• Title/Summary/Keyword: accelerated curing

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Pore Structure and Fractal Characters of Cement Mortar Containing γ-C2S (γ-C2S 혼입 시멘트 모르타르의 공극구조 및 Fractal특성)

  • Chen, Zheng-Xin;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.24-25
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    • 2017
  • Gamma-C2S (γ-C2S) is a substance that is difficult to react with water under normal temperature but can absorb a large amount of CO2 in the air. The addition of γ-C2S to cementitious materials through the curing of CO2 can improve the pore structure and improve the durability of the material. In this study, three kind of Ca-bearing materials : CaO, Ca(OH)2, CaCO3, were calcined 2.5h at 1450℃ to synthesize γ-C2S after mixing with SiO2 respectively. Among them, Ca(OH)2 mixed with SiO2 after calcining shows highest content. Synthesized γ-C2S was added to the cement mortar, after water curing for 1 month, accelerated carbonation test was experimented. After 28d accelerated carbonation test, pore structure will be detectived by MIP. Based on the MIP result, following the calculation method of Fractal theory, the pore structure will be quantitative described.

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Physicochemical Properties of Cement Paste Containing Mg(OH)2 Cured by CO2 curing Method (CO2 양생을 이용한 Mg(OH)2 혼입 시멘트 페이스트의 물리화학적 특성)

  • Chen, Zheng-Xin;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.203-210
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    • 2018
  • Corrosion of the rebar is one of the main factors affecting the durability of reinforced concrete in the world which lead to the failure of the reinforced concrete structures. In this research, a new method of fixing $CO_2$ is practiced to improve the carbonation resistance of the concrete. Brucite($Mg(OH)_2$), a kind of common $CO_2$ fixation materials, was added into ordinary Portland cement paste. Samples containing 0%, 5%, 10%, and 15% $Mg(OH)_2$ were exposed to an accelerated carbonation curing regime with 20% concentration of $CO_2$, 60% relative humidity, and a temperature of $20^{\circ}C$ until tested at 3d, 7d, 14d and 28d. After 28d of $CO_2$ accelerated curing, in the paste containing $Mg(OH)_2$, magnesian calcite was detected by SEM-EDX. Meanwhile, the paste containing $Mg(OH)_2$ exhibit the better pore distribution than ordinary Portland cement paste and the compressive strength of the cement paste containing $Mg(OH)_2$ were more than 50Mpa.

Accelerated Degradation Test and Failure Analysis of Rapid Curing Epoxy Resin for Restoration of Cultural Heritage (문화재 복원용 속(速)경화형 Epoxy계 수지의 가속열화시험 및 고장분석 연구)

  • Nam, Byeong Jik;Jang, Sung Yoon
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.467-483
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    • 2017
  • In this study, the degradation properties by temperature stress of $Araldite^{(R)}$ rapid-curing epoxy resin used for inorganic cultural heritages, was identified. The tensile and tensile shear strength of durability decreased for 12,624 hours at temperatures of $40{\sim}60^{\circ}C$. In terms of stability of external stress and temperature, the slow-curing epoxy was superior to the rapid-curing epoxy, and cultural heritage conservation plans should therefore consider the strength and stress properties of restoration materials. Color differences increased for 12,624 hours at temperatures of $40{\sim}60^{\circ}C$, and glossiness decreased. Both color and gloss stability were weak, which necessitates the improvement of optical properties. Thermal properties (weight loss, decomposition temperature, and glass transition temperature) of adhesives are linked to mechanical properties. Interfacial properties of the adherend and water vapor transmission rates of adhesives are linked to performance variation. For porous media (ceramics, brick, and stone), isothermal and isohumid environments are important. For outdoor artifacts on display in museums, changes in physical properties by exposure to varying environmental conditions need to be minimized. These results can be used as baseline data in the study of the degradation velocity and lifetime prediction of rapid-curing epoxy resin for the restoration of cultural heritages.

Modeling of Compressive Strength Development of High-Early-Strength-Concrete at Different Curing Temperatures

  • Lee, Chadon;Lee, Songhee;Nguyen, Ngocchien
    • International Journal of Concrete Structures and Materials
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    • v.10 no.2
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    • pp.205-219
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    • 2016
  • High-early-strength-concrete (HESC) made of Type III cement reaches approximately 50-70 % of its design compressive strength in a day in ambient conditions. Experimental investigations were made in this study to observe the effects of temperature, curing time and concrete strength on the accelerated development of compressive strength in HESC. A total of 210 HESC cylinders of $100{\times}200mm$ were tested for different compressive strengths (30, 40 and 50 MPa) and different curing regimes (with maximum temperatures of 20, 30, 40, 50 and $60^{\circ}C$) at different equivalent ages (9, 12, 18, 24, 36, 100 and 168 h) From a series of regression analyses, a generalized rate-constant model was presented for the prediction of the compressive strength of HESC at an early age for its future application in precast prestressed units with savings in steam supply. The average and standard deviation of the ratios of the predictions to the test results were 0.97 and 0.22, respectively.

Curing Reaction and Physical Properties of Acrylic High-Solid Coatings (아크릴계 하이솔리드 도료의 경화반응과 도막물성)

  • Park, Hyong-Jin;Kim, Sung-Rae;Jung, Choong-Ho;An, Chong-Il;Park, Hong-Soo;Kim, Tae-Ok
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.261-272
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    • 2001
  • An ACR/HMMM film was prepared by blending high-solid ACR with curing agent, hexamethoxymethyl melamine (HMMM). An active curing reaction was observed at $170^{\circ}C$. The dynamic viscoelastic $T_{g}$ of the final film increased with the static viscoelastic $T_{g}$ of the film. The log damp value, which means a viscoelastic ratio, decreased with the increase in the curing temperature of the film. Physical properties of the films were within a suitable range for films, and by an accelerated weathering resistance test the films were proved weather resistible ones.

