• Title/Summary/Keyword: acid rain environment

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The Influence of Weathering Conditions on the Outer Membrane of Biogas with Plasticized PVC : A Study using Non-destructive Tests

  • Kim, Changhwan;Ki, Wootae;Kim, SangMyung;Shin, Jinyong
    • Journal of the Korean institute of surface engineering
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    • v.47 no.2
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    • pp.57-62
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    • 2014
  • The biogas holder is composed of an outer membrane and an inner membrane which are subject to outdoor exposure and gas exposure respectively. The influence of weathering conditions on the photo-degradation of a biogas holder was investigated. Tests were performed under three different methods - outdoor exposure tests (Seosan, Arizona), accelerated tests (Xenon-are lamp) with the outer-membrane of biogas. Moreover, the changes in the aging process were monitored using color difference, gloss, the contact angle and an optical microscope. Changes in physical properties, such as decrease reduction in gloss, decrease in the contact angle, increase in color difference were observed in the aging process. The comparison between membrane 3B, 4B and membrane 5B under xenon-arc were discussed. Membrane 5B was very sensitive to ultraviolet (UV) ray. There were many difficulties in the outdoor exposure test due to acid rain, dust, and stain resistance.

A Study on practice for an Environment Friendly Design (환경친화적 디자인을 위한 실천을 관한 연구)

  • 송인호;이종석
    • Archives of design research
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    • v.13 no.4
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    • pp.33-41
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    • 2000
  • More recently, the ecocide like an environmental shocks of acid rain, oil spills and now the ozone layer have driven home the fact that we're all responsible for looking after our natural environment and threaten the our right to live. At such a situation enterprises has been to develop techniques of enhancing environment friendly design. However it is difficult to producing environment friendly product - especially at electronic product like a high accumulated thing and produced with a small amount - while they know the importance of environment. Because of a direct and actual disadvantage of enterprise and customer. Moreover it is rare and negative for physical point that an adaptation case of recycled material or natural one for designing. Therefore it is important to positive consideration and action of design process for the nature. In this paper the focus of interest is find out the active and real environmental friendly design practice scheme as a designer and understanding of basic of the environmental friendly design for a coexistence of the enterprise, customer, and environment.

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Reaction Path Modeling of Granitic Cultural Properties and Its Implication for Preservation (화강암질 석조문화재의 풍화반응경로 특성과 보존에 대한 제언)

  • Park Maeng-Eon;Sung Kyu-Youl
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.83-92
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    • 2005
  • Dissolution rate of minerals may differ from climates configuration, but weathering rate of feldspars is generally proved to be relatively higher The result of geochemical reaction modeling indicates the acid water of pH 4.5 excluding any other variables, was 2.3 times higher than that in ordinary rain of pH 5.7. This result proved that pH is very important factor in preservation of granite cultural properties. To prevent the weathering of stone cultural properties, weathering characteristics of stones should be studied first and constitution of dry environments, using water repellent or oil coating, isolating water which cause chemical weathering reaction like hydration and oxidization should be considered. Considering the long-term reactions between granite and rain, selection of materials, which can bring neutralization and non-oxidization conditions, are very important in using cleaning agents and biological controls.

A Study on the Comparison of Chemical Components in Rainwater at Coastal and Metropolitan areas (해안지역과 도시지역 강수의 화학적 성상에 관한 연구)

