• 한국광물학회지
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• 제9권1호
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• pp.17-25
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• 1996

Usual experimental adsorption isotherms as a function of relative humidity were constructed from adsorbed water contents in soils, which were kept more than 2 days in vacuum desiccators with constant humidities controlled by sulfuric acids of various concentrations. From the experimental data, the adsorption surface areas were calculated on the basis of the existing adsorption theory, such as Langmuir, BET, and Aranovich. Based on the Gibbs function describing chemical potential of perfect gas, the relative humidities in the desiccators were transformed into their chemical potentials, which were assumed to be the same as the potentials of equilibratedly adsorbed water in soils. Moreover, the water potentials were again transformed into the equivalent capillary pressures, heads of capillary rise, and equivalent radius of capillary pores, on the basis of Laplace equation for surface tension pressure of spherical bubbles in water. Adsorption quantity distributions were calculated on the profile of chemical potentials of the adsorbed water, equivalent adsorption and/or capillary pressures, and equivalent capillary radius. The suggested theories were proved through its application for the prediction of temperature rise of sulfuric acid due to hydration heat. Adsorption heat calculated on the basis of the potential difference was dependant on various factors, such as surface area, equilibrium constants in Langumuir, BET, etc.

• 한국대기환경학회지
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• 제14권2호
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• pp.133-142
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• 1998

Gas adsorption on adsorbents depends on temperatures and pressures. When these parameters are fixed, the adsorption capability and selectivity can not be changed. If the gas adsorption is controlled by another factor like electromagnetic field, the adsorption and desorption can be managed by much intentional way. The microwave has characteristics to excite particular components such as water without destroying it. In this study, microwave was irradiated to the adsorbent of an NaY zeolite which is almost transparent to microwave. As vapor of 1, 1, 2- trichloro-1, 2, 2-trifluoroethane (CFC-113) and water flowed simultaneously on the zeolite packed in a column at room temperature, only water was adsorbed. The . adsorbed water was removed from the zeolite and then replaced by CFC-113, since the microwave was irradiated. Greater the power of microwave was, more CFC-113 was adsorbed. The water adsorption took place again after a latent period by stopping the microwave irradiation.

• 대한화학회지
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• 제15권6호
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• pp.285-293
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• 1971

The statistical thermodynamical properties of heavy water are calculated according to the transient state theory of significant liquid structure. The calculated values are shown to be in good agreement with the observed ones. The grand canonical ensemble partition function for the adsorbed phase of heavy water on graphite surface is derived using the theory. The adsorption isotherm, the surface pressure, the molar entropy and the molar internal energy for the adsorbed phase and then the molar heat of adsorption are calculated according to the derived partition function. The thermodynamic properties of the adsorbed water are also calculated and the results are compared with those of heavy water and discussed in view of the experimentally observed phenomena.

• Journal of the Korean Wood Science and Technology
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• 제43권5호
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• pp.691-699
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• 2015

To evaluate the possibility of charcoal as Green Infrastructure (GI) materials, data such as moisture content, amount of adsorbed water, and amount of evaporation were collected. Some data from previous study were referenced to find out if correlations exist between results in this study and previous study. Only porosity was directly related to moisture content. Two mechanical charcoal had better abilities than traditional charcoal in all three categories. Mechanical black charcoal chips produced by National Forestry Cooperative Federation (NFCFC) adsorbed 333.3% of water in thirty minutes, 297.5% in five minutes, and evaporated around 75% water in four days. This ability is much higher than other five charcoal. Even though results of test showed various degrees and NFCFC was the best as GI materials, data of charcoal were also within acceptable range based on generally accepted characteristics of GI materials.

• 한국농공학회지
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• 제42권2호
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• pp.63-70
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• 2000

The present study was carried out for 7-months (from October 1.1997 to April 30. 1998) at a rice cultivation area blocked from livestock farming, farmstead and industrial complex to investigate the runoff loading of nitrogen and phosphorus in a plot(5,000$m^2$) paddy field areas. The runoff loading of total-N, amminia-N nitrate-N and total-P were 12.96kg/ha, 5.42kg/ha, 1.52kg/ha and 1.41kg/ha , respectively. When the runoff loading of nutrients was compared by dissolved and adsorbed forms, about 66% of total-N by dissolved form and the rest 34% by adsorbed form were flowed into streams. But 56% of total-P by adsorbed form and the rest 44% by dissolved form were flowed into streams. The phosphrous compounds , which were flowed into streams by runoff sediments and then sedimented, keep exchanging with water at water body in undelivered condition. And it moves gradually into water layer. This process can cause eutrophication continually and repeatedly in water environment . So, a sound program is needed to reduce soil erosion from farmlands.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2003년도 춘계학술발표논문집
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• pp.328-330
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• 2003

A surface equation of state for globular proteins at air-water interface accounting for the molecular structure, segment-segment, segment-solvent, and electrostatic interactions was proposed and compared to C-14 isotope experiments. This lattice model comprised a simplifying assumption that all adsorbed segments are in the form of trains. The number of segment adsorbed per molecule in case of bovine serum albumin linearly depended on the surface concentration whereas the lysozyme segments adsorbed at the interface were independent of surface concentration. The segment-solvent(water) interaction for both of proteins were found to be unfavorable owing to the proteins unfolding. From comparison of model computation and experimental data, BSA unfolded more than lysozyne because of the larger surface area of contact.

