• Journal of Korean Society for Atmospheric Environment
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• v.13 no.4
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• pp.249-256
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• 1997

To identify the long-term influence of acid rain treatment on tree growth, acid rain of various composition (pH 2.0, pH 4.0 and pH 5.6 as control) was applied to several landscape trees for five months (April through August, 1991). Tree height, pH values and $Al^{3+}$ concentration in soil were investigated. Acid rain treatments seemed to promote height growth in the first year (1991), but have become an inhibiting factor over five years. All of coniferous species and most broad-leaved species, except Acer ginnala, showed opposite trends in height responses to acid rain treatments between the first (1991) and last (1996) year. In contrast, Acer ginnala showed similar trends to acid rain treatments in the height growth between 1991 and 1996. This result suggested that Acer ginnala has a characteristic adapability to acid rain stress. pH values of surface soil were lower than those of 30 cm soil depth. This fact suggested that acid rain treatments made surface soil acidic condition. In addition, physiological characteristics (photosynthesis, stomatal condition and biomass) have to be investigated to identify the relationship between long-term effects of $AL^{3+}$ concentration and growth.

• Journal of Korean Society for Atmospheric Environment
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• v.7 no.3
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• pp.208-218
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• 1991

To compare the resistance of landscape trees by acid rain, simulated acid rain was treated on the seeds of 6 coniferous species (Pinus densiflora, Pinus thunbergii, Pinus koraiensis, Taxus cuspidata, Cedrus deodara, Thuja occidentalis) and 6 broad-leafed species (Ligustrum obtusifolium, Acer Buergerianum, Acer Ginnala, Styrax obassia, Cornus Kousa, Magnolia obovata). The experimental design of randomized block arrangement with three replications was implemented in the experimental field of Yesan National Agri-Tech Junior College. The seeds of 12 tree species were planted on the nursery soil in the early spring of 1991. The regime of artificial acid rain, in terms of spray frequency per monthly and spray amount at year records. Simulated acid rain (pH 2.0, pH 4.0, pH 5.6 as control) containing sulfuric and nitric acid in the ratio of 3:2 (chemical equivalant basis) diluted ground water, were treated on the experimental plants under condition of cutting off the natural precipitation with vinyl tunnel, during the growing season (April 8 to August 31) in 1991. Seedling establishment, seedling growth and nutrient contents in needles and leaves were measured and compared among the treatment. The results were summerized as follows; 1. In general, coniferous species were more resistant than broad-leafed species in the resistant comparisons of landscape trees by simulated acid rain. But there were resistant tree species to acid rain among the broad-leafed species. 2. Among 6 coniferous species used in this experiment, Pinus densiflora, Pinus koraiensis, Taxus cuspidata, Cedrus deodara and Pinus thunbergii revealed the resistant tree species to acid rain. But Thuja occidentalis was very susceptible to acid rain, because of no germination in pH 2.0 treatment plot of acid rain. 3. Among 6 broad-leafed species used in this study, Magnolia obovata, Styrax obassia and Ligustrum obtusifolium showed relative resistant tree species to acid rain. But Acer Buergerianum, Acer Ginnala and Cornus Kousa were very susceptible to acid rain, because of no germination in pH 2.0 plot of acid rain treatment.

• Asian Journal of Atmospheric Environment
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• v.9 no.3
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• pp.222-227
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• 2015

The environmental education with ideal teaching tools (e.g., a small-scaled experimental kit) is essential for raising the public's, especially student's, awareness of many environmental issues. This study was undertaken to develop a do-it-yourself model instrument of acid rain and estimating its applicability to the environmental education. Our novel model tool consists of a body (17 cm width, 6 cm depth, and 17 cm height), an acid gas injector, acid four rain reservoirs, and a drop supply pump. An alternative model instrument that can be more readily assembled was also suggested. Based on our novel approach, we carried out several model experiments with educatees (i.e., high school and college students, and adults). The results of questionnaires indicated that educatees achieved a very deep understanding of acid rain through an experienced model experiment. A 77 to 89% of educatees experienced the reappearance experiment of acid rain by our model instrument felt that it was very useful as a teaching tool of environmental education.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.2
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• pp.191-204
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• 2003

A one dimensional time dependent acid rain model considering size distribution of aerosols and hydrometeors is developed to predict observed chemical and physical properties of precipitation. Temporal variations of anions and cations observed are predicted fairly well with acid rain model simulations. It is found that aerosol depletion rates are highly dependent on aerosol sizes under the assumption of Marshall - Palmer raindrop size distribution. Also, the aerosol depletion during the initial rain event largely influences on ion concentrations in rainwaters.

