• 제목/요약/키워드: acrylic modified

검색결과 133건 처리시간 0.042초

자동차용 고무호스의 진동 절연성능 향상에 관한 연구 (Improvement of Insulation Performance of Vehicle Rubber Hoses)

  • 정헌섭;민병권;이성훈;우희수;박현호
    • 한국소음진동공학회논문집
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    • 제22권9호
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    • pp.837-844
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    • 2012
  • We considered an approach in terms of materials for improvement of insulation performance of vehicle rubber hoses. Ethylene propylene rubber(EPDM) for heater hoses in cooling system and acrylic rubber(AR) for intercooler hose in intake system were chosen for mixing for the vibration and noise performance. We modified EPDM and AR through changing compound of base polymer, reinforcement fillers and additives. Dynamic mechanical analysis(DMA) was used to measure viscoelastic properties such as shear modulus and loss factor($tan{\delta}$). Vehicle acceleration test was also conducted to observe indoor changes in insulation performance of hoses.

4각 순환유동층의 수력학적 특성 (Hydrodynamic Characteristics of the Rectangular Type Circulating Fluidized Bed)

  • 현상열;이관석
    • 열처리공학회지
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    • 제10권4호
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    • pp.232-236
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    • 1997
  • A rectangular type circulating fluidized bed (CFB) with an internal nozzle and two partition walls was proposed. In this modified CFB, an internal nozzle and two slanted partition walls were additionally set in the riser. This cold mode apparatus was made of acrylic resin; the riser was 1500mm high and $1000{\times}1000mm^2$ in the cross sectional area, the internal nozzle was 200mm high and 10mm in the inner diameter, and the partition wall was 7mm thick. Glass beads of $91{\mu}m$ in the mean diameter were employed as bed materials. In the cold mode by using the proposed CFB with an internal nozzle, it was possible to change the particle hold up by changing the gas flow ratio of the nozzle to the total(Qn/Qt). It was found that the inflection point which devided the bed structure between the dense and the dilute phase in the riser varied with Qn/Qt.

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한국산 저질무연탄 연소용 순환식유동층 연소로 개발(간막이벽과 내부노즐을 설치한 순환유동층내에서의 유체거동) (Technical Development for the Circulating Fluidized Bed Combustor of firing Korean Low Grade Anthracite Coals (Particle Flow Patterns in a Circulating Fluidized-Bed with an internal Nozzle and a Partition Wall))

  • 이관석
    • 열처리공학회지
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    • 제6권4호
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    • pp.243-248
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    • 1993
  • A Circulating Fluidized-Bed (CFB) with an internal nozzle and a partition wall was proposed. The technique of fluidization is related to operations first used commercially in the fields of metallurgical and mechanical engineering such as the heat treatment of metals and power station combustors. In the modified CFB, an internal nozzle and a partition wall were additionally set in the main bed. This cold mode CFB apparatus made of acrylic resin; the main bed is 1,500mm high and 100mm in the inner diameter, the internal nozzle is 130mm high and 10mm in the inner diameter, and the partition wall is 7mm thick and 100mm in the diameter. Glass beads of $89{\mu}m$ in the mean diameter were employed as bed materials.

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Grafting of Casein onto Polyacrylonitrile Fiber for Surface Modification

  • Jia Zhao;Du Shanyi
    • Fibers and Polymers
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    • 제7권3호
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    • pp.235-240
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    • 2006
  • Polyacrylonitrile (PAN) fiber was grafted with casein after alkaline hydrolysis and chlorination reactions of the original fiber. The structures and morphologies of the casein grafted fiber were characterized by Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), and scanning electron microscope (SEM). Moisture absorption, specific electric resistance, water retention value, and mechanical properties were also investigated. The results showed that casein was grafted onto the surface of the PAN fiber and the grafted PAN fiber presented better hygroscopicity compared with the untreated fiber. With proper tensile strength, the modified fiber could still meet the requirement for wearing. A mechanism was proposed to explain the deposit of casein on the synthetic acrylic fiber.

