• Title/Summary/Keyword: accelerated stability analysis

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A Review on Ammunition Shelf-life Prediction Research for Preventing Accidents Caused by Defective Ammunition (불량탄 안전사고 예방을 위한 탄약 수명 예측 연구 리뷰)

  • Young-Jin Jung;Ji-Soo Hong;Sol-Ip Kim;Sung-Woo Kang
    • Journal of the Korea Safety Management & Science
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    • v.26 no.1
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    • pp.39-44
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    • 2024
  • In order to prevent accidents via defective ammunition, this paper analyzes recent research on ammunition life prediction methodology. This workanalyzes current shelf-life prediction approaches by comparing the pros and cons of physical modeling, accelerated testing, and statistical analysis-based prediction techniques. Physical modeling-based prediction demonstrates its usefulness in understanding the physical properties and interactions of ammunition. Accelerated testing-based prediction is useful in quickly verifying the reliability and safety of ammunition. Additionally, statistical analysis-based prediction is emphasized for its ability to make decisions based on data. This paper aims to contribute to the early detection of defective ammunition by analyzing ammunition life prediction methodology hereby reducing defective ammunition accidents. In order to prepare not only Korean domestic war situation but also the international affairs from Eastern Europe and Mid East countries, it is very important to enhance the stability of organizations using ammunition and reduce costs of potential accidents.

A Study on the Surface Deterioration Evaluation of Epoxy Resin Coating as Anticorrosive Material of Concrete Water Tank Using Ozone($O_3$) (오존 정수처리 음용수조 구조물에 사용하는 에폭시 수지 방수.방식재의 표면특성 평가)

  • 오상근;강효진;곽규성
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.513-518
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    • 2003
  • Recently, advanced systems for water treatment are introduced for water quality improvement. One of those systems is water treatment method using ozone($O_3$). For it has strong oxidizing energy, it is necessary to have materisl stability against $O_3$. In this paper, epoxy resin specimens using as anticorrosive material of concrete structure for drink water are used to serve as a material of deterioration evaluation. It is to be studied weight loss, surface corrosion of specimens, ingredient analysis of floating particle, a solute of chemical ingredient by way of accelerated ozone testing. As the results of experiment, specimen weight is decreased. The surface of specimen is eroded heavily and showed a loss of gloss and floating particle, and in the stability for drinking water, harmful ingredient is not detected in the water.

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Flow-Accelerated Corrosion Analysis for Heat Recovery Steam Generator in District Heating System (지역난방 배열 회수 보일러의 유동 가속 부식 원인 고찰)

  • Hong, Minki;Chae, Hobyung;Kim, Youngsu;Song, Min Ji;Cho, Jeongmin;Kim, Woo Cheol;Ha, Tae Baek;Lee, Soo Yeol
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.11-15
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    • 2019
  • Severe wall thinning is found on the tube of a low-pressure evaporator(LPEVA) module that is used for a heat recovery steam generator(HRSG) of a district heating system. Since wall thinning can lead to sudden failure or accidents that lead to shutdown of the operation, it is very important to investigate the main mechanism of the wall thinning. In this study, corrosion analysis associated with a typical flow-accelerated corrosion(FAC) is performed using the corroded tube connected to an upper header of the LPEVA. To investigate factors triggering the FAC, the morphology, composition, and phase of the corroded product of the tube are examined using optical microscopy, scanning electron microscopy combined with energy dispersive spectroscopy, and x-ray diffraction. The results show that the thinnest part of the tube is in the region where gas directly contacts, revealing the typical orange peel type of morphology frequently found in the FAC. The discovery of oxide scales containing phosphate indicates that phosphate corrosion is the main mechanism that weakens the stability of the protective magnetite film and the FAC accelerates the corrosion by generating the orange peel type of morphology.