  • 강공언;강병욱;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.3
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    • pp.191-197
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    • 1992
  • In order to investigate the chemical components of acid precipitation at Kangwha near the Yellow Sea and Seoul in Korea, the precipitation samples were collected by wetonly precipitation sampler from February 1991 to January 1992, and pH, electric conductivity(E. C.) and major water-soluble ionic components were analyzed. Strong negative linear correlations were observed between the rainfall amount and the sum of major ionic components in $\mu eq/\ell$ at two sites. The sum of major ionic components also correlated negatively with rain intensity. The analytical results of precipitation samples at two sites were compared each other. Average values of volume-weighted pH were found to be 5.21 at Kangwha and 5.09 at Seoul. The cationic abundance($\mu eq/\ell$) in rainwater showed the general trend $NH_4^+ > Na^+ > Ca^{2+} > Mg^{2-+} > H^+ > K^+$ at Kangwah and $NH_4^+ > Ca^{2+} > Na^+ > H^+ > Mg^{2+} > K^+$ at Seoul. The anionic abundance showed the general trend $SO_4^{2-} > Cl^- > NO_3^-$ at Kangwha and $SO_4^{2-} > NO_3^- > Cl^-$ at Seoul. The concentrations of seasalt such as $Na^+ and Cl^-$ were higher at Kangwha than Seoul. The concentrations of $nss-SO_4^{2-}, nss-Cl^- and NO_3^-$ which are acid composition were higher at Seoul(96.3 $\mu eq/\ell$) than Kangwha(69.0 $\mu eq/\ell$). The contribution of seasalt to the composition of precipitation were higher at Kangwha(34.1%) than Seoul(15.7%). Ammonia and calcium species in rainwater at Kangwha and Seoul are interpreted to have 91% of neutralizing capacity of the original sulfuric and nitric acids. Provided that the precipitation acidity originates primarily from sulfate and nitrate, sulfate was found to contribute about 73-75% of the free precipitation acidity.

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Ecological Examinations of the Radial Growth of Pine Trees (Pinus densiflora S. et Z.) on Mt. Namsan and the Potential Effects of Current Level of Air Pollutants to the Growth of the Trees in Central Seoul, Korea.

  • Kim, Eun-Shik
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.E
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    • pp.371-386
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    • 1994
  • Ecological examinations of the radial growth Patterns of pine trees(Pinus densiflora Sieb. et Zucc) growing on Mt. Namsan in central Seoul were made to test a Proposition that the pine trees decline due to the influence of air pollution and acid rain, which was proposed by some researchers in Korea, and the potential effects of current level of air pollutants to the growth of the Pine trees in central Seoul have been speculated. Tree-rings of 40 trees sampled at 3 sites of Mt. Namsan were prepared and examined using a Computer-aided Tree-Ring Measuring System at Kookmin University, Korea. Air Pollutant data collected by the Ministry of Environment( MOE ) and the Forestry Research Institute(FRI) were used to infer the general conditions of the environment. Correlation analysis was applied to the data set of tree growth and the other environmental factors. General information derived from the close examination of the tree-rings and the data on air pollution, drought and the other biological conditions suggested that the growth of the pine trees was severely affected by the occurrence of drought(climatic variation), the prevalence of the pine leaf gall midges(insects), and the suppression by the black locust trees(Robinia pseudo-acacia L.) (competition among trees). While the current condition of air pollution in Seoul cannot be categorized as good, the concentrations of air pollutants are not so high as to cause acute damages to the trees. In addition, while the data of rain acidity showed episodic low PHs of under 4.0, the average of them is far less acidic than those which were observed in either northeastern United States or central Europe, where the decline of trees were not solely attributed to any of the air pollutants. Considering the sequential facts that one of the most important environmental factors that affect the growth of trees is weather condition of the forest that the proposition of the decline of the pine trees was made without careful examination of the growth patterns and past growth history of them as well as the complex influences of many other factors including the weather conditions to the growth of trees, and that no objective explanation has been made on the causal relationships between the current condition of air pollution and the growth of the trees, such a proposition should be evaluated as invalid for the explanation of tree growth on Mt. Namsan in central Seoul, Korea. The author evaluates the factors of air pollution (including acid rain) as the predisposing factors, which may have the Potentials to chronically affect the tree growth at the forest ecosystem on Mt. Namsan for a long period of time. Ecosystem ecological studies should be further carried out to carefully explain both the functional and the structural aspects of the ecosystem processes, which include the biogeochemistry and the long-term changes of soil conditions as well as the growth of the other tree species on the mountain.

