• 제목/요약/키워드: accelerated stability analysis

검색결과 66건 처리시간 0.02초

BD-R 장기보존 특성 평가를 위한 가속 열화 실험 조건과 안정성 평가 기준에 관한 연구 (A Study on Suitable Condition of Accelerated Aging Test and Evaluation Criteria of Data Stability for Archival Performance Analysis of BD-R media)

  • 이관용;박선주;김도현;조이형;김영주
    • 정보저장시스템학회논문집
    • /
    • 제10권1호
    • /
    • pp.7-13
    • /
    • 2014
  • The Blu-ray Disc Recordable(BD-R) is one of strong candidates for archival application among optical media formats, because of its large capability. However, the well-defined accelerated aging test conditions and evaluation criteria have not yet been fully confirmed for BD-R. In this study, the data stability and degradation aspect of BD-R were analyzed by the random-symbol error rate(R-SER) measurement after the accelerated aging test. And a reasonable test condition of accelerated aging for BD-R and the appropriate evaluation criterion using R-SER measurement were discussed.

지상환경하에서 복합재료의 물성저하를 고려한 한국형 틸팅열차 하이브리드 차체 구조물의 정적안정성 평가 (Evaluation of Static Stability of Hybrid Carbody Structures of Korean Tilting Train eXpress Including Degradation Effects of Composite Materials under Ground Environments)

  • 신광복;한성호
    • 대한기계학회논문집A
    • /
    • 제28권6호
    • /
    • pp.807-815
    • /
    • 2004
  • In order to evaluate the static stability of hybrid carbody structures of Korean Tilting Train eXpress(TTX) caused by degradation of composites under ground environments, T300/AD6005 graphite/epoxy composite specimens were exposed to accelerated environmental conditions including ultraviolet radiation, temperature and moisture fer 2000 hours. It was found that the stiffness and strength of composites after aging were lower than those of unexposed specimens, and decreased as the aging time increases. The values of the degraded properties were used in the static analysis to check the static stability of hybrid carbody structures caused by environmental degradation of composites. The results shown that the structural stability of hybrid carbody structures was affected by the degradation of composites after exposure to accelerated aging environments.

지르코늄-피리치온 착물에 관한 연구 (Studies on the Zr-Pyrithione Complex)

  • 권중무;이계주
    • Journal of Pharmaceutical Investigation
    • /
    • 제20권3호
    • /
    • pp.145-152
    • /
    • 1990
  • Zirconium pyrithione complex was prepared by reaction of sodium-pyrithione solution and zirconyl chloride solution. The physico-chemical properties of the complex was examined by means of IR, XRD, DSC and NMR. And the stability of Zr-complex was investigated on the basis of accelerated stability analysis under conditions of temp. elevation, UV radiation and pH dependence. The result indicates that the ratio of the ligand to metal in Zr-pyrithione complex was determined 4:1, and its stability constant was $4.643{\times}10^4$. The rate order of decomposition of the complex was apparent first-order reaction of which rate constant and the decomposition rate was not only accelerated by effect of heat and UV radiation but was catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of the complex and the suspension was most stable over the range pH 4-8 indicating that solvent catalysis is the primary made of reaction in this region.

  • PDF

장경간 강바닥판 케이블교량에 적용하기 위한 폴리우레탄 폴리머콘크리트의 공용특성 연구 (A Study to Evaluate Performance of Poly-Urethane Polymer Concrete for Long-Span Orthotropic Steel Bridge)

