• 콘크리트학회논문집
• /
• 제18권6호
• /
• pp.785-791
• /
• 2006

본 연구에서는 스틸렌(styrene)과 부틸아크릴레이트(butyl acrylate)를 모노머 비에 따라 합성 제조하고, 합성 제조 된 시멘트 혼화용 폴리머를 혼입한 폴리머 시멘트 모르타르의 물리적 성질과 내구성에 대한 특성을 보통 시멘트 모르타르와 기존에 생산되어 현장에 적용되고 있는 St/BA계 폴리머 시멘트 모르타르를 비교 분석하고자 하였다. 실험 결과, St/BA의 모노머 비가 50:50, 60:40일 경우에는 시멘트 혼화용으로 사용하기에 가장 적합하였으며, 세공용적의 분포나 강도 특성에서도 우수한 결과를 나타냈다. 또한 방수성능과 염화물 이온에 대한 침투 저항성도 St/BA의 모노머비가 증가할수록, 폴리머 시멘트 비가 증가할수록 증진 효과가 우수한 결과를 나타냈다. 따라서 본 연구를 통해 합성제조된 St/BA 라텍스를 시멘트 모르타르에 혼입할 경우 우수한 성능개선 효과를 얻을 수 있었다.

• 한국수소및신에너지학회논문집
• /
• 제27권3호
• /
• pp.318-327
• /
• 2016

In order to improve the performance of temperature field measurements by CT-TDLAS (Computer Tomography Tunable Diode Laser Absorption Spectroscopy), a new reconstruction algorithm, named two-ratios-of-three-peaks method is proposed in this paper. Further, two methods for selecting appropriate initial values of the iterative calculation of CT-TDLAS are proposed. One is MLOS (multiplicative line of sight) method and the other one is ALOS (additive line of sight) method. Two-ratios-of-three-peaks (2R3P) algorithm combined with MART (multiplicative algebraic reconstruction technique) is finally developed for the enhancements of reconstructive calculations. The results have been compared with those obtained by the conventional one-ratio-of-two-peaks (1R2P) algorithm. In order to evaluate the performance of this algorithm, numerical test has been performed using phantom Gaussian temperature distributions with $11{\times}11$ square mesh. The performance of the constructed algorithm has been demonstrated by comparing the results obtained in actual burner experiments with those obtained by thermocouples. It has been verified that 2R3P algorithm with MART and MLOS showed best performance than that of 1R2P algorithm.

• Journal of the Korean Wood Science and Technology
• /
• 제21권2호
• /
• pp.57-65
• /
• 1993

The aim of this research was to manufacture sludge-particle board using paper sludge with wood particle and to investigate physical and mechanical properties of various sludge-particle boards, fabricated with ratios of sludge to particle of 10 to 90, 20 to 80, 30 to 70, 40 to 60 and 50 to 50(oven dry weight based). Sludge-particle boards were manufactured by urea-formaldehyde resin, 0.8 target specific gravity, and 10mm thickness. It was possible to manufacture sludge-particle board as the same processing in the present particleboard manufacturing system. This sludge-particle board have different properties as composition ratios of sludge and particle. And sludge-particle board made from 10 percent to 20 percent of sludge mixing ratio have similar mechanical properties compared with control particleboard. Especially, the sludge-particle board made from 10 percent to 40 percent mixing ratios of sludge have superior to control particleboard in internal bond, screw withdrawal holding strength and modulus of elasticity. In the case of dimensional stability, water absorption was increased and thickness swelling was decreased as increased with sludge mixing proportion. The sludge-particle board made of different mixing ratios of our laboratory design was able to concluded that there is possibility of partial substitution of wood particle materials.