Physical Properties of Non-sintered Cement Mortar with Heat Treatment after Steam Curing (비소성 시멘트 모르타르의 증기양생 후 열처리에 따른 물리적 특성)

  • Na, Hyeong-Won;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.2
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    • pp.97-104
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    • 2021
  • This study aims to develop non-sintered cement that can replace the Portland cement by utilizing industrial by-products. As a suggestion, the physical properties of non-sintered cement mortar depending on the curing method were investigated with ground granulated blast furnace slag, class C fly ash, and class F fly ash. As a result of the study, it was found that the strength performance and absorption rate were improved through the heat treatment process after steam curing. It was confirmed through crystal phase analysis that the hydration was accelerated after heat treatment, and the bonding material formed a dense internal structure.

Effect of the Curing Temperature on Autogenous Shrinkage of the High Strength Mortar incorporating Mineral Admixtures (양생온도가 혼화재 치환 고강도 모르터의 응결 및 자기수축에 미치는 영향)

  • Han, Min-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.127-133
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    • 2012
  • In this paper, tests were carried out to monitor the effect of the curing temperature on autogenous shrinkage of the high strength cement mortar incorporating silica fume, blast furnace slag and fly ash ranged from 10%~30% by mass of cement. The curing temperatures were varied from $5^{\circ}C$ to $35^{\circ}C$, respectively. According to results, the setting time exhibited to delay with increase of admixture and drop of temperature. As for the effect of curing temperature on autogenous shrinkage, the increase of SF and BS resulted in an increase of autogenous shrinkage, while the use of FA decrease. The higher the curing temperature is, the greater the autogenous shrinkage is. This is due to the accelerated hydration rate of cement. It is found that the maturity does not consider the effect of curing temperature on autogenous shrinkage.

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A Study on the Properties of Epoxy Based Powder Coating with Various Curing Agents (에폭시 분체도료의 경화제 종류에 따른 물성에 관한 연구)

  • Park, Jae-Hong;Shin, Young-Jo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.58-65
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    • 1998
  • Substituted dicyandiamide(Sub-DICY), Accelerated dicyandiamide(Acc-DICY), Trimellitic anhydride(TMA), Pyromellitic dianhydride(PMDA) and Phenolic curing agent(Ph.C.A.) are mainly used for epoxy powder coating curing agent. Various characteristics of epoxy films fully cured by optimum condition such as mechanical properties like $T_g$, tensile strength, elongation at break hardness, abrasion resistance and chemical properties like water absorption, acid resistance, alkali resistance and electrical properties, corrosion resistance are determined by various measuring devices and analyses devices. In conclusion, phenolic curing agent was shown excellent thoughness but severe color change as temperature increased. Acid anhydride has excellent insulation properties and color stability at elevated temperature but lower thoughness and adhesion to substrate. DICY curing agent was shown high water absorption and severe color chance as temperature increased.

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Characteristics of Carbon Capture by the Accelerated Carbonation Method of Circulating Fluidized Bed Combustion Ash (순환 유동층 보일러 애시의 촉진탄산화에 의한 탄소포집 특성)

  • Choi, Young-Cheol;Yoo, Sung-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.165-172
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    • 2021
  • The purpose of this study is to investigate the carbon capture capacity of various inorganic materials. For this purpose, the change in property of ordinary Portland cement (OPC), blast furnace slag fine powder (GGBS), and circulating fluidized bed boiler ash (CFBC) due to carbonation were analyzed. Carbonation curing was performed on all specimens through the accelerated carbonation experiment, and the amount of carbon capture was quantitatively analyzed by thermogravimetric analysis according to the age of carbonation. From the results, it is confirmed that the carbon capture capacity was shown in all specimens. The carbon capture amount was shown in the order of CFBC, OPC, and GGBS. The 28-day carbon capture of CFBC, OPC, and GGBS was 3.9%, 1.3%, and 9.4%, respectively. Carbon capture reaction occurred rapidly at the beginning of carbonation, and occurred slowly with increasing age. SEM image analysis revealed that an additional product generated by carbonation curing in all specimens was calcium carbonate.

Studies on the Pretreatment Effect of Ginger on Long-term Storage (생강의 저장 전처리 효과에 관한 연구)

  • Chung, Tae-Yon;Lee, Se-Eun;Jeong, Mun-Cheol;Kim, Dong-Chul
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.458-463
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    • 1996
  • Fresh ginger harvested in Seosan, Choongchengnam-do, was used to investigate the pretreatment effect before long-term storage. Wounded ginger were cured at the temperature of 25, 30, $35^{\circ}C$ and the RH 83 and 93% for 1, 3, 5, 7 days, respectively Then the cured ginger were stored in the laboratory scale storage room ($12^{\circ}C,$ 95% RH) in order to find out the optimum curing condition. At a constant temperature and a RH. the longer ginger were cured, the more their weight was decreased; at a constant temperature and a curing period, the higher RH was, the less weight was lost. During the curing process, sprouting rate was accelerated at temperature higher than $30^{\circ}C$ and humidity higher than 90%; mold growing was observed at any temperature and humidity, but especially at $35^{\circ}C$ the rate was relatively faster when the curing time was increased. Hardness of wound surface cured at 93% RH was relatively higher than those cured at 83% RH at all temperatures. The weight loss of store ginger after curing was $2.0{\sim}8.2$ after 30 days and $7.2{\sim}14.2%$ after 60 days storage. Compared with all results through a screening procedure, the condition of 3-days curing at $25^{\circ}C$ and 93% RH showed th best result for minimizing quality changes during storage.

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