carbon materials in the air electrode, which blocks oxygen from diffusing to the reaction sites. Hence, the real capacity of a Li-air battery is determined by the carbon air electrode, especially by the pore volume available for the deposition of the discharged products. In this study, a simple and fast method is reported for the large-scale synthesis of carbon nanoballs (CNBs) consisting of a highly mesoporous structure for Li-air battery cathodes. The CNBs were synthesized by the solution plasma process from benzene solution, without the need for a graphite electrode for carbon growth. The CNBs so formed were then annealed to improve their electrical conductivity. Structural characterization revealed that the CNBs exhibited both an pore structure and high conductivity.

Transient Characteristics of Mg/Air Fuel Cell (마그네슘/공기연료전지의 과도특성에 관한 연구)

  • Kim, Yong-Hyuk
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.65 no.3
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    • pp.210-215
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    • 2016
  • The transient characteristics of the Mg/Air fuel cell were ascribed to the load current, electrolyte concentrations, air electrode area and electrode distance. It was found that transient phenomena occurred in the load current, which is due to activate of the oxidation and reduction reaction process. The transient time increase with the load current increase. The transient characteristics were investigated with regard to internal resistance. The maximum power output analysis was employed in order to explain the delayed action under various experimental conditions. The internal resistances had a significant effect on the transient characteristics. The transient curves thus obtained were in almost agreement with internal resistance characteristics.

The Partial Discharge Characteristics of the XLPE According to the Tilt of the Needle Electrode (침 전극 기울기에 따른 XLPE의 부분 방전 특성)

  • Shin, Jong-Yeol;Ahn, Byung-Chul;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.28-33
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    • 2015
  • The needle electrode is inserted into the cross-linked polyethylene(XLPE) which is the ultra high voltage cable for electric power. By changing the tilt of the needle electrode, we investigated how the void and the thickness of the insulating layer influence the partial discharge(PD) characteristics and the insulating breakdown. In order to investigate the PD characteristics, The XLPE cable was used to the specimens and the tungsten electrode was used with the needle electrode. And the inner semi-conductive layer material of XLPE cable was used with the negative electrode by bonding with the use of conduction tape. The size of the specimens was manufactured to be $16{\times}40{\times}30[mm^3]$. We confirmed the effect on changing the PD characteristics according to the changing voltage and the tilt of the electrode after applying the voltage on the electrode from 1[kV] to 40[kV] at room temperature. In the PD characteristics, it was confirmed that the PD current of air void specimens with tilt was unstable more than that of no void specimens with tilt. It was also confirmed that the breakdown voltage was decreased because the effect of air void is more active than the change of the needle electrode tilt in the specimen with air void inside the insulation.

Breakdown Characteristics of Air in the Gap between Line Conductor and Plane Electrode in Case of Combustion Flame on the Plane Electrode (선도체 대 평면전극 갭에서 평면전극에 연소화염 존재시 대기의 절연파괴 특성)

  • Kim, In-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.4
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    • pp.73-80
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    • 2013
  • Breakdown characteristics of air in the vertical arrangement of line conductor and plane electrode in case of combustion flame on the plane electrode are examined by the application of AC. and DC voltages to the gap. In order to investigate the effect of paraffin flame on the breakdown characteristics of air, flashover voltages are measured according to the variation of the gap length and the horizontal distance between the flame and the line conductor. As the result of the experiment, flashover voltages are substantially lowered down to 29.8% in case of the AC voltage, and 16.1% in case of the negative DC voltage, when in the presence of the flame. from 100% when in the absence of flame. Flashover voltages of air in the range of smaller than 3㎝ at the horizontal distance are increased in the proportion of the gap length and the horizontal distance in case of both AC and negative DC voltages. But before the flashover occurs, the flame is extinguished by such corona wind that is produced from the line conductor when the gap length and the horizontal distance reach to a certain degree. The effect of relative air density and the phenomenon of thermal ionization are analysed as the reduction factors of flashover voltages, due to high temperature of the flame.

Particle collection characteristics of carbon fiber sheet discharge electrode by particle size and application to air cleaner (탄소섬유 시트 방전극의 입자 크기 별 집진 특성 및 공기청정기로의 응용)

  • shin, Dongho;Woo, Chang Gyu;Hong, Keejung;Kim, Hak-Joon;Kim, Yong-Jin;Han, Bangwoo
    • Particle and aerosol research
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    • v.14 no.3
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    • pp.81-88
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    • 2018
  • The market for improving the indoor air quality is continuously increasing, and air cleaners are the representative products. As interest in indoor air quality increases, so are the ultrafine particle which are harmful to the human body. Despite its many advantages, electrostatic precipitators are less used in indoor air due to ozone production. In this study, the carbon fiber sheet was applied to the discharge electrode and compared with the conventional tungsten wire discharge electrode. The particle collection efficiency and the amount of ozone generation were measured for 10-100 nm particles. Furthermore, it was applied to commercial air purifier with electrostatic precipitator to compare particle removal performance. The carbon fiber sheet type discharge electrode generates a small amount of ozone, and thus it can be applied to improve indoor air quality.

A Study of Power Output Characteristics for the Magnesium Metal Fuel Cell (마그네슘 금속연료전지의 출력특성에 관한 연구)

  • Kim, Yong-Hyuk
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.3
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    • pp.212-217
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    • 2014
  • The electric power output characteristics of magnesium fuel cell were investigated with regard to internal resistance. A equivalent circuit with the series-connected three internal resistance was introduced to analyze of the response to change of power. The power output analysis was employed in order to investigate the effect of internal resistances for the electrolyte concentration, air electrode area, Mg electrode area and distance between the electrodes. It was confirmed that internal resistance is generated by the electrolyte, air electrode and metal electrode, then those Internal resistances had a significant effect on the power output decrease. The power output was a maximum when the load resistance maches the internal resistance of the magnesium fuel cell. The fuel efficiency was only 50% at maximum power output. Higher fuel efficiency was achieved when the load resistance is greater than the internal resistance.