• Journal of Pharmaceutical Investigation
• /
• 제24권2호
• /
• pp.95-104
• /
• 1994

Inclusion complexes of ketoconazole(KT) with ${\alpha}^_$, ${\beta}^_$cyclodextrin(CD) and $dimethy1-{\beta}-cyclodextrin$ (CD) and $dimethy1-{\beta}-cyclodextrin(DM{\beta}CD)$ as nasal absorption enhancer were prepared in 1: 2 molar ratios by freeze-drying and solvent evaporation methods. In order to compare with the intrinsic absorptivity of KT in the jejunum(J) and the nasal cavity(N), the in situ simultaneous perfusion method was employed. The in situ recirculation study revealed that KT-CD inclusion complexes with the greater stability constant and the faster dissolution rate proportionally increased the absorption of KT in the J and N of rats. The rank order of apparent KT permeability$(P_{app}\;:\;cm/sec\;{\time}\;1O^{-5}{\pm}S.E.)$, corrected by surface area of absorption, was $5.10{\pm}0.3(N,\; KT-DM{\beta}CD)$ )> $4.13{\pm}0.4(N,\;KT-{\beta}-CD)$ )> $3.52{\pm}0.2(N,\;KT-{\alpha}-CD)$ )> $2.76{\pm}0.3(J,\; KT-DM{\beta}CD)$ )> $2.61{\pm}0.5(J,\;KT-{\beta}-CD)$ )> $2.42{\pm}0.4(J,\;KT-{\alpha}-CD)$ at pH 4.0. The in crease in permeability of $KT-DM{\beta}CD$ inclusion complex was 2.6 folds in the J and 4.5 folds in the N when the perfusing solution was changed from the buffer(pH 4.0) to saline. The absorption rate of $KT-DM{\beta}CD$ inclusion complex after nasal administration was more rapid than those of ketoconazole alone and $KT-DM{\beta}CD$ inclusion complex after oral administration to rats. In comparision with an oral administration of ketoconazole suspension in corn oil, the relative bioavailability was calculated 137.3% for the oral and 195.0% for nasal $KT-DM{\beta}CD$ inclusion complex in rats. The present results suggest that $KT-DM{\beta}CD$ inclusion complex may serve as a potential nasal absorption enhancer for the nasal delivery of ketoconazole.

• 공업화학
• /
• 제22권5호
• /
• pp.501-507
• /
• 2011

친환경 복합단열재를 개발하기 위하여 천연섬유질과 다공성 세라믹볼을 심재로, 활성황토를 결합재로 사용하였다. 물/결합재비 및 심재/결합재비를 다양하게 변화시켜 공시체를 제작하였으며, 공시체의 제 물성을 조사하기 위하여 압축강도, 휨강도, 흡수성, 내열수성, 세공분석, 열전도율 및 SEM에 의한 미세조직 관찰을 실시하였다. 그 결과 최대 압축강도는 물/결합재비와 심재/결합재비에 따라 다양하게 나타났으나 휨강도는 심재/결합재비가 증가될수록 물/결합재비에 관계없이 높게 나타났다. 내열수성시험 후에 측정한 압축 및 휨강도는 내열수성시험 전에 측정한 값에 비하여 압축 및 휨강도 모두 현저하게 저하되었다. 내열수성시험 후에 측정한 세공분석에서 결합재의 수화반응이 촉진됨으로서 세공의 평균직경, 총세공량 및 공극률은 감소되었으나 밀도는 증가되었다. 열전도율은 심재/결합재비가 증가될수록 낮아졌다. 복합단열재의 단열성과 기계적강도가 우수하여 실용화에 문제가 없는 것으로 평가되었다.

• Food Science and Biotechnology
• /
• 제17권3호
• /
• pp.564-568
• /
• 2008

The effects of sodium copper chlorophyllin (SCC) on bioaccessibility and uptake of mercury from fish were investigated using an in vitro digestion coupled with a Caco-2 cell. Fish along with SCC was subjected to a simulated in vitro digestion, which simulates both the gastric and small intestinal phase in vivo. Mercury bioaccessibility, the amount of mercury released from fish to aqueous phase following a digestion, was measured. Various amounts of SCC (0.1-25 mg) significantly reduced mercury bioaccessibility in a dose dependent manner by 49-89% compared to the negative control (fish without SCC) (p<0.05). Mercury bioaccessibility in varying molar ratios of mercury to positive control, 2,3-dimercapto-1-propane sulfonate (DMPS) was between 24 and 52%. Mercury uptake by Caco-2 cells from test media containing aqueous phase following in vitro digestion was measured after 6 hr incubation at $37^{\circ}C$. Cellular mercury uptake with increasing amount of SCC ranged from 0.352 to $0.052\;{\mu}g$ mercury/mg protein, while those in DMPS treatment were between 0.14 and $0.27\;{\mu}g$ mercury/mg protein. Our study suggests that SCC can reduce mercury absorption following fish consumption and may be efficient as a synthetic chelating agent for long term chronic mercury exposure in fish eating populations.