  • 박희영;이정훈;곽병석;최이현;김태우
    • 한국도로학회논문집
    • /
    • 제15권1호
    • /
    • pp.1-9
    • /
    • 2013
  • PURPOSES: The purpose of this study is to evaluate physical properties, durability, fatigue resistance, and long-term performance of poly-urethane concrete (PU) which can be possible application of thin layer on long-span orthotropic steel bridge and to check structural stability of bridge structure. METHODS : Various tests of physical properties, such as flexural strength, tensile strength, bond strength and coefficient of thermal expansion tests were conducted for physical property evaluation using two types of poly urethane concrete which have different curing time. Freezing and thawing test, accelerated weathering test and chloride ion penetration test were performed to evaluate the effect of exposed to marine environment. Beam fatigue test and small scale accelerated pavement test were performed to assess the resistance of PU against fatigue damage and long-term performance. Structural analysis were conducted to figure out structural stability of bridge structure and thin bridge deck pavement system. RESULTS: The property tests results showed that similar results were observed overall however the flexural strength of PUa was higher than those of PUb. It was also found that PU materials showed durability at marine environment. Beam fatigue test results showed that the resistances of the PUa against fatigue damage were two times higher than those of the PUb. It was found form small scale accelerated pavement test to evaluate long-term performance that there is no distress observed after 800,000 load applications. Structural analysis to figure out structural stability of bridge structure and thin bridge deck pavement system indicated that bridge structures were needed to increase thickness of steel deck plate or to improve longitudinal rib shape. CONCLUSIONS: It has been known that the use of PU can be positively considered to thin layer on long-span orthotropic steel bridge in terms of properties considered marine environment, resistance of fatigue damage and long-term performance.

수용액 중 Trimebutine maleate의 안정성 (Studies on the Stability of Trimebutine maleate in Aqueous Solution)

  • 박종현;이계주
    • 약학회지
    • /
    • 제34권6호
    • /
    • pp.415-421
    • /
    • 1990
  • The effects of temperature, pH, light and concentration on the degradation of trimebutine maleate in aqueous solution were investigated on the basis of accelerated stability analysis, and the stabilization of the solution was attempted by addition of several additives. The decomposition of trimebutine maleate in solution followed first-order reaction the was not only accelerated by temperature elevation but also the lower the concentratin the more speeded up the reaction. The decomposition mechanism of trimebtine could be confirmed by hydrolysis of ester bond in the structure. It was assumed trimebutine maleate is so photosensitive that the solution of the drug underwent accelerated decomposition under UV rays. What is more, the degradation of trimebutine solution was supposed to catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of ester, and the solution was most stable over the range of pH 2-2.8 in solution. The additives, citric acid, asparitc acid and glutamic acid, inhibited considerably the decomposition of the drug solution, and these additives might be used as stabilizers in trimebutine maleate solution.

  • PDF

합성수지 용기가 FAD 수용액의 안정성에 미치는 영향 (Effect of Synthetic Resin Container on the Stability of FAD Solution)

  • 이계주;유병설
    • 약학회지
    • /
    • 제23권3_4호
    • /
    • pp.147-152
    • /
    • 1979
  • Experiments were carried out to investigate for the interaction between FAD solution and synthetic resin containers made of polyvinylchloride(PVC), polyethylene(PE), and polycarbonate(PC), and for the effect of glycyrrhizine or malic acid on stabilization of FAD in aqueous solution by accelerated stability analysis. Analysis of FAD was determined by means of spectrometer and by separating by paper chromatography and metal ions were detected by atomic absorption spectrophotometer, which were extracted from containers by means of Food and Additive Regulation Standard. The thermal decomposition of FAD in aqueous solution was pseudo first order reaction and it was inhibited by adding glycyrrhizine or malic into the solution. PVC, PE and PC containers accelerated the decomposition of FAD in solution. It is assumed that bivalent heavy metals in resin containers may catalize the hydrolysis of FAD. The metals detected from the containers were Ca, Zn, Cu, Fe, Pb and Cd. And the total amounts of detected metals from PVC were 6.2mcg/cm$^{2}$, PE, 5.5mcg/cm$^{2}$, and PC, 2.7mcg/cm$^{2}$ which were proportional to the rate constant of FAD decomposition in aqueous solution.

  • PDF

트리메토프림과 ${\beta}$-시클로덱스트린 고분자 간의 포접복합체 형성에 의한 용출 및 안정성 향상 (Dissolution and Stability Enhancements of Trimethoprim by ${\beta}-Cyclodextrin$ Polymer Inclusion Complexation)

  • 김형태;박경옥;서성훈
    • Journal of Pharmaceutical Investigation
    • /
    • 제22권2호
    • /
    • pp.105-113
    • /
    • 1992
  • To improve the solubility and dissolution rate of trimethoprim (TMP), which is slightly soluble drug, its inclusion complexes were prepared and studied in this experiment. Inclusion complexes of TMP with ${\beta}-cyclodextrin$ and ${\beta}-cyclodextrin$ polymer (CDPS) were prepared according to Fenyvesi method. These were compared with TMP and its physical mixture with CDPS. Water, diluted hydrochloric acid and phosphate buffer solution were used as dissolution media. And accelerated stability test was studied at $50,\;70\;and \;80^{\circ}C$. It was found that solubility and dissolution rate of inclusion complexes were increased in water. Especially, the solubility and dissolution rate of TMP was found to be markedly increased by inclusion complexation with CDPS. In stability test, ${\beta}-cyclodextrin$ inclusion complexes were more or less stable than TMP alone. This tendency was not led in CDPS. Consequently, CDPS was useful in increasing dissolution rate and stability of TMP.

