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A study on skin permeability enhancement of active substances in cosmetics using nanobubble technique (나노버블 기법을 이용한 화장품 내 유효물질의 피부투과성 증가에 관한 연구)

  • Lee, Sung-Joo;Lee, Soon-Hong;Park, Seung-il
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.4
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    • pp.1041-1051
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    • 2020
  • The technology of microbubbles and nanobubbles originated in Japan and Europe is applicable to various applications and its effects are diverse, attracting attention not only from many researchers but also from industry experts. In particular, nanobubbles have the advantage that they can be applied to products in the form of liquids, such as cosmetics, from the study that they can exist for more than several months in water. In this study, it was carried out the production of nanobubbles using bubble encapsulation technique and the experiment of skin permeability enhancement of active substances in cosmetics using nanobubble techniquethree. Nanobubbles were confirmed to affect the skin permeability increase of active substances, and up to 250% increase in skin permeability compared to non-bubbles-free materials(Caffeic acid, at 8 hour). It is expected that research results and industrial ripple effects can be expected not only in the cosmetic field, but also in fields applicable to the improvement of permeability by nanobubble techniques, such as areas related to drug delivery system.

Container Types Influence Chamaecyparis obtusa Seedling Growth During Nursery Culture (시설양묘과정에서 용기에 따른 편백 유묘의 생장 특성 변화)

  • Cho, Min Seok;Yang, A-Ram;Hwang, Jaehong
    • Journal of Korean Society of Forest Science
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    • v.103 no.4
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    • pp.556-563
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    • 2014
  • The purpose of this study was to evaluate the effects of container types on seedling growth of Chamaecyparis obtusa (2-year-old) in the container nursery culture. We used three container types [20 cavities (400 mL/cavity, $150seedlings/m^2$), 24 cavities (320 mL/cavity, $200seedlings/m^2$), and 35 cavities (240 mL/cavity, $260seedlings/m^2$)] and measured root collar diameter (RCD), height, biomass, root density and seedling quality index (SQI). The RCD, height, biomass, root density and SQI were the highest at 20 cavities/tray because this container has the largest volume and lowest seedling density. However, H/D and T/R ratio at all container types were not significantly different. The total biomass per unit area ($m^2$) were the lowest at 35 cavities/tray and those at both 20 and 24 cavities/tray were not significantly different. Container volume was positively correlated with RCD, height, biomass, root density and SQI except for H/D and T/R ratio, while seedling density negatively affected on them. Based on these results, 20 cavities/tray are optimal for container seedling production of C. obtusa. Usage of optimal container will make us get better quality seedlings and reduction of production costs in the container nursery as well as good field performances with higher survival rate in plantation.

Adsorption and Storage of Hydrogen by Nanoporous Adsorbents (나노세공체 흡착제에 의한 수소 흡착 및 저장)

  • Jhung, Sung Hwa;Chang, Jong-San
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.99-110
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    • 2007
  • Efficient and inexpensive hydrogen storage is an essential prerequisite for the utilization of hydrogen, one of the new and clean energy sources for $21^{st}$ century. In this review, several storage techniques are briefly reviewed and compared. Especially, adsorption/storage via physisorption at low temperature, by using nanoporous adsorbents, is reviewed and evaluated for further developments. The adsorption over a porous material at low temperature is currently investigated deeply to fulfill the storage target. In this review, several characteristics needed for the high hydrogen adsorption capacity are introduced. It may be summarized that following characteristics are necessary for high storage capacity over porous materials: i) high surface area and micropore volume, ii) narrow pore size, iii) strong electrostatic field, and iv) coordinatively unsaturated sites, etc. Moreover, typical results demonstrating high storage capacity over nanoporous materials are summarized. Storage capacity up to 7.5 wt% at liquid nitrogen temperature and 80 atm is reported. Competitive adsorbents that are suitable for hydrogen storage may be developed via intensive and continuous studies on design, synthesis, manufacturing and modification of nanoporous materials.

Effects of Scarification and Water Soaking Treatment on Germination of Hard-Seeded Legumes (두과 작물의 경실종자 발아촉진에 대한 종피연화처리의 효과)

  • Kim, Seok-Hyeon;Chang, Mi-Ha;Chung, Jong-Il;Shim, Sang-In
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.3
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    • pp.320-326
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    • 2009
  • The crops showing hard seed character have high seed viability after seed storage for long period. The low germination rate due to hard seed coat, however, cause a problem of low seedling establishment in field condition. Three legumes used in the experiment, lablab bean (Dolichos lablab L.), asparagus bean (Vigna sesquipedalis L. Fruwirth), and soybean (Glycine max L. Merr.), showed low germination rate (26, 17, and 5%, respectively) due to thick and hard seed coat. In this study artificial treatment for breaking dormancy was tested in hard seeds. The effect of proper treatment was various depending on species. The germination rate of lablab bean was highly improved up to 94% by soaking into water for 24 hours. In the case of asparagus bean, the rate was increased up to 90% by soaking for eight hours near boiling water until it cools. The germination rate of small hard seed soybean was increase to 96% by soaking into concentrated sulfuric acid for 10 minutes. Ultrastructural change revealed by scanning electron microscope (SEM) reflects that the structure of micropyle was changed and water uptake was facilitated with all treatments tested in the experiment. Especially, sulfuric acid treatment resulted in the degradation of micropylar tissue. These results demonstrate that the artificial treatment including sulfuric acid and (hot) water soaking treatment for promoting water uptake can be applied to improve seed germination in legume seed with thick and hard seed coat.

