• Journal of Korean Society for Atmospheric Environment
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• 제21권E3호
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• pp.87-94
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• 2005

Wet scavenging by rain drops is a most important removal process of air pollutants. In order to study the scavenging mechanisms of aerosol particles, the characteristics of chemical components in the rain water were examined as a function of the amount of rainfall. Rain water were collected continuously and separated into the soluble and insoluble components. The elemental concentrations in both components were determined by a PIXE analysis. The physical and chemical characteristics of atmospheric aerosols during the rainfall events were measured simultaneously. The elemental concentrations in rain water decreased substantially just after rain started and then gradually declined in subsequential rain fall exceeding 1.0 mm. The large particles were scavenged more easily than the fine particles. Fe, Ti and Si in rain water were in high insoluble state. Contrarily, almost whole of S was dissolved in rain water.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.112-112
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• 2010

최근 세라믹스의 고온소결과정 없이 상온 후막제조가 가능한 에어로졸 데포지션법이 개발되어 이를 응용한 다양한 연구들이 진행되고 있다. 본 연구에서는 차세대 3차원 초고밀도 집적용연성(flexible)기판재료로서 $Al_2O_3$-PTFE(polytetrafluoroethylene) 복합체를 에어로졸 데포지션을 이용하여 상온제조 하였으며, 제조된 복합체 내의 $Al_2O_3$ 함량계산에 관한 연구를 진행하였다. 제조된 복합체는 기존의 세라믹만의 $Al_2O_3$ 후막에 비하여 PTFE의 첨가로 인한 잔류응력 감소효과가 있음이 확인되었으며 SEM, TEM 등 미세구조 분석을 통하여 충격고화 시 파우더의 미립화감소를 확인할 수 있었다. 또한, 공정의 최적화를 위한 분석 시 중요한 요소인 복합체 내의 세라믹 함량을 간편한 전기적 특성 측정을 통하여 계산하는 방법에 대한 연구를 진행하였다. 이를 위하여 이종 물질의 혼합에 관한 이론인 Hashin-Shtrikman bound theory와 3차원 정전장 해석 시뮬레이션을 병행하여 계산의 오차범위를 산출하고 실제 제조된 복합체 내의 $Al_2O_3$ 함량을 5 vol.% 이내의 오차로 측정할 수 있었다.

• Nuclear Engineering and Technology
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• 제51권1호
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• pp.125-137
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• 2019

The purpose of this paper is to study the source term behavior after severe accidents by using a semi-kinetic model for simulation and calculation of in-containment activity. The reactor containment specification and the safety features of the containment under different accident conditions play a great role in evaluating the in-containment activity. Assuming in-vessel and instantaneous release of radioactivity into the containment, the behavior of in-containment isotopic activity is studied for noble gasses (Kr and Xe) and the more volatile elements of iodine, cesium, and aerosols such as Te, Rb and Sr as illustrative examples of source term release under LOCA conditions. The results of the activity removal mechanisms indicates that the impact of volumetric leakage rate for noble gasses is important during the accident, while the influence of deposition on the containment surfaces for cesium, mainly iodine isotopes and aerosol has the largest contribution in removal of activity during evolution of the accident.

• 한국전기전자재료학회논문지
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• 제35권4호
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• pp.322-332
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• 2022

Energy storage capacitors based on dielectric ceramics with superior polarization properties and dielectric constant can provide much higher output power density due to their very fast energy charging/discharging rates, which are particularly suitable for operating pulsed-power devices. For an outstanding energy storage performance of dielectric capacitor, a large recoverable energy density could be derived by introducing a slim polarization-electric field hysteresis loop into dielectric materials by various technical approaches. Many research teams have explored various dielectric capacitor technologies to demonstrate high output power density and ultrafast charging/discharging behavior. This article reviews the recent research progress in high-performance dielectric capacitors for pulsed-power electronic applications.

