• 제목/요약/키워드: a.c. impedance

검색결과 713건 처리시간 0.032초

임피던스 측정에 의한 혼합재를 포함한 포틀랜드 시멘트의 수화 (Hydration of Portland Cement Containing Blending Components by Impedance Spectroscopy)

  • 송종택;김훈상;배승훈
    • 한국세라믹학회지
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    • 제39권6호
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    • pp.540-549
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    • 2002
  • 본 실험에서는 Impedance Spectroscopy(IS)를 이용하여 플라이 애쉬, 고로 슬래그, 실리카 퓸 등의 혼합재가 치환 첨가된 포틀랜드 시멘트의 수화거동을 검토하였다. 플라이 애쉬 및 고로 슬래그가 시멘트에 치환 첨가될 경우, 수화 초기 IS 의 전기적 변수, $R_{t(s+1)}$$R_{t(s+1)}$의 증가폭이 감소하였다. 이것은 동일한 W/C비에서 혼합재를 포함한 시멘트의 수화가 늦게 진행되고 있음을 보여준다. 그러나, 실리카 퓸의 경우 초기에 매우 빠른 포졸란 반응성으로 인하여 플라이 애쉬 및 고로 슬래그가 첨가된 경우에 비해 큰 폭의 $R_{t(s+1)}$$R_{t(s+1)}$ 변화를 확인 할 수 있었다. OPC-플라이 애쉬계의 경우 반원과 직선 영역 사이에서 특이 할만한 평할한 곡선 영역이 출현하였으며, 수화가 진행되고 플라이 애쉬의 치환첨가량이 증가할수록 그 영역이 증가하였다.

포스포늄 염을 포함한 폴리스티렌 공중합체의 감습 성질 (Humidity Sensitive Properties of Copolymers of Polystyrene Contains Phosphonium Salts)

  • Paek, Jee-Seon;Gong, Myoung-Seon
    • 한국재료학회지
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    • 제5권6호
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    • pp.715-722
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    • 1995
  • Vlnylbenzyl triphenyl phosphonim chloride (VTPC) 단량체를 감습막으로 사용하기 위하여 합성하였다. 감습막 성분은 서로 다른 조성의 VTPC와 스티렌의 공중합체(VTPC : ST=1 : 0, 7 : 3, 1 : 1, 3 : 7)들이며 감습막의 상대 습도 변화에 대한 전기적 성질의 변화를 측정하였다. 임퍼던스는 감습막중 VTPC의 함량이 증가할수록 감소하였으며, 또한 전극위에 도포한 감습막의 두께가 증가하면 임퍼던스 역시 감소하였다. 감습막중 VTPC와 ST의 성분비가 1대 1인 감습막의 임피던스는 상대습도 70~90%RH 범위에서 12M$\Omega$에서 100K$\Omega$ 사이에서 변하였으며 고습이나 결로를 감지할 수 있는 센서로서 응용이 가능하였다. 15$^{\circ}C$~35$^{\circ}C$범위에서의 은도 의존상수는 -0.5%RH/$^{\circ}C$이었으며 히스테리시스는 $\pm$2%RH의 범위 안에서 나타났다. 응답속도는 상대습도가 75%RH에서 95RH%까지 또는 역으로 변화할 때 40초이었다.

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접합된 Stepped impedance resonator를 이용한 온도보상형 유전체 대역통과 필터 (A temperature stable bandpass filter using dieletric-filled stepped impedance resonators)

  • 임상규;김준철;김덕환;하종수;오창헌;심화섭;안철
    • 전자공학회논문지D
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    • 제35D권2호
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    • pp.78-85
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    • 1998
  • 공진주파수의 온도계수(.tau./sub f/)가 큰 양(+)의 값을 가졌거나 혹은 음(-)의 값을 지녀 실제 활용되지 못하고 있는 마이크로파 유전체를 대역통과 필터에 응용하기 위한 대역통과 필터의 설계 방법이 제안되었고, 이 방법에 따라 제작된 대역통과 필터의 온도 안정성이 확인되었다. 이 방법에서 유전체 대역통과 필터를 구성하는 각각의 유전체 공진기는 서로 상반된 유전율의 온도계수(.tau./sub .epsilon./)를 지닌 유전체를 접합시켜 만든 SIR(Stepped Impedance Resonator) 구조로 되어있으며, 공진조건으로부터 접합 SIR의 공진주파수가 온도 변화에 안정하기 위한 길이 조건과 필터 설계에 필요한 susceptance slope parameter가 구해졌다. 설계하고자 하는 접합 SIR을 이용한 대역통과 필터는 중심주파수 915 MHz에서 통과대역폭 20 MHz를 갖도록 하였으며, 접합 SIR의 유전재료는 유전율의 온도계수(.tau./sub .epilon./)가 양(+)의 값을 갖는 MgTiO/sub 3/(.tau./sub .epilon./=+99 ppm/.deg. C)와 음(-)의 값을 갖는 Ba(Zn/sub 1/3/Nb/sub 2/3/)O/sub 3/(.tau./sub .epilon./=-77 ppm/.deg. C)을 이용하였다. 최종적으로 필터 설계식에 따라 설계된 접합 SIR 대역통과 필토의 온도 안정성이 시뮬레이션과 실제 제작을 통해 확인되었다.

