• Title/Summary/Keyword: accelerated corrosion

Search Result 450, Processing Time 0.025 seconds

Characteristics of surface damage with applied current density and cavitation time variables for 431 stainless steel in seawater (431 스테인리스강의 해수 내 적용 전류밀도 및 캐비테이션 시간 변수에 따른 표면손상 특성)

  • Kim, Seong-Jong;Chong, Sang-Ok
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.38 no.7
    • /
    • pp.883-889
    • /
    • 2014
  • It is generated for cavitation erosion due to the local static boiling by pressure differentials in high speed rotating fluid environment. The cavitation is influenced by various elements such as pressure, velocity, temperature, pH of fluid and medium. In particular, the damage of material is accelerated due to the electrochemical corrosion by $C1^-$ and cavitation erosion due to cavities in seawater. In this paper, hence, it investigated for martensite stainless steel the damage behavior with applied current density and cavitation time in natural seawater solution. Less damage depth at the cavitation condition was observed than static condition as a result of galvanostatic experiment. Furthermore, it was shown that dramatic increase of weightloss, damage rate and damage depth after 3 hour of cavitation test.

Relationship Between Local Wall Thinning and Velocity Components of Deflected Turbulent Flow Inside the Tee Sections of Carbon Steel Piping (탄소강 배관 티에서 편향 난류유동에 따른 속도성분과 국부감육의 상관관계)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Kang, Deok-Won
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.35 no.7
    • /
    • pp.717-722
    • /
    • 2011
  • The aim of this study is to identify the locations at which local wall thinning occurs and to determine the turbulence coefficients related to local wall thinning. Experiments and numerical analyses of the tee sections of different down-scaled piping components were performed and the results were compared. Numerical analyses of full-scale models of actual plants were performed in order to simulate the flow behaviors inside the piping components. In order to determine the relationship between the turbulence coefficients and the rate of local wall thinning, numerical analyses of the tee components in the main feedwater systems were performed. The turbulence coefficients obtained from the numerical analyses were compared with the local wear rate obtained from the measurement data. From the comparison of the results, the vertical flow velocity component (Vr) flowing to the wall after separating in the wall due to the geometrical configuration and colliding with the wall directly at an angle of some degree was analogous to the configuration of local wall thinning.

A Study on Characteristics of pH Control with Amines in the Secondary Side of Nuclear Power Plants (원전 2차 계통에서 아민의 pH 제어 특성 연구)

  • Rhee, In-H.;Ahn, Hyun-Kyoung;Park, Byung-Gi;Jun, Gwon-Hyuk;Ho, Song-Chan
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.11 no.8
    • /
    • pp.3112-3118
    • /
    • 2010
  • The pH control agent in PWRs, to insure the integrity of steam generator, was changed from ammonia to ethanolamine(ETA) which decreased pH at condensate system and low pressure feedwater heater drain system, so that several amines were investigated for the selection of the optimum amine. There was no single alternative amine to meet the optimum condition. The more volatile ammonia provides the higher pH in condensate, while the less volatile ETA increases the pH in wet steam area. Thus, the combined amine of ammonia and ETA is able to equally raise the pH in both region so that the flow accelerated corrosion be reduced in the every system of the secondary side and the integrity of steam generator be also improved in pressurized water reactors (PWRs).

The advancing techniques and sputtering effects of oxide films fabricated by Stationary Plasma Thruster (SPT) with Ar and $O_2$ gases

  • Jung Cho;Yury Ermakov;Yoon, Ki-Hyun;Koh, Seok-Keun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 1999.07a
    • /
    • pp.216-216
    • /
    • 1999
  • The usage of a stationary plasma thruster (SPT) ion source, invented previously for space application in Russia, in experiments with surface modifications and film deposition systems is reported here. Plasma in the SPT is formed and accelerated in electric discharge taking place in the crossed axial electric and radial magnetic fields. Brief description of the construction of specific model of SPT used in the experiments is presented. With gas flow rate 39ml/min, ion current distributions at several distances from the source are obtained. These was equal to 1~3 mA/$\textrm{cm}^2$ within an ion beam ejection angle of $\pm$20$^{\circ}$with discharge voltage 160V for Ar as a working gas. Such an extremely high ion current density allows us to obtain the Ti metal films with deposition rate of $\AA$/sec by sputtering of Ti target. It is shown a possibility of using of reactive gases in SPT (O2 and N2) along with high purity inert gases used for cathode to prevent the latter contamination. It is shown the SPT can be operated at the discharge and accelerating boltages up to 600V. The results of presented experiments show high promises of the SPT in sputtering and surface modification systems for deposition of oxide thin films on Si or polymer substrates for semiconductor devices, optical coatings and metal corrosion barrier layers. Also, we have been tried to establish in application of the modeling expertise gained in electric and ionic propulsion to permit numerical simulation of additional processing systems. In this mechanism, it will be compared with conventional DC sputtering for film microstructure, chemical composition and crystallographic considerations.