Field Applicability of Low Temperature Thermal Desorption Equipment through Environmental Impact Analysis of Remediated Soil and Exhaust Gas (정화토양 및 배출가스의 환경적 특성 분석을 통한 저온열탈착장치의 현장 적용성 평가)

  • Oh, Cham-Teut;Yi, Yong-Min;Kim, Young-Soung;Jeon, Woo-Jin;Park, Gwang-Jin;Kim, Chi-Kyung;Sung, Ki-June;Chang, Yoon-Young;Kim, Guk-Jin
    • Journal of Soil and Groundwater Environment
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    • v.17 no.3
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    • pp.76-85
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    • 2012
  • Geochemical and ecological properties of remediated soil and gas exhausted from a low-temperature thermal desorption (LTTD) process were analyzed to assess the environmental impact of LTTD treatment. Soil characteristics were examined with regard to the chemical (EC, CEC, and organic matter) and the ecological (dehydrogenase activity, germination rate of Brassica juncea, and growth of Eisenia andrei) properties. The exhaust gases were analyzed based on the Air Quality Act in Korea as well as volatile organic compounds (VOCs) and mixed odor. Level of organic Organic matter of the soil treated by LTTD process was slightly decreased compared to that of the original soil because the heating temperature ($200^{\circ}C$) and retention time (less than 15 minutes) were neither high nor long enough for the oxidation of organic matter. The LTTD process results in reducing TPH of the contaminated soil from $5,133{\pm}508$ mg/kg to $272{\pm}107$ mg/kg while preserving soil properties. Analysis results of the exhaust gases from the LTTD process satisfied discharge standard of Air Quality Law in Korea. Concentration of VOCs including acetaldehyde, propionaldehyde, butyraldehyde and valeraldehyde in circulation gas volatilized from contaminated soil were effectively reduced in the regenerative thermal oxidizer and all satisfied the legal standards. Showing ecologically improved properties of contaminated soil after LTTD process and environmentally tolerable impact of the exhaust gas, LTTD treatment of TPH-contaminated soil is an environmentally acceptable technology.

Test of Official Range in Characteristics for Jisan Soil Series (지산통(芝山統)의 토양특성(土壤特性) 범위(範圍) 검정(檢定))

  • Jung, Sug-Jae;Park, Chang-Seo;Hyeon, Geun-Soo;Moon, Joon;Um, Ki-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.2
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    • pp.81-85
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    • 1989
  • The 113 soils representing the Jisan soil series (fine loamy, mixed, mesic fluventic Haplaquepts) as mapped in Korea were to characterize the Jisan soil throughout its official range which was the range of properties used to establish series limits. The samples were stratified according to master horizon designation for statistical analysis. The means in selected soil properties, horizon thickness, solum thickness, soil texture, clay content, pH, BSP, and horizon sequence, were within acceptable limits. The minimum values were considerably lower than the lower limits of the official ranges while the maximum values were above the allowable amount. The ranges of definition degree which mean the test of proper placement of any marginal limits were 0.687 to 0.929. Thus, Jisan series as mapped from other soil bodies in the field could be seen similarities and understood relationships among individuals.

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Consulting Competence of IT Consultants: Perceptual Differences between IT Consultants and Business Clients (IT 컨설턴트의 컨설팅 역량: 컨설턴트와 고객의 인식 차이를 중심으로)

  • Park, So-Hyun;Lee, Kuk-Hie
    • Information Systems Review
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    • v.11 no.1
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    • pp.107-132
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    • 2009
  • The purpose of this research is to define the consulting competence of IT consultants and empirically analyze the perceptual differences between the IT consultant group and the client group. Based on the previous researches and the opinion of the actual IT consultants, the consulting capability model has been established, which consists of six categories and eighteen factors. Six categories are (1) IT domain expertise, (2) problem solving ability, (3) project management capability, (4) communication skills, (5) human relations skills, and (6) professional ethics and attitude. Two field surveys have been performed and the responses of 174 IT consultants 116 clients have been acquired. It is shown that the level of possessed proficiency of IT consulting capability is far lower than the level of the required proficiency. And there exist the perceptual difference between two responding groups with respect to the level required proficiency but no difference exists in terms of the level of possessed proficiency. The findings of this research can provide some useful information in order to fully understand the differences between the IT consultant group and the client group.