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Corrosion Behaviors of Dental Implant Alloy after Micro-sized Surface Modification in Electrolytes Containing Mn Ion

  • Kang, Jung-In;Son, Mee-Kyoung;Choe, Han-Cheol
    • Journal of Korean Dental Science
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    • 제11권2호
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    • pp.71-81
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    • 2018
  • Purpose: The purpose of this study was to investigate the corrosion behaviors of dental implant alloy after microsized surface modification in electrolytes containing Mn ion. Materials and Methods: $Mn-TiO_2$ coatings were prepared on the Ti-6Al-4V alloy for dental implants using a plasma electrolytic oxidation (PEO) method carried out in electrolytes containing different concentrations of Mn, namely, 0%, 5%, and 20%. Potentiodynamic method was employed to examine the corrosion behaviors, and the alternatingcurrent (AC) impedance behaviors were examined in 0.9% NaCl solution at $36.5^{\circ}C{\pm}1.0^{\circ}C$ using a potentiostat and an electrochemical impedance spectroscope. The potentiodynamic test was performed with a scanning rate of $1.667mV\;s^{-1}$ from -1,500 to 2,000 mV. A frequency range of $10^{-1}$ to $10^5Hz$ was used for the electrochemical impedance spectroscopy (EIS) measurements. The amplitude of the AC signal was 10 mV, and 5 points per decade were used. The morphology and structure of the samples were examined using field-emission scanning electron microscopy and thin-film X-ray diffraction. The elemental analysis was performed using energy-dispersive X-ray spectroscopy. Result: The PEO-treated surface exhibited an irregular pore shape, and the pore size and number of the pores increased with an increase in the Mn concentration. For the PEO-treated surface, a higher corrosion current density ($I_{corr}$) and a lower corrosion potential ($E_{corr}$) was obtained as compared to that of the bulk surface. However, the current density in the passive regions ($I_{pass}$) was found to be more stable for the PEO-treated surface than that of the bulk surface. As the Mn concentration increased, the capacitance values of the outer porous layer and the barrier layer decreased, and the polarization resistance of the barrier layers increased. In the case of the Mn/Ca-P coatings, the corroded surface was found to be covered with corrosion products. Conclusion: It is confirmed that corrosion resistance and polarization resistance of PEO-treated alloy increased as Mn content increased, and PEO-treated surface showed lower current density in the passive region.

개방형 도파관 배열안테나의 조향소자 특성 (Scan Element Characteristics of Open-Ended Waveguide Array Antenna)

  • 김동석;김태현;박동철;김찬홍
    • 한국전자파학회:학술대회논문집
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    • 한국전자파학회 2005년도 종합학술발표회 논문집 Vol.15 No.1
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    • pp.347-352
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    • 2005
  • Scan Element Pattern(SEP) and Scan Impedance(SI) concepts are used to analyze the characteristics of open-ended waveguide array, which is the representative phased array antenna element in C-band and X-band. Transmit SEP's are calculated for 15$\sim$15 subarray and SI's are obtained by applying periodic boundary conditions for a unit cell of the given array condition. CST's MWS and Ansoft's HFSS are utilized for each analysis. Some relations are reviewed between the two results, which are based on mutual coupling effects. For validation purpose, an 8$\sim$8 subarray is constructed and tested. Transmit SEP measured in MTG's far-field range shows good agreement with the calculated transmit SEP.

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교류급전시스템의 단권변압기 탭변환에 따른 고장전류 및 고장임피던스 검토 (Investigation of Fault Current and Impedance according to Autotransformer Tap Changing)

  • 김주락;한문섭;창상훈;김정훈
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1167_1168
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    • 2009
  • This paper presents new configuration of a.c. traction power supply system. The proposed system includes autotransformer with variable tab. The voltage drop in traction power supply system can be reduced due to tap change of autotransformer. In this paper, fault current and Impedance is investigated, when fault occurs in traction power supply system.