Influence of Temperature and pH on the Stability of Dimethoxy Biphenyl Monocarboxylate${\cdot}$HCl Solutions

  • Choi, Woo-Chang;Kim, Dae-Duk;Shin, Young-Hee;Lee, Chi-Ho
    • Archives of Pharmacal Research
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    • v.24 no.2
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    • pp.159-163
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    • 2001
  • The accelerated stability of dimethoxy biphenyl monocarboxylate.HCl (DDB-S) was investigated in 6 mg/mL water solution in the pH ranging 2-10 and the temperature of $45-85^{\circ}C$. The observed rate of degradation followed first-order kinetics. The energy of activation for DDB-S degradation was calculated to be 14.1 and 16.5 $Kcal/mole$ at pH 5 and in distilled watery respectively. The degradation rate constant ($K_{25^{\circ}C}$) obtained by trending line analysis of Arrhenius plots for DDB-S was $5.3{\times}10^{-6}h^{-1}$. The times to degrade 10% ($t_{10}$) and 50% $t_{500}$) at $K_{25^{\circ}C}$ were 829 and 5,416 days, respectively. DDB-S exhibited the fastest degradation at pH 10 and the slowest rate at pH 5. In addition, at $K_{65^{\circ}C}$, degradation rate constants of DDB-S were 0.066, 0.059, 5.460, 32.171, and $1.4{\times}10^{-6}h^{-1}$ at pH 2, 5, 8, 10 and in distilled water, respectively. These observations indicated that the rate-pH profile of DDB-S showed general acid-base catalysis reaction in the range of pH 2-10.

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Studies on the Formation of Inclusion Complex between Omeprazole and $\beta$-cyclodextrin (오메프라졸과 베타-시클로덱스트린과의 포접화합물 형성에 따른 특성)

  • 소재일;이창현;이계주
    • YAKHAK HOEJI
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    • v.35 no.5
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    • pp.372-378
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    • 1991
  • To increase the stability and bioavailability of Omeprazole(OMP), which is used newly as a proton-pump inhibitor, inclusion complex of OMP with $\beta$-cyclodextrin($\beta$-CD) was prepared by coprecipitation method and its characteristics were ascertained by means of solubility test, DSC, IR, and the accelerated stability analysis. The type of OMP inclusion complex is classified as Bs-type on phase solubility diagram, and the stoichiometric ratio of OMP: $\beta$-CD complex is 1:2 and formation constant is 80.82/mole. The solubility of the complex could be increased remarkably by complexation compare with OMP. Degradation process of both OMP and OMP complex followed apparent first-order kinetics, of which degradation rate constants and activation energies are k$_{25}$=8.1$\times$10$^{-4}$/day, E$_{a}$=22 Kcal/mole (OMP), and k$_{25}$=4.65$\times$10$^{-6}$/day, E$_{a}$=35 Kcal/mole (complex), respectively. These results show the increase of the stability and solubility of OMP markedly, therefore it is believed that the improvement of stabilization for OMP by inclusion complexation might be practically available.

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Enhanced Aqueous Stability of Hirsutenone with Antioxidant

  • Moon, Ki-Young;Ahn, Byeong-Kil;Lee, Sang-Gon;Lee, Seo-Hyun;Yeom, Dong-Woo;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.41 no.6
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    • pp.331-336
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    • 2011
  • The instability of hirsutenone (HST), a potential therapeutic candidate for the treatment of atopic dermatitis (AD) and ovarian carcinoma, is one of the main concerns for the development of drug product. In the present study, aqueous stability of HST was investigated by kinetic analysis, and the effect of several factors covering temperature, nitrogen gas ($N_2$) flushing, and selection of proper antioxidant was compared. Cosolvent system composed of distilled water and methanol (9:1 v/v) was used as a vehicle to dissolve HST at the concentration of $200{\mu}g/mL$. Samples of aqueous solution were prepared under the absence or presence of antioxidants, such as ascorbic acid (AA), sodium edetate (EDTA), and ascorbyl palmitate (AP), and subjected for stability test. The degradation of HST in aqueous solution was followed by the first order kinetics with an extremely short half life of less than a week at room temperature, and was accelerated as the temperature increased. $N_2$ flushing brought a little enhancement in stability compared to control solution, but the effect was insufficient. The addition of AA and EDTA (0.1%) significantly enhanced the stability of HST at $40^{\circ}C$, but the addition of AP (0.01%) was limited due to its water insolubility and revealed no promising result. The stability of HST was increased proportionally by the amount of AA added, showing the difference in degree of stabilization as an order of magnitude. Finally, we conclude that HST was stabilized by the addition of a suitable antioxidant, suggesting AA as the most effective stabilizer.

