• Title/Summary/Keyword: accelerated stability analysis

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A Study on Suitable Condition of Accelerated Aging Test and Evaluation Criteria of Data Stability for Archival Performance Analysis of BD-R media (BD-R 장기보존 특성 평가를 위한 가속 열화 실험 조건과 안정성 평가 기준에 관한 연구)

  • Lee, Kwan-Yong;Park, Sun-Joo;Kim, Do-Hyun;Jo, Yi-Hyung;Kim, Young-Joo
    • Transactions of the Society of Information Storage Systems
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    • v.10 no.1
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    • pp.7-13
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    • 2014
  • The Blu-ray Disc Recordable(BD-R) is one of strong candidates for archival application among optical media formats, because of its large capability. However, the well-defined accelerated aging test conditions and evaluation criteria have not yet been fully confirmed for BD-R. In this study, the data stability and degradation aspect of BD-R were analyzed by the random-symbol error rate(R-SER) measurement after the accelerated aging test. And a reasonable test condition of accelerated aging for BD-R and the appropriate evaluation criterion using R-SER measurement were discussed.

Evaluation of Static Stability of Hybrid Carbody Structures of Korean Tilting Train eXpress Including Degradation Effects of Composite Materials under Ground Environments (지상환경하에서 복합재료의 물성저하를 고려한 한국형 틸팅열차 하이브리드 차체 구조물의 정적안정성 평가)

  • Shin, Kwang-Bok;Hahn, Seong-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.6
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    • pp.807-815
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    • 2004
  • In order to evaluate the static stability of hybrid carbody structures of Korean Tilting Train eXpress(TTX) caused by degradation of composites under ground environments, T300/AD6005 graphite/epoxy composite specimens were exposed to accelerated environmental conditions including ultraviolet radiation, temperature and moisture fer 2000 hours. It was found that the stiffness and strength of composites after aging were lower than those of unexposed specimens, and decreased as the aging time increases. The values of the degraded properties were used in the static analysis to check the static stability of hybrid carbody structures caused by environmental degradation of composites. The results shown that the structural stability of hybrid carbody structures was affected by the degradation of composites after exposure to accelerated aging environments.

Studies on the Zr-Pyrithione Complex (지르코늄-피리치온 착물에 관한 연구)

  • Kwon, Chung-Moo;Rhee, Gye-Ju
    • Journal of Pharmaceutical Investigation
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    • v.20 no.3
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    • pp.145-152
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    • 1990
  • Zirconium pyrithione complex was prepared by reaction of sodium-pyrithione solution and zirconyl chloride solution. The physico-chemical properties of the complex was examined by means of IR, XRD, DSC and NMR. And the stability of Zr-complex was investigated on the basis of accelerated stability analysis under conditions of temp. elevation, UV radiation and pH dependence. The result indicates that the ratio of the ligand to metal in Zr-pyrithione complex was determined 4:1, and its stability constant was $4.643{\times}10^4$. The rate order of decomposition of the complex was apparent first-order reaction of which rate constant and the decomposition rate was not only accelerated by effect of heat and UV radiation but was catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of the complex and the suspension was most stable over the range pH 4-8 indicating that solvent catalysis is the primary made of reaction in this region.

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A Study to Evaluate Performance of Poly-Urethane Polymer Concrete for Long-Span Orthotropic Steel Bridge (장경간 강바닥판 케이블교량에 적용하기 위한 폴리우레탄 폴리머콘크리트의 공용특성 연구)

