• Journal of the Korea Institute of Building Construction
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• v.19 no.1
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• pp.31-38
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• 2019

In this study, amine derivatives and ion exchange resins were selected to actively control penetration ions ($SO{_4}^{2-}$, $Cl^-$) as the element technology of repair materials for concrete structures in drainage environments. Ions ($SO{_4}^{2-}$, $Cl^-$) adsorption performance and corrosion resistance of calcium hydroxide solution with amine derivative and ion exchange resin were confirmed by ion chromatography and potentiostat analysis. As a result of the experiment, it was confirmed that the amine derivative is excellent in the adsorption of chlorine ion and the ion exchange resin is excellent in the adsorption of sulfate ion. It has been confirmed that corrosion resistance can be increased by proper combination of two materials in the calcium hydroxide solution containing sulfate ion and chloride ion simulating sewage environment.

• Journal of the Korea Institute of Building Construction
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• v.20 no.1
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• pp.1-9
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• 2020

Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.

• Journal of environmental and Sanitary engineering
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• v.14 no.1
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• pp.31-41
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• 1999

Several new ion exchange resins have been synthesized from chloromethyl styrene-1, 4-di-vinylbenzene with 1%, 2%, 5% and 10%-crosslinking and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and had good resistance to heat at $280^{\circ}C$. The $UO_2^{2+}$ aqueous solution was not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was twenty minutes and adsorptive power decreased in proportion to crosslinking size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations is in the order of $UO_2^{2+}$, $Cu^{2+}$ and $Ce^{3+}$ .

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.74-79
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• 2016

The effects of scale formation of hardness material caused by electrode reactions on the desalination performance of the membrane capacitive deionization (MCDI) were investigated. During the repeated adsorption and desorption process for the influent containing $Ca^{2+}$ ion, changes in effluent concentration and cell potential with respect to the number of adsorption were analyzed. It was found that $OH^-$ generation at the cathode was initiated at about 0.8 V or more of cell potential. In addition, the scale of $Ca(OH)_2$ was formed on the surface of cathode carbon electrode by combining adsorbed $Ca^{2+}$ ions and $OH^-$ ions generated from electrode reaction. As the scale was forming, the electrical resistance of carbon electrode was increasing, which resulted in the decrease of the adsorption amount. In the case of the operation at 1.5 V cell potential, the adsorption was reduced to 58% of the initial adsorption amount due to the scale formation.

• Journal of environmental and Sanitary engineering
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• v.15 no.1
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• pp.77-87
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• 2000

Several new ion exchange resins have been synthesized from chloromethyl styrene-l,4-divinylbenzine with 1%, 2%, 10% and 20%-crosslink and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and have good resistance to heat. The $UO_2^{2+}$ was not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was two hours and adsorptive power decreased in proportion to crosslink size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations was in the order of $UO_2^{2+}$, $Ni{2+}$ and $Nd{3+}$.

• Nuclear Engineering and Technology
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• v.16 no.2
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• pp.80-88
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• 1984

The removal mechanism of air borne methyl iodide by triethylenediamine (TEDA) impregnated charcoal bed was investigated. The analysis of experimental data indicates that pore diffusion is the rate controlling step when the air velocity is over 20cm/sec, and both fore diffusion resistance and external mass transfer resistance are contributed to the overall resistance when the air velocity is 10cm/sec. The adsorption model to describe the performance of impregnated charcoal bed under dry condition where water vapors do not exist in air, is proposed. The calculated values and experimental results are well matched.

• Applied Science and Convergence Technology
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• v.23 no.6
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• pp.366-370
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• 2014

ZnO:Al transparent conductive films were deposited on glass substrates by RF magnetron sputtering technique and annealed by rapid thermal annealing system. The influence of annealing time on the structural, electrical, and optical properties of ZnO:Al thin films was investigated by atomic force microscopy, X-ray diffraction, Hall method and optical transmission spectroscopy. As the annealing time increases from 0 to 5 min, the crystallinity is improved, the root main square surface roughness is decreased and the sheet resistance is decreased. The lowest sheet resistance of ZnO:Al thin film is 90 ohm/sq. The reduction of sheet resistance is caused by increasing carrier concentration due to substituent Al ion. All films are transparent up to 80% in the visible wavelength range and the adsorption edge is a blue-shift due to Burstein-Moss effect with increasing annealing time.

• Proceedings of the KIEE Conference
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• 2000.11c
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• pp.434-436
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• 2000

In this study, we investigate the optical characteristics of merocyanine dye Langmuir-Blodgett(LB) film using the oscillation characteristics of quartz crystal. As results, the resistance and frequency shift at the parallel resonance under the UV irradiation is to be going down. This behaviour of resistance and frequency is different from the case of general mass adsorption into the organic film on the quartz crystal. Generally the frequency decrease of quartz crystal oscillator, which has been considered as mass loading, goes along with the resistance increase. Thus it has been suggested that the J-aggregate dissociation in merocyanine dye LB film by UV irradiation give rise to transformation of oscillation characteristics of quartz crystal.

• KSBB Journal
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• v.17 no.4
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• pp.345-349
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• 2002

The adsorption of the antimicrobial compounds(AMCs) and their heat-resistance were investigated for the packaging film manufacture, wherein, the antimicrobial compounds were adsorbed on a silica component. The naturally source antimicrobial compounds were produced by methylotropic actinomycetes strains MO-16 and MO-17, extracted with ethylacetate. Antimicrobial compounds adsorbed on water-soluble silica had retained activity against Gram(+) and the Gram(-) bacteria after heat treatment at 150$\^{C}$ for 5min. The benzoic acid showed strong antimicrobial activity to fungi and was stable to heat treatment. The combination of antimicrobial compound plus benzoic acid was synergistic against test strains. Therefore, we estimated that the water-soluble silica is suitable for the packaging film manufacture as a adsorbent of the antimicrobial compounds.

• Journal of Biomedical Engineering Research
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• v.34 no.1
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• pp.34-39
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• 2013

For the biocompatibility test of implantable devices or for the sensitivity evaluation of biomedical sensors, it is required to understand the mechanism of the protein adsorption and the interaction between the adsorbed proteins and cells. In this study, the adsorption of proteins in a cell culture medium with fetal bovine serum onto an indium tin-oxide electrode was characterized by using linear sweep voltammetry and impedance spectroscopy. We immersed the fabricated ITO electrodes in the culture medium for 30, 60, or 90 min, and then measured the electrochemical properties of electrodes with 10 mM $Fe(CN){_6}^{3-/4-}$ and 0.1 M KCl electrolyte. With an increase of contacting time, the anodic peak current was decreased and the charge transfer resistance was increased. However, both parameters were recovered to the values before contact with the medium after the treatment of Trypsin/Ethylenediaminetetraacetic acid hydrolyzing proteins.