• Membrane and Water Treatment
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• 제15권1호
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• pp.31-39
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• 2024

The flow in a nanopore of filtration membrane is often multiscale and consists of both the adsorbed layer flow and the intermediate continuum fluid flow. There is a controversy on which interface the slippage should occur in the nanopore filtration: On the adsorbed layer-pore wall interface or on the adsorbed layer-continuum fluid interface? What is the difference between these two slippage effects? We address these subjects in the present study by using the multiscale flow equations incorporating the slippage on different interfaces. Based on the limiting shear strength model for the slippage, it was found from the calculation results that for the hydrophobic pore wall the slippage surely occurs on the adsorbed layer-pore wall interface, however for the hydrophilic pore wall, the slippage can occur on either of the two interfaces, dependent on the competition between the interfacial shear strength on the adsorbed layer-pore wall interface and that on the adsorbed layer-continuum fluid interface. Since the slippage on the adsorbed layer-pore wall interface can be designed while that on the adsorbed layer-continuum fluid interface can not, the former slippage can result in the flux through the nanopore much higher than the latter slippage by designing a highly hydrophobic pore wall surface. The obtained results are of significant interest to the design and application of the interfacial slippage in nanoporous filtration membranes for both improving the flux and conserving the energy cost.

• 대한화학회지
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• 제19권5호
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• pp.317-324
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• 1975

$Na^+,\;Ca^{2+},\;Ni^{2+},\;Al^{3+}$ 이온이 포화된 montmorillonite상에 여러 溫度에서 일어난 $H_2O와\;D_2O$의 氣相吸着에 관하여 연구하였다. 吸着으로 인하여 생긴 OH의 IR 신축진동 band를 computer에 의하지 않고 4개의 Gauss 成分으로 나누었다. 물과 silanol OH기와의 共鳴理論은 $3625cm^{-1}와\;2680cm^{-1}$로 증명되었다. $3400cm^{-1}$와 2475cm 에서의 broad한 吸收는 吸着된 물과 水素結合을 일으키고 있는 silanol OH의 신축진동에 의한 것이었고 $3650cm^{-1}와\;2345cm^{-1}$ band는 吸着된 $H_2O와\;D_2O$에 의한 것이었다. 吸着水와 表面 OH사이의 水素結合은 精電氣的 相互作用에 의한 것임이 밝혀졌다.

• KEPCO Journal on Electric Power and Energy
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• 제2권3호
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• pp.437-445
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• 2016

This paper discussed the effect of ammonia concentration adsorbed on fly ash for the ammonia emission as AAFA (Ammonia Adsorbed Fly Ash) produced from coal fired plants due to operation of NOx reduction technologies was landfilled with distilled or sea water at closed and open systems, respectively. Ammonia bisulfate and sulfates adsorbed on fly ash is highly water soluble. The pH of ammonium bisulfate and sulfate solution had significant effect on ammonia odor emission. The effect of temperature on ammonia odor emission from mixture was less than pH, the rate of ammonia emission increased with increased temperature when the pH conditions were kept at constant. Since AAFA increases the pH of solution substantially, $NH_3$ in the ash can release the ammonia order unless it is present at low concentration. $NH_4{^+}$ ion is unstable in fly ash and water mixtures of high pH at open system, which is changed to nitrite or nitrate and then released as ammonia gas. The proper conditions for < 20 ppm of ammonia concentration released from the AAFAs landfilled in ash pond were explored using an open system with sea water. It was therefore proposed that optimal operation to collect AAFA of less than 168 ppm ammonia at the electrostatic precipitator were controlled to ammonia slip with less than 5 ppm at SCR/SNCR installations, and, ammonia odor released from mixture of fly ash of 168 ppm ammonia with sea water under open system has about 20 ppm.

• KEPCO Journal on Electric Power and Energy
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• 제4권1호
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• pp.39-45
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• 2018

Ammonia Adsorbed Fly Ash (AAFA) samples produced from coal fired plants equipped with SNCR (Selective Non-Catalytic Reduction) of nitrogen oxides with urea have been chemically analyzed, and their physical and dissolution properties have been investigated. XRD results for the ammonia component in AAFA ascertained that ABS (ammonium bisulfate) and AS (ammonium sulfate) were deposited on fly ash as $SO_3$ reacted with unreacted ammonia at SNCR. SEM and EDS images showed that fine ashes on large fly ash surface of sphere type were agglomerated, due to adhesive role of ammonium salts attached fly ashes. Dissolution test results of ammonium salts absorbed on AAFA in distilled water or sea water showed that the proportion of un-ionized $NH_3$ to $NH_4{^+}$ were primarily a function of pH and temperature. Increasing pH and temperature causes an increase in the fraction of un-ionized $NH_3$. At pHs of 9.6 and 10.7, un-ionized $NH_3$ and $NH_4{^+}$ ions are present in equal amounts at distilled water and sea water, respectively.