  • Park, Heeyoung;Lee, Junghun;Kwak, Byeongseok;Choi, Iehyun;Kim, Taewoo
    • International Journal of Highway Engineering
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    • v.15 no.1
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    • pp.1-9
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    • 2013
  • PURPOSES: The purpose of this study is to evaluate physical properties, durability, fatigue resistance, and long-term performance of poly-urethane concrete (PU) which can be possible application of thin layer on long-span orthotropic steel bridge and to check structural stability of bridge structure. METHODS : Various tests of physical properties, such as flexural strength, tensile strength, bond strength and coefficient of thermal expansion tests were conducted for physical property evaluation using two types of poly urethane concrete which have different curing time. Freezing and thawing test, accelerated weathering test and chloride ion penetration test were performed to evaluate the effect of exposed to marine environment. Beam fatigue test and small scale accelerated pavement test were performed to assess the resistance of PU against fatigue damage and long-term performance. Structural analysis were conducted to figure out structural stability of bridge structure and thin bridge deck pavement system. RESULTS: The property tests results showed that similar results were observed overall however the flexural strength of PUa was higher than those of PUb. It was also found that PU materials showed durability at marine environment. Beam fatigue test results showed that the resistances of the PUa against fatigue damage were two times higher than those of the PUb. It was found form small scale accelerated pavement test to evaluate long-term performance that there is no distress observed after 800,000 load applications. Structural analysis to figure out structural stability of bridge structure and thin bridge deck pavement system indicated that bridge structures were needed to increase thickness of steel deck plate or to improve longitudinal rib shape. CONCLUSIONS: It has been known that the use of PU can be positively considered to thin layer on long-span orthotropic steel bridge in terms of properties considered marine environment, resistance of fatigue damage and long-term performance.

Studies on the Stability of Trimebutine maleate in Aqueous Solution (수용액 중 Trimebutine maleate의 안정성)

  • Park, Jong-Hyen;Rhee, Gye-Ju
    • YAKHAK HOEJI
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    • v.34 no.6
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    • pp.415-421
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    • 1990
  • The effects of temperature, pH, light and concentration on the degradation of trimebutine maleate in aqueous solution were investigated on the basis of accelerated stability analysis, and the stabilization of the solution was attempted by addition of several additives. The decomposition of trimebutine maleate in solution followed first-order reaction the was not only accelerated by temperature elevation but also the lower the concentratin the more speeded up the reaction. The decomposition mechanism of trimebtine could be confirmed by hydrolysis of ester bond in the structure. It was assumed trimebutine maleate is so photosensitive that the solution of the drug underwent accelerated decomposition under UV rays. What is more, the degradation of trimebutine solution was supposed to catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of ester, and the solution was most stable over the range of pH 2-2.8 in solution. The additives, citric acid, asparitc acid and glutamic acid, inhibited considerably the decomposition of the drug solution, and these additives might be used as stabilizers in trimebutine maleate solution.

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Effect of Synthetic Resin Container on the Stability of FAD Solution (합성수지 용기가 FAD 수용액의 안정성에 미치는 영향)

  • 이계주;유병설
    • YAKHAK HOEJI
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    • v.23 no.3_4
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    • pp.147-152
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    • 1979
  • Experiments were carried out to investigate for the interaction between FAD solution and synthetic resin containers made of polyvinylchloride(PVC), polyethylene(PE), and polycarbonate(PC), and for the effect of glycyrrhizine or malic acid on stabilization of FAD in aqueous solution by accelerated stability analysis. Analysis of FAD was determined by means of spectrometer and by separating by paper chromatography and metal ions were detected by atomic absorption spectrophotometer, which were extracted from containers by means of Food and Additive Regulation Standard. The thermal decomposition of FAD in aqueous solution was pseudo first order reaction and it was inhibited by adding glycyrrhizine or malic into the solution. PVC, PE and PC containers accelerated the decomposition of FAD in solution. It is assumed that bivalent heavy metals in resin containers may catalize the hydrolysis of FAD. The metals detected from the containers were Ca, Zn, Cu, Fe, Pb and Cd. And the total amounts of detected metals from PVC were 6.2mcg/cm$^{2}$, PE, 5.5mcg/cm$^{2}$, and PC, 2.7mcg/cm$^{2}$ which were proportional to the rate constant of FAD decomposition in aqueous solution.