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Chemical Properties and Nutrient Loadings of Rainwater during Farming Season (영농기 강우의 화학적 특성 및 부하량 평가)

  • Ko, Byong-Gu;Kim, Min-Kyeong;Lee, Jong-Sik;Kim, Gun-Yeob;Park, Seong-Jin;Kwon, Soon-Ik;Jung, Goo-Buk;Lee, Deog-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.578-583
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    • 2010
  • Acid rain and its problem to environment such as acid precipitation and environmental problems related to the air pollution in East Asia has been emerging. To evaluate the acidity and chemical characteristics of rainwater precipitated in western Korea, Suwon and Taean, its pH and ion concentrations were investigated during farming season (April to November) in 2009. Also, ion composition and cation-affected neutralization were determined to evaluate the contribution of cations on the acidity of rainwater. Ion and electrical conductivity between the measured and the estimated showed high correlation. The $Na^+$ in rainwater was the main cation followed by ${NH_4}^+>Ca^{2+}>H^+>Mg^{2+}>K^+$. Sum of $Na^+$ and ${NH_4}^+$ contents was over 65% of total cations contents. In the case of anions, the concentration was in order of ${SO_4}^{2-}>{NO_3}^->Cl^-$. The ${SO_4}^{2-}$ among anions in rainwater composed about 61%, which showed on average 130.2 ${\mu}eq\;L^{-1}$ and 121.3 ${\mu}eq\;L^{-1}$ during monitoring at Suwon and Taean, respectively. Also, 89.6 and 88.6% of soluble sulfate in rainwater at Suwon and Taean area was NSS-${SO_4}^{2-}$ (Non-Sea Salt sulfate). Especially, ${NH_4}^+$ and $Ca^{2+}$ contributed greatly in neutralizing the acid rain in dry season. Total nitrogen content flowed into soil from rain was around 1~2 kg $ha^{-1}$ in each month, but in July at Suwon, it reached 6 kg $ha^{-1}$ due to heavy rain (over 7.3 mm).

Characteristics of the rocks and its weathering phenomena of the Gameunsa 3-story and Naweonri 5-story Pagodas located at the Kyeongju city, Korea (감은사지 3층 석탑(동탑)과 나원리 5층 석탑의 암석과 풍화현상의 특징에 대한 연구)

  • Lee, Sang Hun
    • Journal of Conservation Science
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    • v.5 no.1 s.5
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    • pp.20-40
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    • 1996
  • For obtaining the basic data for establishing plan on the conservation of the Gameunsa 3-story and Naweonri 5-story Pagodas located at the Kyeongju city, the characteristics of the rock and weathering phenomena have been investigated. The former consists of quartz-rlch granite containing small amount of biotite, and the latter of alkali granite with abundant perthite, These rock phases are nearly identical to the marginal phase of medium-grained hornblende-biotite granodiorite and alkali granite respectively, which are distributed around the Kyeongju city. The rock weathering may be governed mainly by chemical weathering of feldspar following physical segregation of quartz grains and pervasive moss. The feldspar easily dissolve In the solution with pH<7 to precipitate clay mineral such as a kaolinite as a secondary phase on the feldspar surface. However, the chemical weathering of feldspar may continue when the surface is washed by the rain according to removal of the reprecipitated phase. On forwarding, the weathering may be greatly Influenced by the acid rain. Exfoliation and weathering along igneous lineation resulting in exfoliating along the structural line are the characteristic weathering phenomena. Also the secondary small cracks are irregularly developed on the rocks due to different strain on places by the overall structural unbalance of the pagodas. Along these cracks, the rain water intrudes deeply into the rocks and weathering occurs intensively compared to other parts. Weathering may be artificially promoted by the grinding or sculpturing when the pagodas were made. Because it may influence on the physical properties of the rocks as well as destruct the surface of the feldspar crystals, the major constituents of the rocks, it results in providing the environment of easy chemical weathering along time. For conservation, the pagodas must be structurally balanced by compacting the soil basement and supplementing rocks on the destroyed part. On the exfoliated part it is better not to be artifically treated as using cementing material. But the cracks may be filled up by cementing material to avoid the intrusion of acidic water. To supplement the rocks on the destroyed part, it may be better to use similar rock phases from identical biotite granite and alkali granite masses around the Kyeongju city.