  • PDF

면내 방향 맥동 운동하는 외팔평판의 동적 안정성 해석 (Dynamic Analysis of Cantilever Plates Undergoing Translationally Oscillating Motion)

  • 현상학;유홍희
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2001년도 춘계학술대회논문집B
    • /
    • pp.366-371
    • /
    • 2001
  • Dynamic stability of an oscillating cantilever plate is investigated in this paper. The equations of motion include harmonically oscillating parameters which originate from the motion-induced stiffness variation. Using the multiple scale perturbation method is employed to obtain a stability diagram. The tability diagram shows that relatively large unstable regions exist when the frequency of oscillation is near twice the frequencies of the 1st torsion natural mode and the 1st chordwide bending mode.

  • PDF

Accelerated Newton-Raphson 방법에 의한 대형구조물의 자유진동수와 모우드형의 결정 (Determination of the Natural Frequencies and Mode Shapes of Large Structures by Accelerated Newton-Raphson Method)

  • 김만철;이인원
    • 대한토목학회논문집
    • /
    • 제14권5호
    • /
    • pp.1105-1113
    • /
    • 1994
  • 각종 구조물의 설계에 있어서 동적해석은 필수적이다. 이러한 구조물의 동적해석에 모우드 중첩법을 사용할 경우 고유치문제의 해석이 선행되어야 한다. 그러나 동적해석에 있어서 대부분의 노력, 즉 시간은 고유치와 그에 대응하는 고유벡터를 구하기 위하여 사용되기 때문에 보다 효율적인 고유치해법의 개발이 요구된다. 본 논문은 수치적 불안정성을 해소하고 수렴성을 향상시킴으로써 전체 해석시간을 줄이기 위해 Robinson-Lee 방법에 accelerated Newton-Raphson 방법을 적용한 고유치해법을 제시하였다. 제안방법의 효율성은 몇가지의 수치해석을 통해서 증명하였다.

  • PDF

자연 노화된 니트로셀룰로오스의 수명에 관한 연구 (A Study of Life about Naturally Aged Nitrocellulose by Storage)

  • 김동성;진홍식
    • 한국산학기술학회논문지
    • /
    • 제21권11호
    • /
    • pp.595-601
    • /
    • 2020
  • 10년 이상 보관된 니트로셀룰로오스 (Nitrocellulose, 니트로셀룰로오스) 재질의 화약용기 안전 검사를 진행하는 과정 중 화약이 보관되어진 용기에 균열이 발생한 것을 확인하여 고장 원인 분석 시험을 실시하였다. 고장이 발생한 데에 영향을 준 요인을 선별하기 위해 먼저 고장수목분석(Fault Tree Analysis, FTA)을 통해 고장 요인 및 원인에 대해 탐구하였으며, 보관 시 발생할 수 있는 내·외부적인 요인 및 환경에 대한 영향성을 확인한 결과 열에 의해 화학 반응이 가속화되어 발생한 화약용기의 물성 변화가 고장의 원인인 것으로 추정하였다. 이를 확인하기 위해 자연 노화된 화약용기를 이용하여 열충격시험, 양립성 시험 등의 환경시험을 수행하여 고장의 원인 분석을 수행하였으며, 가속노화시험을 통해 고장 재현 시험을 실시하였다. 이를 통해 앞선 고장수목분석 결과와 같이 열과 화약에 의해 화학 반응이 가속화되는 것을 확인할 수 있었으며, 화약용기의 물성이 변화하는 것을 확인하였다. 또한, 열 노화에 의한 수명 추정을 위해 아레니우스 모델(Arrhenius Model)을 이용하여 화약용기의 사용 수명을 추정하였다.