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Dissolution and Stability Enhancements of Trimethoprim by ${\beta}-Cyclodextrin$ Polymer Inclusion Complexation (트리메토프림과 ${\beta}$-시클로덱스트린 고분자 간의 포접복합체 형성에 의한 용출 및 안정성 향상)

  • Kim, Hyung-Tae;Park, Kyung-Ock;Seo, Seong-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.22 no.2
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    • pp.105-113
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    • 1992
  • To improve the solubility and dissolution rate of trimethoprim (TMP), which is slightly soluble drug, its inclusion complexes were prepared and studied in this experiment. Inclusion complexes of TMP with ${\beta}-cyclodextrin$ and ${\beta}-cyclodextrin$ polymer (CDPS) were prepared according to Fenyvesi method. These were compared with TMP and its physical mixture with CDPS. Water, diluted hydrochloric acid and phosphate buffer solution were used as dissolution media. And accelerated stability test was studied at $50,\;70\;and \;80^{\circ}C$. It was found that solubility and dissolution rate of inclusion complexes were increased in water. Especially, the solubility and dissolution rate of TMP was found to be markedly increased by inclusion complexation with CDPS. In stability test, ${\beta}-cyclodextrin$ inclusion complexes were more or less stable than TMP alone. This tendency was not led in CDPS. Consequently, CDPS was useful in increasing dissolution rate and stability of TMP.

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Dynamic Analysis of Cantilever Plates Undergoing Translationally Oscillating Motion (면내 방향 맥동 운동하는 외팔평판의 동적 안정성 해석)

  • Hyun, Sang-Hak;Yoo, Hong-Hee
    • Proceedings of the KSME Conference
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    • 2001.06b
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    • pp.366-371
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    • 2001
  • Dynamic stability of an oscillating cantilever plate is investigated in this paper. The equations of motion include harmonically oscillating parameters which originate from the motion-induced stiffness variation. Using the multiple scale perturbation method is employed to obtain a stability diagram. The tability diagram shows that relatively large unstable regions exist when the frequency of oscillation is near twice the frequencies of the 1st torsion natural mode and the 1st chordwide bending mode.

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Determination of the Natural Frequencies and Mode Shapes of Large Structures by Accelerated Newton-Raphson Method (Accelerated Newton-Raphson 방법에 의한 대형구조물의 자유진동수와 모우드형의 결정)

  • Kim, Man Cheol;Lee, In Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.5
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    • pp.1105-1113
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    • 1994
  • For the design of various structures, the dynamic analysis of the structures is essential. Eigenproblem must be first computed when the mode superposition method is used in the dynamic analysis of the structures. However, since most of solution time is spent on calculating the eigenpairs of the system, the development of more efficient solution method is required. The purpose of this paper is to present the efficient solution method that combines the Robinson-Lee's method and accelerated Newton-Raphson method to improve numerical stability and increase convergence. Effectiveness of the proposed method is verified through numerical examples.

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A Study of Life about Naturally Aged Nitrocellulose by Storage (자연 노화된 니트로셀룰로오스의 수명에 관한 연구)

  • Kim, Dong-seong;Jin, Hong-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.595-601
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    • 2020
  • During the safety inspection of nitrocellulose-made explosive containers stored for more than 10 years, cracks were found in the containers. Therefore, a failure cause analysis test was performed. First, the cause of failure through the failure tree analysis was conducted to select the factors that influenced failure. The changes in the properties of the container caused by the acceleration of the reaction were found to be the cause of the failure by confirming the influence on the environment and internal/external factors that may occur during storage. To confirm this, environmental tests, such as thermal shock test and vacuum thermal stability test, were performed using a naturally aged container to analyze the cause of failure, and an accelerated aging test was performed to reproduce the failure. Through this, the chemical reaction was accelerated by heat and charge, as in the result of the fault tree analysis, and it was confirmed that the physical properties of the container were changed. In addition, the service life of the container was estimated using the Arrhenius model for the storage life due to thermal aging.