• Interaction and multiscale mechanics
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• v.5 no.1
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• pp.41-56
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• 2012

This study is focused on evaluation of the tensile properties of concrete exposed to acid rain environment. Acid rain environment was simulated by the mixture of sulfate and nitric acid in the laboratory. The dumbell-shaped concrete specimens were submerged in pure water and acid solution for accelerated conditioning. Weighing, tensile test, CT, SEM/EDS test and microanalysis were performed on the specimens. Tensile characteristics of the damaged concrete are obtained quantitatively. Evolution characteristics of the voids, micro cracks, chemical compounds, elemental distribution and contents in the concrete are examined. The deterioration mechanisms of concrete exposed to acid rain are well elucidated.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.1
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• pp.33-44
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• 1988

For the purpose of examining the effects of simulated acid rain on the chemical properties of the experimental soil in Pinus densiflora seedlings and Forsythia koreana rooted cuttings, the experimental design of randomized block arrangement with three replications was implemented in the experimental field of Yesan National Agricultural Junior College. One-year-old Pinus densiflora seedlings and Forsythia koreana cuttings were planted in the pots filled the mixed soils (nursery soil: forest soil of siliceous sandy loam = 1 : V/V)in the early spring of 1985. The regime of artificil acid rain, in terms of spray frequency per monthly and spray amount at single treatment per plot, was simulated on the basis of climatological data averaged from 30 years records. Simulated acid rain (pH 2.0, pH4.0, and pH 5.5 as control) containing sulfuric and nitric acid in the ratio of 3:2 (chemical equivalant basis) diluted ground water, were treated on the experimental plants under condition of cutting off the natural precipitation with vinyl tunnel, during the growing season (May 1 to August 31) in 1985. THe results obtained in this study were as follows; 1. Soil acidity was dropped, and exchangeable aluminum contents in the soil was dramatically increased in both species, with decreasing pH levels of acid rain. 2. Exchangeable potassium, clacium, magnesium contents, and base saturation degree of the soil were highly drcreased in two species as the pH levels of acid rain decreased. 3. In two species, sulfate concentrations in the soil were decreased of pH 4.0 treatment, and remarkably increased at pH 2.0 treatment of acid rain in comparison with control. 4. Total nitrogen and available phosphate contents of the soil were not affected by acid rain treatment in the both species, and Fe contents at pH 2.0 treatment were highest among three acid rain treatments.

• Korean Journal of Environment and Ecology
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• v.7 no.1
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• pp.10-21
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• 1993

Artificial acid rain (pH 3.0, 4.0 and 5.0) and ground was treated on the seeded pots of 4 species to examine its effects on germination and survival rate, seedling growth and contact angles on needle surface. Artificial acid rain was prepared by diluting sulfuric acid with ground water and ground water (pH 6.5) was used as control. Artificial acid rain was sprayed to seeded pots two or three times per week for growing season, one times per week for winter seasons. About 5mm of artificial acid rain was treated each time from early April, 1991 to early October, 1993. Germination and survival rate, soil acidity, seedling growth and contact angles on the needle surface were measured and compared among the treatments. The results were summarized as follows ; Artificial acid rain might have positive effects on growth-related characteristics of the seedlings in the first and second year of acid rain treatment, and the effects were differed among four species. All growth-related characteristics of the seedlings in third year, however, decreased with decrease of pH values of artificial acid rain. This was considered to the results of acidic accumulation over soil buffer capacity. Needle injury and biomass (defoliation) was correlated with the pH values of artificial acid rain, and this character might be a good criteria for early diagnosis of acid rain injury. The differences of soil acidity were significant among the treatments for all species. Contact angles between needle surface and water droplet decreased with decrease of pH values of artificial acid rain. Measuring and comparing contact angles might be very good criteria for early diagnosis of acid rain injury.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.3
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• pp.263-268
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• 1996