Alternative impression technique for multiple abutments in difficult case to control

  • Jung, Bock-Young;Lee, Keun-Woo
    • The Journal of Advanced Prosthodontics
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    • 제2권1호
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    • pp.1-3
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    • 2010
  • BACKGROUND. Even though excellent impression materials are now available for making accurate replication for hard and soft tissue, the numerous dentists have faced lots of obstacles in making simultaneous impressions of multiple abutments. CASE DESCRIPTION. This article describes a modified method of tray fabrication using auto-polymerizing acrylic resin and impression technique for multiple prepared teeth in cases with limitations and difficulties in taking dental impressions. CLINICAL IMPLICATION. This segmental tray technique has several advantages, including higher impression quality, fewer impressions, and being more comfortable for the patient and less stressful for the clinician.

Comparative evaluation of micro-shear bond strength to different luting procedures of ceramics to dentin

  • Lee, Yoon-Jeong;Park, Sang-Jin;Choi, Kyoung-Kyu
    • 대한치과보존학회:학술대회논문집
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    • 대한치과보존학회 2003년도 제120회 추계학술대회 제 5차 한ㆍ일 치과보존학회 공동학술대회
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    • pp.569-569
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    • 2003
  • I. Objectives The purpose of this study was to evaluate the effort of a modified luting procedure called "dual bonding technique" by compare micro-shear bond strength to different luting procedures of ceramics to dentin. II. Materials and Methods Eighty-four freshly extracted caries-and restoration-free human third molar were embedded in epoxy resin using acrylic ring. Flat superficial occlusal dentin surfaces were obtained, initially using a Low speed diamond saw and exposed detin surface was group with #600-grit SiC paper.(omitted)

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EFFECTS OF CHOPPED GLASS FIBER ON THE STRENGTH OF HEAT-CURED PMMA RESIN

  • Lee Sang-Il;Kim Chang-Whe;Kim Yung-Soo
    • 대한치과보철학회지
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    • 제39권6호
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    • pp.589-598
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    • 2001
  • The fracture of acrylic resin dentures remains an unsolved problem. Therefore, many investigations have been performed and various approaches to strengthening acrylic resin, for example, the reinforcement of heat-cured PMMA resin using glass fibers, have been suggested over the years. The aim of the present study was to investigate the effect of short glass fibers treated with silane coupling agent on the transverse strength of heat-polymerized PMMA denture base resin. To avoid fiber bunching and achieve even fiber distribution, glass fiber bundles were mixed with PMMA powder in conventional mixer whose blade was modified to be blunt. Composite of glass fiber($11{\mu}m$ diameter, 3mm & 6mm length, silane treated) and PMMA resin was made. Transverse strength and Young's modulus were estimated. Glass fibers were incorporated with 1%, 3%, 6% and 9% by weight. Plasticity and workability of dough was evaluated. Fracture surface of specimens was investigated by SEM. The results of this study were as follows 1. 6% and 9% incorporation of 3mm glass fibers in the PMMA resin enhanced the transverse strength of the test specimens(p<0.05). 2. 6% incorporation of 6mm glass fibers in the PMMA resin increased transverse strength, but 9% incorporation of it decreased transverse strength(p<0.05). 3. When more than 3% of 3mm glass fibers and more than 6% of 6mm glass fibers were incorporated, Young's modulus increased significantly(p<0.05). 4. Workability decreased gradually as the percentage of the fibers increased. 5. Workability decreased gradually as the length of the fibers increased. 6. In SEM and LM, there was no bunching of fibers and no shortening of fibers.

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기상 UV 그라프트 반응에 의한 고분자 필름의 표면 개질 (Surface Modification of Polymer Films by Vapor Phase Photografting of Functional Monomers)