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Effect of Temperature and Water Immersion on Strength Properties of Spot Welded Zincked Steel Plates (점용접 아연도금강판의 강도특성에 미치는 온도 및 침수의 영향)

  • Seo, Do-Won;Choi, Jun-Yong;Lim, Jae-Kyoo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.12
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    • pp.1864-1870
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    • 2004
  • A spot welded structures have an influence on a diverse climatic situation, for instance temperature, humidity and precipitation. In addition factors of environmental pollution such as acid rain, that courses corrosion, have the tendency to increase. But spot welded structures strength is affected by humidity and environment temperature. Therefore, it is important to evaluate effect of temperature and water immersion on strength properties of spot welded part. In this study, the strength distribution of spot welded plates is evaluated the environmental temperature of zinc coated steel plates. Test is conducted with welded part immersed in distilled and synthetic sea water. Specimens are immersed into water for 10, 100, 500 and 1000 hours to evaluate the offsets of water immersion time on tensile-shear strength under the conditions of -40, 0, 20 and 5$0^{\circ}C$. From this result, spot welded specimens with 5 mm clearance have lower tensile-shear strength in the distilled water or synthetic sea water than without clearance. And they have lower tensile-shear strength under -4$0^{\circ}C$ and over 5$0^{\circ}C$.

A Numerical Study on the $NO_{x}$ Reduction in 500MW Pulverized Coal Tangential Firing Boiler (500MW급 접선분사형 미분탄보일러의 $NO_{x}$ 저감에 관한 수치해석적 연구)

  • Choi, Choeng-Ryul;Kang, Dae-Woong;Kim, Chang-Nyung;Park,, Man-Heung;Kim, Kwang-Chu;Kim, Jong-Kill
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.967-972
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    • 2001
  • The emission of $NO_{x}$ during coal combustion is a major reason of environment impact. $NO_{x}$ is an acid rain precursor and participates in the generation of smog through ozone production. $NO_{x}$ can be divided into thermal $NO_{x}$, fuel $NO_{x}$ and prompt $NO_{x}$. Thermal $NO_{x}$ is formed in a highly temperature condition dependent. Fuel $NO_{x}$ is dependent on the local combustion characteristics and initial concentration of nitrogen bound compound, while prompt $NO_{x}$ is formed in a significant quantity in some combustion environments, such as low temperature and short residence times. This paper presents numerical simulation of the flow and combustion characteristics in the furnace of a tangential firing boiler of 500MW with burners installed at the every comer of the furnace. The purpose of this paper is to investigate the reduction of $NO_{x}$ emission in a 500MW pulverized coal tangential firing boiler with different OFA's and burner angles. Calculations with different air flow rates of over fired air(OFA) and burner angles are performed.

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Internal Flow Analysis of a Tubular-type Small Hydroturbine by Runner Vane Angle

  • Nam, Sang-Hyun;Kim, You-Taek;Choi, Young-Do;Lee, Young-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.7
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    • pp.1044-1050
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    • 2008
  • Most of developed countries, the consumption of fossil fuels has been serious problems that cause serious environment pollution like acid rain, global warming. Also, we have faced that limitation fossil fuels will be exhausted. Currently, small hydropower attracts attention because of its small, clean, renewable, and abundant energy resources to develop. By using a small hydropower generator of which main concept is based on using the different water pressure levels in pipe lines, energy which was initially wasted by use of a reducing valve at the end of the pipeline, is collected by turbine in the hydropower generator. A propeller shaped hydroturbine has been used in order to use this renewable pressure energy. In this study, in order to acquire basic design data of tubular type hydraulic turbine, output power, head, efficiency characteristics due to the flow coefficient are examined in detail. Tubular-turbine among small hydraulic power generation can be used at low-head. The purpose of this study is to research turbine's efficiency due to runner vane angle using CFD analysis.