• Bulletin of the Korean Chemical Society
• /
• 제33권2호
• /
• pp.393-397
• /
• 2012

We report a new route to synthesize high quality zinc blende CdS and ZnS nanocrystals in noncoordinating solvent 1-octadecene, using dodecanethiol (DDT) molecules as both the sulfur source and surface capping ligands. Different reaction temperatures and Cd(Zn)/DDT molar ratios were tested to optimize the synthesis conditions. Absorption photoluminescence (PL) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) pattern, and transmission electron microscopy (TEM) were used to characterize assynthesized nanocrystals. The narrow half width at the half-maximum on the long wavelength side of the firstexcitonic absorption peak and TEM images demonstrated nearly monodisperse size distributions of asprepared CdS, ZnS, and CdS/ZnS core/shell nanocrystals. Only trap emissions of the nanocrystals were detected when the amount of DDT was excessive, this came from the strong quenching effect of thiol groups on the nanocrystal surfaces. After overcoating with ZnS shells, band-gap emissions of CdS nanocrystals were partially recovered.

• Journal of electromagnetic engineering and science
• /
• 제8권2호
• /
• pp.70-75
• /
• 2008

In this paper, the EM wave absorber was designed and fabricated for countermeasure against EMI from a ceiling of a tollgate in ETC system. We fabricated several samples in different composition ratios of MnZn-ferrite, Carbon, and CPE(Chlorinated Polyethylene). Absorption abilities were simulated in accordance with different thicknesses of the prepared absorbers and changed complex relative permittivity and permeability according to composition ratio. The optimized mixing ratio of MnZn-ferrite, Carbon, and CPE was found as 40:15:45 wt.% by experiments and simulation. Then the EM wave absorber was fabricated and tested using the simulated data. As a result, the developed EM wave absorber has the thickness of 3.3 mm and absorption ability was more than 20 dB in the case of normal incidence and more than 11 dB for the incident angle from 15 to 45 degrees at 5.8 GHz. Therefore, it was confirmed that the newly developed absorber can be used for ETC system.

• 한국농공학회지
• /
• 제31권3호
• /
• pp.81-91
• /
• 1989

The aims of this study were to determine mechanical properties of steel-fiber reinforced concrete under splitting tensile, flexural and compressive loading, and thus to improve the possible applications of concrete. The major factors experimentally investigated in this study were the fiber content and the length and the diameter of fibers. The major results obtained are summarized as follows : 1.The strength, strain, elastic modulus and energy obsorption capability of steel-fiber reinforced concrete under splitting tensile loading were significantly improved by increasing the fiber content or the aspect ratio. 2.The flexural strength, central deflection, and flexural toughness of steel4iber reinforced beams were significantly improved by increasing the fiber content or the aspect ratio. And flexural behavior characteristic was good at the aspect ratio of about 60 to 75. 3.The strength, strain, and energy absorption capability in compression were increased with the increase of the fiber content. These effects were not so sensitive to the aspect ratio. The energy absorption capability was improved only slightly with the increase of the fiber length. 4.The elastic modulus, transverse strains, and poisson's ratios in compression were not influenced by the fiber content. 5.The steel-fibers were considered to be appropriated as the materials covering the weakness of concrete because the mechanical properties of concrete in tension and flexure were significantly improved by steel-fiber reinforcement.

• 한국강구조학회 논문집
• /
• 제20권2호
• /
• pp.215-226
• /
• 2008

강관이 삽입된 강합성 중공 기둥의 내진 성능 평가 실험을 수행하였다. 준정적 실험을 통하여 강합성 중공 기둥과 일반 중실 RC기둥의 내진 성능을 비교 평가 하였다. 각각의 기둥 시험체에 대해 최대 하중과 변위의 관계를 측정하였으며, 이를 바탕으로 연성도, 소산에너지, 등가 감쇠비, 손상 지수가 계산되었다. 실험 결과 강합성 중공 기둥은 중실 RC 기둥에 비해 약 2배의 모멘트에 저항을 하였으며, 에너지의 흡수와 소산에서도 2배 정도의 성능을 보여주어, 강합성 중공 기둥의 우수한 성능을 확인하였다.