  • PDF

Behavior of Elastic and Plastic Limit Loads of Thinned Elbows Observed During Real-Scale Failure Test Under Combined Load (감육엘보 실증실험에서의 탄성 및 소성 한계하중 거동 고찰)

  • Lee, Sung-Ho;Lee, Jeong-Keun;Park, Chi-Yong
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.34 no.9
    • /
    • pp.1293-1298
    • /
    • 2010
  • In most power plants, wall thinning in carbon-steel pipes due to flow-accelerated corrosion is one of the major aging phenomena, and it reduces the load-carrying capacity of the piping system. Various types of wall-thinning defects were manufactured in real-scale elbows, and monotonic in-plane bending tests were performed under internal pressure to evaluate the failure behavior of the elbows. In this paper, the behavior of elastic and plastic limit leads of locally thinned elbows in a real-scale failure test is presented. The loads determined on the basis of TES (twice elastic slope) were considered to be the limit loads of locally thinned elbows so that the integrity of the thinned elbows could be maintained, even when a small amount of plastic deformation might have occurred.

Effect of Strain Aging on the Tensile Properties of an API X70 Linepipe Steel (API X70 라인파이프강의 인장 특성에 미치는 변형 시효의 영향)

  • Lee, Seung-Wan;Lee, Sang-In;Hwang, Byoungchul
    • Korean Journal of Materials Research
    • /
    • v.27 no.10
    • /
    • pp.524-529
    • /
    • 2017
  • The effect of strain aging on the tensile properties of API X70 linepipe steel was investigated in this study. The API X70 linepipe steel was fabricated by controlled rolling and accelerated cooling processes, and the microstructure was analyzed using optical and scanning electron microscopes and electron backscatter diffraction. Strain aging tests consisting of 1 % pre-strain and thermal aging at $200^{\circ}C$ and $250^{\circ}C$ were conducted to simulate U-forming, O-forming, Expansion(UOE) pipe forming and anti-corrosion coating processes. The API X70 linepipe steel was composed of polygonal ferrite, acicular ferrite, granular bainite, and bainitic ferrite whose volume fraction was dependent on the chemical composition and process conditions. As the thermal aging temperature increased, the steel specimens showed more clearly discontinuous type yielding behavior in the tensile stress-strain curve due to the formation of a Cottrell atmosphere. After pre-strain and thermal aging, the yield and tensile strengths increased and the yield-to-tensile strength ratio decreased because yielding and aging behaviors significantly affected work hardening. On the other hand, uniform and total elongations decreased after pre-strain and thermal aging since dislocation gliding was restricted by increased dislocation density after a 1 % pre-strain.

Evaluation of Bioactivity of Ti-6Al-7Nb Alloys with Various Hydrothermal Treatment Times (열수처리 시간에 따른 Ti-6Al-7Nh 합금의 생체활성 평가)

