• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2000년도 춘계학술발표대회
• /
• pp.572-575
• /
• 2000

The highly efficient photoelectric conversion of chlorophyll a (Chl a) monolayers and multilayers was investigated. Using the Langmuir-Blodgett (LB) technique, Chl a monolayers and multilayers were fabricated onto optically transparent electrode, such as ITO glass. The photocurrent could be observed according to the light illumination. The action spectrum of the Chl a LB films was well consistent with its absorption spectrum. The possible application of the proposed system as a constituent of the artificial color recognition device was suggested.

• 한국의학물리학회지:의학물리
• /
• 제4권2호
• /
• pp.37-47
• /
• 1993

Jones 모델 및 HKB모델을 이용하여 Laplace transform방법으로 6MV X-ray의 대략적인 에너지 스펙트럼을 분석하였다. Jones모델은 투과계수 0.1이하에서는 Laplace transform방법이 적용될 수 없는 심한 제약을 받는다는 것을 알 수 있었다. HKB모델에 의한 에너지 스펙트럼은 대체로 실제의 에너지 스펙트럼과 일치하는 형태를 나타내지만 6MeV에너지 이상의 영역에서 길게 꼬리를 이루는 단점이 있었다.

• Bulletin of the Korean Chemical Society
• /
• 제35권10호
• /
• pp.3015-3020
• /
• 2014

The behavior of benzo[a]pyrene-7,8-dione (BPQ) in aqueous solution and its interaction with native DNA was investigated using conventional absorption and linear dichroism (LD) spectroscopy. The appearance of a broad absorption maximum at long wavelengths and its proportional relationship to solvent polarizability suggested that BPQ adopts a aggregated state for all solutions examined. Disappearance of this absorption band at higher temperatures in aqueous solution also supported BPQ aggregation. When associated with DNA absorption spectral properties were essentially the same as that in aqueous solution. However, two isosbestic wavelengths were found in the concentration-dependent absorption spectrum of the BPQ-DNA complex, suggesting the presence of at least two or more DNA-bound BPQ species. Both species produced $LD^r$ spectra whose magnitude in BPQ absorption region is larger or comparable to that in the DNA absorption region, suggesting that the molecular BPQ plane is near perpendicular relative to the local DNA helical axis. Therefore, BPQ molecules are aligned along the DNA stem in both DNA-aggregated BPQ species.

• ETRI Journal
• /
• 제24권3호
• /
• pp.221-225
• /
• 2002

We performed nonlinear transmission measurements and quantum-chemical calculations on dithienothiophene(DTT)-based molecules to gain insight into the effect of acceptor and donor groups on two-photon absorption(TPA) properties. The TPA intensity showed dispersion characteristics of the single-photon absorption spectrum. When the molecules included an asymmetric donor-acceptor pair, the single- and two-photon absorption maximum wavelengths were red-shifted more than when the molecules had a symmetric donor-donor structure. We interpreted this result as indicating that the $S_2$ state plays the dominating role in the absorption process of molecules with a symmetric structure. The experimental TPA ${\delta}$ values at the absorption peak wavelength showed a dependence on the structural variations. We found the self-consistent force-field theory and Hartree-Fock Hamiltonian with single configuration interaction formalism to be valid for evaluating TPA ${\delta}$. Although the quantum-chemical calculations slightly underestimated the experimental ${\delta}$ values obtained from nonlinear trans -mission measurements, they reasonably predicted the dependence of the ${\delta}$ value on the structural variations. We confirmed the role of molecular symmetry by observing that donor-donor substituted structure gave the highest experimental and theoretical TPA ${\delta}$ values and that the donor-acceptor substituted structure showed a greater red-shift in the TPA absorption maximum wavelength. Overall, the theoretical ${\delta}$ values of DTT-based molecules were in the order of $10^{-46}\;cm^4{\cdot}s{\cdot}photon^{-1}$ and are higher than that of AF-50 by nearly two orders of magnitude.