• Nuclear Engineering and Technology
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• 제53권2호
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• pp.509-521
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• 2021

In this paper, from a review of the size distribution of the bubbles during pool scrubbing obtained from experiments by EPRI, we apply the bubble size distributions to analyses on the decontamination factors of pool scrubbing via I-COSTA (In-Containment Source Term Analysis). We perform sensitivity studies of the bubble size on the various mechanisms of deposition of aerosol particles in pool scrubbing. We also perform sensitivity studies on the size distributions of the bubbles depending on the diameters at the nozzle exit, the molecular weights of non-condensable gases in the carrier gases, and the steam fractions of the carrier gases. We then perform analyses of LACE-ESPANA experiments and compare the numerical ~ results to those from SPARC-90 and experimental results in order to show the effect of the bubble size distributions.

• 한국대기환경학회지
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• 제16권5호
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• pp.487-497
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• 2000

Spring time is a favorable season to be easily observed the Yellow Sand phenomenon in East Asia. In particular most of the phenomenon tend to occur in April. However, Yellow Sand phenomenon was observed from almost the whole country of Korea in winter of 1966, 1977 and 1999. The features of the synoptic weather pattern in the source regions, air stream flow between the source region and Korea, the measurement of TSP concentration, aerosol size distribution, and chemical composition of snow samples associated with Yellow Sand phenomenon were investigated. The result showed the characteristic evolutionary feature of the synoptic system associated with Yellow Sand phenomena, that is, a strong low level wind mobilized the dust within 2 or 3 days before Yellow Sand phenomenon being observed in Seoul. The wind was remarkably intensified in the source region on January 24, 1999 under the strong pressure gradient, A trajectory analysis showed that the Yellow Sand particle could be reached to Korea within 2 days from the source region, Gobi desert, through Loess plateau and Loess deposition region. The TSP concentration at the top of Kwanak mountain during the Yellow Sand phenomenon is abruptly increasing than the monthly mean concentration. The size resolved number concentration of aerosols ranging from 0.3 to 25${\mu}{\textrm}{m}$ was analyzed during Yellow Sand episode. It was evident that aerosols were distinguished by particles in the range of 2-3 ${\mu}{\textrm}{m}$ to result in the abrupt increase in January 1999, After Yellow Sand phenomenon, there was heavy snow in Seoul. By the analysis of snow collected during that time, it was observed that both the Ca(sup)2+ concentration and pH were increased abnormally compared to those in the other winter season.

• Journal of Korean Society for Atmospheric Environment
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• 제19권E3호
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• pp.137-148
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• 2003

In this study, we examined the influence of long-range transport of dust particles and air pollutants on the photochemistry of NO$_3$on Jeju Island, Korea (33.17 N, 126.10$^{\circ}$E) during the Asian Dust-Storm (ADS) period of April 2001. Three ADS events were observed during the periods of 10∼12, 13∼14, and 25∼26 April. Average concentration level of nighttime NO$_3$on Jeju Island during the ADS period was estimated to be about 2 x 10$^{8}$ molecules cm$^{-3}$ ( - 9 pptv). Decreases in NO$_3$levels during the ADS period was likely to be determined mainly by the enhancement of the $N_2$O$_{5}$ heterogeneous reaction on dust aerosol surfaces. The reaction of N20s on aerosol surfaces was a more important sink for nighttime N03 during the ADS due to the significant loading of dust particles. The reaction of $N_2$O$_{5}$ with NMHCs and the gas-phase reaction of N20s with water vapor were both significant loss mechanisms during the study period, especially during the NADS. However, dry deposition of these oxidized nitrogen species and a heterogeneous reaction of NO$_3$were of no importance. Short-term observations of $O_3$, NO$_2$, DMS, and SO$_2$in the MBL indicated that concentrations of most of these chemical species were different between the ADS and non - Asian - Dust-Storm (NADS) periods, implying that their levels were affected sensitively by the differences in air mass trajectories.