  • Kwon O. S.;Choi S. K.;Park K. B.;Lee M. H.;Bae T. S.;Lee O. Y.
    • Korean Journal of Materials Research
    • /
    • v.14 no.12
    • /
    • pp.876-884
    • /
    • 2004
  • This study was to investigate whether the bioactivity of the anodized and hydrothermally treated Ti-6Al-7Nb alloy were affected by the time of hydrothermal treatment. Anodizing was performed at current density 30 $mA/cm^2$ up to 300 V in electrolyte solutions containing $DL-{\alpha}-glycerophosphate$ disodium salt hydrate $(DL-{\alpha}-GP)$ and calcium acetate (CA). Hydrothermal treatment was done at $300^{\circ}C$ for 30 min, 1 hr, 2 hrs, and 4 hrs to produce a thin film layer of hydroxyapatite (HA). The bioactivity was evaluated from HA formation on the surfaces in a Hanks' solution with pH 7.4 at $36.5^{\circ}C$ for 10, 20, and 30 days. Anodic oxide films were porous with pore size of $1\sim4{\mu}m\;and\;3\sim4{\mu}m$ thickness. The anodic oxide films composed with strong anatase peak with presence of rutile peak, and showed the increase in intensity of anatase peak after hydrothermal treatment. It was shown that the intensity of anatase peak increased with increasing the time of hydrothermal treatment but was no difference in rutile peak. The corrosion voltage was the highest in the group of hydrothermal treatment for 2 hrs (Ecorr: -338.6 mV). The bioactivity in Hank's solution was accelerated with increasing the time of hydrothermal treatment.

Chloride Diffusion Coefficients in Cold Joint Concrete with GGBFS (고로슬래그 미분말을 혼입한 콜드조인트 콘크리트의 염화물 확산계수)

  • Oh, Kyeong-Seok;Mun, Jin-Man;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.20 no.5
    • /
    • pp.44-49
    • /
    • 2016
  • Among the deteriorating agents, chloride ion is reported to be one of the most harmful ions due to its rapid diffusion and direct effect on steel corrosion. Cold joint which occurs in mass concrete placing is vulnerable to shear resistance and more severe deterioration. The paper presents an quantitative evaluation of chloride diffusion coefficient in OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag) concrete containing cold joint. GGBFS concrete shows $6.6{\times}10^{-12}m^2/sec$ which is almost 30% level of OPC concrete results and the trend is repeated in the case of cold joint concrete. Compared with OPC concrete, GGBFS concrete is evaluated to have better resistance to chloride penetration, showing 0.30 times of chloride diffusion coefficient in concrete without cold joint 0.39 times with cold joint, respectively.

Probabilistic Estimation of Service Life of Box Culvert for Power Transmission Considering Carbonation and Crack Effect (탄산화와 균열을 고려한 전력구 콘크리트 구조물의 확률론적 수명 예측)

  • Woo, Sang-Kyun;Lee, Yun
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.18 no.6
    • /
    • pp.30-40
    • /
    • 2014
  • The demand of underground structure such as box culvert for electric power transmission is increasing more and more, and the service life extension of these structures is very important. Recent observations in field and experimental evidences show that even steel in concrete can be corroded by carbonation reaction of cover concrete. Carbonation-induced corrosion in concrete may often occur in a high carbon dioxide environment. In this study, the risk of carbonation of box culverts in our nation was evaluated by measuring the carbonation rate and concrete cover depth in field. Then, the service life due to carbonation at the cover depth was calculated by in situ information and the Monte Carlo simulation in a probabilistic way. Additionally, the accelerated carbonation test for the cracked beam specimen was executed and the crack effect owing to the carbonation process on the service life of box culvert was numerically investigated via Monte Carlo simulation based on the experimental results.

An Experiemtnal Study on the Air Permeability Effect on Concrete Carbonation (콘크리트의 중성화에 영향을 미치는 투기성에 관한 실험적 연구)

  • 권영진;김무한;강석표;유재강
    • Journal of the Korea Concrete Institute
    • /
    • v.13 no.3
    • /
    • pp.277-284
    • /
    • 2001
  • Hardened concrete contains pores of varying types and sizes, and therefore the transport of air through concrete can be considered. The rate of permeability will not only depends on the continuity of pores, but also on the moisture contents in concrete and finishing material on concrete. Also it knows that the durability of reinforced concrete structure is concerned with air permeability which effects on the carbonation occurred by invasion of CO2 gas and the corrosion of steel bar occurred by O$_2$. In this paper, the effects of curing conditions and finishing materials on carbonation and air permeability are investigated according to the accelerated carbonation test. As results, carbonation velocity and air permeability are effected by curing conditions and finishing materials, and air permeability coefficient is effected by moisture content. Also the relationship between carbonation velocity coefficients and air permeability coefficients has been quite well established.