• 한국음향학회:학술대회논문집
• /
• 한국음향학회 1984년도 추계학술발표회 논문집
• /
• pp.33-35
• /
• 1984

A new type single beam photoacoustic spectrometer suitable for measuring optical absorption of condensed powder matter with the automatic calibration capability of a source power spectrum is introduced. The signal processing until of this spectrometer consists of a photoacoustic cell a lock-in amp., a switching circuit and a personal computer. The measured optical absorption spectra of a few material by this method are good agreement with the results obtained by the double-beam photoacoustic spectrometer.

• 한국전산구조공학회:학술대회논문집
• /
• 한국전산구조공학회 1997년도 가을 학술발표회 논문집
• /
• pp.231-238
• /
• 1997

Many methods have been proposed for achieving optimum performance of structures subjected to earthquake excitation. The conventional approach requires that structures passively resist earthquakes through a combination of strength, deformability, and energy absorption. Base isolation is a technique for mitigating the effects of earthquakes on structures through the introduction of flexibility and energy absorption capability. In this paper, a parametric study of effectiveness of isolation systems with various main structures' properties is carried out through the response spectrum analysis. It is shown that, most base isolators with its longer period and higher damping can significantly reduce the base shear force transmitted to the structures.

• 한국진공학회지
• /
• 제5권1호
• /
• pp.33-38
• /
• 1996

The induced linewidth, frequency shift and absorption spectrum for a molecular dipole in the vicinity of a phase -conjugate mirror have been investgated within a classical phenomenological model, with particularreference to the technique of optical phase conjugation by a surface. While the shifts and the widths show similar characteristics as those obtained recently by Bochove who considered the problem within the context of four-wave mixing, the results obtained in the present model can be defined uniquely with the possibility of an infinite lifetime for the excited admolecule . Furthermore, the absorption lineshape obtained here some interesting features which depend on both the magnitude and the phase of the complex reflectivity of the mirror.

• Bulletin of the Korean Chemical Society
• /
• 제28권12호
• /
• pp.2382-2388
• /
• 2007

A series of dimethine cyanine dyes were synthesized in a fast, efficient and high yield by the condensation of quaternary salts with 1H-indole-3-carbaldehyde in the presence of piperidine under solvent-free microwave irradiation. The products were identified by 1H NMR, IR, UV-Vis spectra and elemental analysis. The absorption and fluorescence properties of these dyes were investigated both experimentally and theoretically. Calculations performed at a combination of time-dependent density functional theory (TD-DFT) and the polarizable continuum model (PCM) reproduced the π-π* type absorption bands of the dyes. Regression analysis was used for studying theoretical results of the absorption maxima in different solvents. Compared with experimental counterparts, estimated overall uncertainties in the absorption maxima were about ±2%.

• Bulletin of the Korean Chemical Society
• /
• 제32권2호
• /
• pp.439-443
• /
• 2011

Using the projection operator technique, a reduced density matrix theory for linear absorption spectrum of energy transfer systems is developed for the theoretical absorption line shape of the systems with non-Condon transitions. As an application, we considered a model system of OH vibrations of water. In the present model calculation, the OH vibration modes are coupled to each other via intra-molecular coupling mechanism while their intermolecular couplings are turned off. The time-correlation functions appearing in the formulation are calculated from a mixed quantum/classical mechanics method. The present theory is successful in reproducing the exact absorption line shape. Also the present theory was improved from an existing approximate theory, time-averaged approximation approach.

• Bulletin of the Korean Chemical Society
• /
• 제14권1호
• /
• pp.118-122
• /
• 1993

The 77 K luminescence and excitation spectra, room-temperature FT-infrared and visible absorption spectra of a newly prepared complex cis-[Cr(cyclam)(pn)]$(ClO_4)_3$, where cyclam and pn represent 1,4,8,11-tetraazacyclotetradecane and 1,2-propanediamine respectively, have been measured. Absorption maximum of the first spin-allowed transition in the electronic absorption spectra of cis-[Cr(cyclam)(pn)]$^{3+}$ and cis-[Cr(cyclam)(en)]$^{3+}$ appears at nearly the same position. The two spin-allowed and six spin-forbidden electronic transitions are assigned from the visible absorption and excitation spectra. It is also shown that the zero phonon line in the excitation spectrum splits into two components by 50 cm$^{-1}$.