This study was conducted for the assessment of the effects of acid rain and soil fertilizers on photosynthetic rate, was content, and contact angle on 5-year seedlings of Japanese red pine (Pinus densiflora Sieb. et Zucc.) leaves. The seedlings were exposed to pH 3.0 (simulated acid rain), pH 6.5 (groung water) and rain (pH around 4.6). The seedlings were also treated with $Ca(OH)_2, Mg(OH)_2, and Ca(OH)_2 + Mg(OH)_2 + C.F.(compound fertilizer)$. Photosynthetic rate, stomatal conductance, was content, contact angle value, and mineral nutrient content of the leaves were measured and the results were as follows: 1. Photosynthetic rate and stomatal conductance of the leaves increased with the increase of pH. Photosynthetic rate and stomatal conductance increased with application of soil fertilizer in the pH 3.0 treatment, but showed no changes in the rain and the pH 6.5. 2. Contact angle value and was content of the leaves did not change with the pH treatment, but increased with the fertilizer treatments. 3. Mineral nutrient contents of the leaves were lowest in the rain treatment and highest in the pH 6.5 treatment. The increase of mineral nutrient contents was observed with the soil fertilizer treatments.

• Korean Journal of Environment and Ecology
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• v.6 no.1
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• pp.1-8
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• 1992

Artificial acid rain (pH 3.0, 4.0 and 5.0) was treated on the seeded pots of 4 species to examine its effects on germination, leaf injury and seedling growth. Artificial acid rain was prepared by diluting sulfuric acid with ground water and ground water (pH 6.5) was used as control. Artificial acid rain was sprayed to seeded pots three times per week. About 5mm of artificial acid rain was treated each time from early April to early October, 1991. Germination, seedling establishment, leaf injury, soil acidity and seedling growth were measured and compared among the treatments. The results were summarized as follows; 1. Germination and seedling establishment rate of Pinus thunbergiana was highest on the pH 4.0 pot whereas that of Picea abies was highest on the pH 3.0 pot. Those of Pinus densiflora and Abies holophylla were not significantly differed among the treatments. 2. The differences in seedling height of all species were not significantly differed among the treatments. 3. Seedling dry weight of Pinus densiflora differed significantly among the treatments. but that of Pinus thunbergiana did not differ. 4. With decrease of pH value of artificial acid rain. the number of injured needle and injured individual tended to be increased. 5. The differences of soil acidity were significant among the treatments for all species.

• Journal of Korean Society for Atmospheric Environment
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• v.9 no.2
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• pp.147-153
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• 1993

From March 1990 to August 1991, every each 5mm bulk precipitation samples were collected at one residental area in Taejon City to investigate chemical characteristics of acid rain. Major ion concentrations of rain samples $(pH, SO_4^{2-}, NO_3^-, CL^-, NH_4^+, Na^+, K^+, Ca^{2+}, Mg^{2+})$ were analysed and compared with the concentration of air pollutants (T. S. P, $SO_2, NO_x$) that were measured by Ministry of Environment. The results of statistical analysis are as followings. Rain pH was relatively high on October and January and relatively low on August, November and February. Major anion is sulfate, and it's concentration is 2.36 times higher than nitrate's, and major cations are ammonium, sodium and calcium ion. Monthly variation of sulfate and calcium concentrations are higher than the others. Ion concentration and rain pH were correlated negatively with rainfall amount. Major ions in rain samples were $SO_4^{2-}, NO_3^-, NH_4^+, Ca^{2+}$ and regression equations are proposed by multiple regression of measured data. Also, regression equation between air pollutants(T. S. P, $SO_2$) and $SO_4^{2-}, Na^+, K^+, Ca^{2+}, Mg^{2+} ions in rain samples were made. From this wer can predict rain pH.