• 한국입자에어로졸학회지
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• 제20권3호
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• pp.95-102
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• 2024

Enhancing the oxygen surface exchange reaction by increasing the specific surface area of the electrode is a promising structural approach to lowering the operating temperature of solid oxide fuel cells (SOFCs). Nanowire structures, due to their high specific surface area and lower tortuosity of ion and electron conduction pathways, play a vital role in enhancing SOFC electrode performance. In this study, we synthesized La_0.6Sr_0.4CoO_3-𝛿 (LSC) nanowires using a polycarbonate membrane filter as a nanotemplate and applied them to the cathode for intermediate-temperature SOFC fabrication. The fabricated cell exhibited a 10% increase in peak power density at 650℃, achieving 0.506 W·cm^-2, compared to cell using only commercial LSC powder. Furthermore, distribution of relaxation times analysis revealed a 15% reduction in area-specific polarization resistance in the mid-frequency range. These findings demonstrated that the electrode with LSC nanowires fabricated through electrospray deposition can significantly improve electrochemical performance of intermediate-temperature SOFC.

• 한국대기환경학회지
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• 제21권1호
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• pp.119-129
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• 2005

The ambient TSP data measured at Seoul, Incheon. Taean, Daegu, Busan in Korea were used to explain the chemical composition and general features of Asian Dust (AD) observed in Korea. 9 episodes out of 19 were sampled from 2000 through May 2002, and measurements were conducted covering ionic and metal components with mass concentration. The results showed that daily averaged mass concentration (TSP) during the AD episodes was 458 $\mu\textrm{g}$/㎥, and ionic and metal concentrations were 27.93 $\mu\textrm{g}$/㎥ and 71.7 $\mu\textrm{g}$/㎥, respectively, accounting for 6.1 % and 15.5% of the total aerosol mass. TSP concentrations during episodes were varied from 120 to 1742 $\mu\textrm{g}$/㎥ according to the impact of Asian Dusts and had a tendency of showing higher values at sites in the west side of Korea, which can be explained by the effect of diffusion and deposition. In this study, ionic components like Ca (NO$_3$)$_2$, CaSO$_4$, NaNO$_3$, Na$_2$SO$_4$ were prominent types in secondary aerosol during AD periods and also indicated that V, Co as well as soil elements such as Ca, Fe, Mg, Mn, K correlated well with Al, while Cu, Cd, Pb, Zn didn't agree well with it. In addition, enrichment factors (EFs) for each metal component were obtained to provide simple information about source contribution of Asian Dust, and the results were compared with those from other AD studies. In this study, the results showed that aerosol properties in Korea during the Asian Dust were considerably different from those of general atmospheric condition and specially varied from case to case rather than site to site, which implies that there are certain variations in the soil of source region, pathways of air mass, and meteorological condition. For the enhanced study, those factors should be combined with the features of Asian Dust resolved from this study.

• The Journal of Advanced Prosthodontics
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• 제6권2호
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• pp.96-102
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• 2014

PURPOSE. This study was performed to characterize the effects of zirconia coated with calcium phosphate and hydroxyapatite compared to smooth zirconia after bone marrow-derived osteoblast culture. MATERIALS AND METHODS. Bone marrow-derived osteoblasts were cultured on (1) smooth zirconia, (2) zirconia coated with calcium phosphate (CaP), and (3) zirconia coated with hydroxyapatite (HA). The tetrazolium-based colorimetric assay (MTT test) was used for cell proliferation evaluation. Scanning electron microscopy (SEM) and alkaline phosphatase (ALP) activity was measured to evaluate the cellular morphology and differentiation rate. X-ray photoelectron spectroscopy (XPS) was employed for the analysis of surface chemistry. The genetic expression of the osteoblasts and dissolution behavior of the coatings were observed. Assessment of the significance level of the differences between the groups was done with analysis of variance (ANOVA). RESULTS. From the MTT assay, no significant difference between smooth and surface coated zirconia was found (P>.05). From the SEM image, cells on all three groups of discs were sporadically triangular or spread out in shape with formation of filopodia. From the ALP activity assay, the optical density of osteoblasts on smooth zirconia discs was higher than that on surface treated zirconia discs (P>.05). Most of the genes related to cell adhesion showed similar expression level between smooth and surface treated zirconia. The dissolution rate was higher with CaP than HA coating. CONCLUSION. The attachment and growth behavior of bone-marrow-derived osteoblasts cultured on smooth surface coated zirconia showed comparable results. However, the HA coating showed more time-dependent stability compared to the CaP coating.