  • 오승희;오세행;이진호
    • 접착 및 계면
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    • 제1권1호
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    • pp.23-29
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    • 2000
  • 소수성 고분자 재료 표면의 친수화 처리 및 기능성 작용기 도입은 재료의 응용성을 상당히 확장할 수가 있기 때문에 중요성이 인지되고 있다. 본 연구에서는 기상 UV 그라프트 반응(vapor phase photografting)에 의해 서로 다른 이온성을 가지는 비닐계 단량체들을 PE 표면에 도입하여 표면 친수성을 향상시켰다. 이를 위해 acrylic acid(음이온성), acrylamide(중성), allylalcohol(중성), allylamine(양이온성) N,N-dimethyl aminopropyl acrylamide(양이온성) 등 서로 다른 기능성 작용기를 갖는 친수성 단량체들을 본 실험실에서 고안한 기상 UV 그라프트 반응장치를 이용하여 기체상태에서 PE 표면에 도입하였다. 이들 단량체들이 도입된 PE 표면을 물 접촉각 측정과 ATR-FTIR을 이용하여 분석한 결과, 각 기능성 단량체들이 효과적으로 PE 표면에 그라프트되어 표면의 친수성이 향상되었음을 확인할 수 있었다. 본 연구에 사용한 기상 UV 그라프트 반응은 고분자 표면에 다양한 작용기를 도입하여 표면을 개질할 수 있는 효과적인 방법으로 생각되어진다.

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Structural Adjustment of In-Situ Surface-Modified Silica Matting Agent and Its Effect on Coating Performance

  • Xu, Qingna;Ji, Tongchao;Tian, Qingfeng;Su, Yuhang;Niu, Liyong;Li, Xiaohong;Zhang, Zhijun
    • Nano
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    • 제13권12호
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    • pp.1850137.1-1850137.9
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    • 2018
  • A series of silica surface-capped with hexamethyldisilazane (denoted as $H-SiO_2$) were prepared by liquid-phase in-situ surface-modification method. The as-obtained $H-SiO_2$ was incorporated into acrylic amino (AA) baking paint to obtain AA/$H-SiO_2$ composite extinction paints and/or coatings. $N_2$ adsorption-desorption tests were conducted to determine the specific surface area as well as pore size and pore volume of $H-SiO_2$. Moreover, the effects of $H-SiO_2$ matting agents on the physical properties of AA paint as well as the gloss and transmittance of AA-based composite extinction coatings were investigated. Results show that $H-SiO_2$ matting agents possess a large specific surface area and pore volume than previously reported silica obtained by liquid-phase method. Besides, they have better dispersibility in AA baking paint than the unmodified silica. Particularly, $H-SiO_2$ with a silica particle size of $6.7{\mu}m$ and the dosage of 4% (mass fraction) provides an extinction rate of 95.2% and a transmittance of 79.3% for the AA-based composite extinction coating, showing advantages over OK520, a conventional silica matting agent. Along with the increase in the silica particle size, $H-SiO_2$ matting agents cause a certain degree of increase in the viscosity of AA paint as well as a noticeable decrease in the gloss of the AA-based composite extinction coating, but they have insignificant effects on the hardness and adhesion to substrate of the AA-based composite coatings. This means that $H-SiO_2$ matting agents could be well applicable to preparing low-viscosity and low-gloss AA-based matte coatings.

전분 유래 엿당-아크릴 공중합체의 접착물성에 관한 연구 (Adhesive Properties of Starch-Derived Maltose-Acryl Copolymer)

  • 박성일;이명천
    • 접착 및 계면
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    • 제21권4호
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    • pp.135-142
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    • 2020
  • 최근 미세플라스틱과 같은 환경 문제로 석유계 플라스틱을 대체할 자연 유래 친환경 플라스틱에 대한 사람들의 관심이 증가하고 있다. 점·접착제 분야에서도 이런 추세에 맞추어 천연 유래 소재를 이용한 친환경 점·접착제들이 개발되고 있다. 그 중에서 엿당은 전분에서 유래한 천연 물질이며 식품 첨가제로 쓰이는 물엿의 주성분이다. 전분보다 낮은 분자량 때문에 물에 쉽게 녹고 무엇보다 이를 이용해 용액중합으로 다른 단량체와 공중합 될 수 있다는 가능성이 있다. 그러나 아직 엿당을 이용하여 점·접착제에 응용한 연구는 미비한 실정이다. 본 연구에서는 엿당을 아크릴 무수물로 개질한 후 FT-IR과 H-NMR을 통해 개질여부를 확인하였다. 그리고 개질한 엿당을 2종의 아크릴 단량체와 공중합 하였다. 합성한 수지의 접착 성능은 목재접착을 통해 조사하였다.