A Study of Dynamis Force Estimation and Strength Design of KALES (포장가속시험시설의 동역학 힘 예측 및 강도설계에 관한 연구)

  • Kim, Nak-In;Yang, Sung-Chul;Park, Yong-Geol
    • Journal of Korean Society of Steel Construction
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    • v.13 no.2
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    • pp.211-221
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    • 2001
  • The dynamic force estimation and strength design of KALES(Korea Accelerated Loading and Environmental Simulator) are studied. The KALES is continuously rotating the test track and subjected to the dynamic or impact forces during operation since the track is composed of straight and curved line. To estimate the dynamic equation for the model car which was already made is derived with analytical and experimental techniques. Using similarity relationships between the model car and KALES, the dynamic force and stability properties for KALES can be predicted. The stress analysis and fatigue life estimation of KALES is also estimated with the calculated dynamic load. From the stress analysis and fatigue life estimation results, it was found that the design of KALES is safe.

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Evaluation of Thermal Aging on PVC Using Thermo Gravimetry Analysis and Accelerated Thermal Aging Test (TGA와 가속열화를 이용한 전선 피복용 PVC의 열적 열화평가)

  • 박형주;김기환;김홍
    • Fire Science and Engineering
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    • v.18 no.3
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    • pp.45-50
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    • 2004
  • Thermal degradation of PVC which used for insulator of 600V vinyl insulated wire has been studied by thermo gravimetry analysis and accelerated thermal aging test. The activation energy using thermo gravimetry analysis was determined by the kinetic methods, such as Kissinger and Flynn-Wall-Ozawa. The activation energy was determined to from 89.29 kJ/mol to 111.39 kJ/mol in 600V PVC insulated wire and from 97.80 kJ/mol to 119.25 kJ/mol in 600v heat-resistant PVC insulated wire. And also, the activation energy through a long-term thermal aging test was calculated by using Arrhenius equation In the low temperature of 8$0^{\circ}C$, 9$0^{\circ}C$, 10$0^{\circ}C$. The results showed that 600V PVC insulated wire was 92.16 kJ/mol, and 600v heat-resistant PVC insulated wire was 97.52 kJ/mol. Consequently, the activation energy of 600V heat-resistant PVC insulated wire is larger than 600V PVC insulated wire. Therefore, it can be predicted that 600V heat-resistant PVC insulated wire has a long-term stability relatively.

The Study of Restoration Technique of Wax-Treated Volume for the Annals of the Joseon Dynasty(II) - Evaluation of aging characteristics of Korean traditional paper, Hanji as the restoration material of the annals - (조선왕조실록 밀랍본 복원기술연구(제2보) - 실록의 복원용지 탐색을 위한 전통한지의 열화특성 평가 -)

  • Jeong, Seon-Hwa;Jeong, So-Young;Seo, Jin-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.43-56
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    • 2008
  • The purpose of the experiment was to evaluate the material stability of the paper of the annals of Joseon Dynasty for the conservation purpose and the categories were as listed below : 1. Procuring traditional Hanji and semi-Hanji from different regional hanji paper mill. 2. Artificial accelerated aging treatment to examination its stability (UV irradiation, dry heat) 3. Analysis of optical, physical characteristic. The suitable Hanji for categories would be used as a reconstruction material for the waxel paper in the papers of the annals of Joseon Dynasty.

Research on Ultraviolet Light Degradation According to Types of Encapsulants for PV Modules (태양광 모듈용 봉지재 종류에 따른 자외선 광열화 연구)

  • Seungah Ur;RakHyun Jeong;JuHwi Kim;Chanyong Lee;Lee Jaehyeong
    • Current Photovoltaic Research
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    • v.11 no.4
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    • pp.108-113
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    • 2023
  • Pressure to reduce costs in the current solar market is driving the development and implementation of new module designs and prompting the use of new materials and components. In order to utilize the variability of each material that makes up the module, it is essential to understand the basic characteristics of the material. In this article, we evaluate light degradation after UV irradiation as an encapsulation material. Measure and analyze the results of various characteristic tests for discoloration, optical and electrical property degradation before and after UV accelerated testing. To evaluate weathering stability, UV tests were performed comparing existing EVA and UVT-EVA, POE and improved low-cost POE. Even in the weather resistance test with a total UV exposure of 60 kW/m2, the properties of the encapsulants were mostly stable. EVA and POE-based encapsulants showed slight differences, and these slight differences are believed to pose a threat to long-term stability. This study is a basic analysis of encapsulation research for PV modules and will be helpful in understanding future development and encapsulant properties.