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SiO2 첨가가 AIN 세라믹스의 고온 비저항에 미치는 영향 (Effects of SiO2 on the High Temperature Resistivities of AIN Ceramics)

  • 이원진;김형태;이성민
    • 한국세라믹학회지
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    • 제45권1호
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    • pp.69-74
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    • 2008
  • The effects of $SiO_2$ impurity on the high temperature resistivities of AIN ceramics have been investigated. When $SiO_2$ was added into 1 wt% $Y_2O_3$-doped AIN, DC resistivities have decreased and electrode polarizations disappeared. Impedance spectroscopy showed two semi-circles at $600^{\circ}C$, which were attributed to grain and grain boundary, respectively. $SiO_2$ doping had more significant effects on the grain resistivity than grain boundary resistivity, implying that doped Si acted as a donor in AIN lattice. In addition, voltage dependency of DC resistivity was observed, which might be related to dependency of size of grain boundary semi-circle on the bias voltage in impedance spectroscopy.

감습특성이 우수한 금속산화물계 습도센서 연구 (A Study on Metal Oxide based Humidity Sensor with Excellent Humidity Sensing Characteristics)

  • 유도현
    • 전기학회논문지
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    • 제58권10호
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    • pp.1982-1988
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    • 2009
  • $TiO_2$ films are fabricated using silk printing method. Heat treatment temperature of films is 600[$^{\circ}C$]. From the analysis of microstructure, grain size of $TiO_2$ films is about $0.2{\sim}0.3[{\mu}m]$. Thickness of films is 30.19[${\mu}m$] and surface uniformity of films is good. From the analysis of crystalline structure, $TiO_2$ films transform anatase phase to rutile phase. Capacitance of films increases according to increase relative humidity and decrease measuring frequency. Hysteresis characteristics of capacitance and impedance are best at 45[%RH] and 75[%RH] respectively. Impedance of films increases according to decrease measuring frequency.

스테인리스 스틸 연결재의 Cr이 LSCF 양극의 분극저항에 미치는 영향 (The Effect of Cr from STS Interconnect on the Polarization Resistance of LSCF Cathode)

  • 황호준;최경만
    • 한국세라믹학회지
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    • 제44권12호
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    • pp.715-719
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    • 2007
  • STS444 with or without $La_{0.9}Sr_{0.1}MnO_3$ (LSM)-coating was contacted to $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ (LSCF) cathode on various electrolyte materials and the polarization resistance $(R_p)$ was measured by impedance spectroscopy. By making a symmetric half-cell and contacting only one side of the cathode with the interconnect, the effect of chromium (Cr) poisoning was separated from the aging effects. When the LSCF cathode was contacted with LSM-coated STS (stainless steel), $R_p$ of LSCF was lower than that contacted with the uncoated STS. Impedance patterns measured for the working electrode (W.E.), the counter electrode (C.E.) at $600^{\circ}C$ in air were analyzed. Normalized data of net Cr effect showed that $Ce_{0.9}Gd_{0.1}O_2$ (GDC) electrolyte is more tolerant to the chromium poisoning than $La_{0.9}Sr_{0.1}Ga_{0.8}Mg_{0.2}$ (LSGM) or 8 mol% $Y_2O_3-doped$ $ZrO_2$ (YSZ) electrolytes.

압전세라믹 PZT-고분자 1-3-0형 복합압전체의 제조 및 전기적 특성 (Fabrication and Electrical Properties of Piezoceramics PZT-Polymer 1-3-0 Type Composite)

  • 손무헌;최헌일;사공건
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권4호
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    • pp.241-246
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    • 1999
  • In this study, the piezoelectric ceramics PZT powders were synthesized by Wet-Dry combination method. And the flexible 1-3-0 type composites were favricated with piezoceramic PZT and Eccogel polymer matrix embedded 3rd phase. Dielectric constant of 1-3-0 type composites was lower than that of single phase PZT ceramics. Thickness mode coupling factor $k_t$ which was comparable with single phase PZT ceramics, and Mechanical Quality factor $Q_m$ were about 0.65 and 6 respectively. These composites are considered as a good candidates for broad-band type transducer applications. The acoustic impedance for 1-3-0 type composites was lower than that of single phase PZT ceramics. Therefore, these composites would be better used for hydrophone applications.

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