커패시터에의 적용을 위해 PET 필름에 스퍼터 증착한 ZrO2 박막의 특성

  • Gwon, Neung;Fei, Chen;Ryu, Han;Park, Sang-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.389.1-389.1
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    • 2014
  • 최근의 환경 및 에너지에 대한 관심으로 수요가 증가하고 있는 하이브리드 및 전기 자동차나 태양광발전, 풍력발전용의 인버터기기에는 고에너지밀도 커패시터가 필수적이 되었다. 높은 에너지 밀도를 요구하는 전력전자, 펄스파워 등의 응용분야에 사용되는 고에너지밀도 커패시터는 PET (Polyethylene terephtalate)와 PP (Polypropylene)와 같은 폴리머 유전체를 사용하는 범용 필름 커패시터가 사용되었으나 사용 요구 조건의 한계에 도달하여, 새로운 유전체를 적용하는 커패시터가 절실히 필요한 상황이다. PET와 PP와 같은 유전체는 유전상수가 2~3의 낮은 값을 가지고 있어 고에너지밀도를 구현하기가 어렵다. 본 연구에서는 새롭게 요구되고 있는 고에너지 밀도 커패시터의의 성능을 만족시키기 위하여 $20{\sim}50{\mu}m$ 두께의 PET 필름상에 세라믹 유전체인 $ZrO_2$ 박막을 스퍼터(Sputter) 증착법에 의해 코팅하여 종래의 필름 커패시터와 세라믹 커패시터의 장점을 갖는 커패시터를 제조하기 위한 박막 유전재료의 개발을 목표로 하였다. 수백 nm~수 ${\mu}m$ 두께의 $ZrO_2$ 박막을 스퍼터링 공정조건에 따라 증착한 후 박막의 결정성, 기판과의 부착성, 증착속도, 유전상수, 절연파괴강도, 온도안정성 등을 XRD, SEM, AFM, EDS, XPS, Impedance analyzer 등에 의해 평가하였다. $ZrO_2$ 유전체막은 상온에서 증착하였음에도 정방정(tetragonal)구조의 결정질로 성장하였고 증착압력이 증가함에 따라 주피크의 세기가 감소하였다. 증착 중 산소가스를 주입하였을 경우에도 결정질막으로 성장하였다. 증착막들은 산소가스의 양이 증가함에 따라 짙은 흰색으로 변하였으며 PET 기판과의 접착력도 약해졌다. 또한 거칠기는 Ar가스만으로 증착한 경우보다 증가하였으며 24~66 nm의 평균 거칠기값을 보였다. PET위에 Ar가스만으로 증착한 $ZrO_2$의 비유전율은 1kHz에서 116~87의 비유전율을 보여 PET에 비해 매우 우수한 특성을 보였다. $ZrO_2$ 막들은 300kV/cm의 전계에서 대략 10-8A 이하의 누설전류를 보였다. 증착가스비를 달리하여 제조된 시편에서도 유사한 누설전류값을 나타내었다. 300 kV/cm 전후의 전계까지 측정한 $ZrO_2$ 막의 P-E (polarization-electric field) 특성을 확인하였는데, 5 mTorr의 압력에서 증착한 막은 253 kV/cm에서 $5.5{\mu}C/cm^2$의 분극값을 보였다. P-E커브의 기울기와 분극량에 따라 에너지밀도가 달라지므로 공정조건에 따라 에너지밀도가 변화됨을 예측할 수 있었다. PET위에 스퍼터 증착한 $ZrO_2$ 유전체막은 5mTorr의 Ar가스분위기에서 제조할 때 가장 안정적인 구조를 보였으며, 고에너지밀도 커패시터에의 적용가능성을 보였다.

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Analysis of Organic Carbon Cycle and Mass Balance in Daecheong Reservoir using Three-dimensional Hydrodynamic and Water Quality Model (3차원 수리·수질 모델을 이용한 대청호 유기탄소 순환 및 물질수지 해석)

  • An, Inkyung;Park, Hyungseok;Chung, Sewoong;Ryu, Ingu;Choi, Jungkyu;Kim, Jiwon
    • Journal of Korean Society on Water Environment
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    • v.36 no.4
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    • pp.284-299
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    • 2020
  • Dam reservoirs play a particularly crucial role in processing the allochthonous and the autochthonous dissolved (DOC) and the particulate (POC) organic carbon and in the budget of global carbon cycle. However, the complex physical and biogeochemical processes make it difficult to capture the temporal and spatial dynamics of the DOC and the POC in reservoirs. The purpose of this study was to simulate the dynamics of the DOC and the POC in Daecheong Reservoir using the 3-D hydrodynamics and water quality model (AEM3D), and to quantify the mass balance through the source and sink fluxes analysis. The AEM3D model was calibrated using field data collected in 2017 and showed reasonable performance in the water temperature and the water quality simulations. The results showed that the allochthonous and autochthonous proportions of the annual total organic carbon (TOC) loads in the reservoir were 55.5% and 44.5%, respectively. In season, the allochthonous loading was the highest (72.7%) in summer, while in autumn, the autochthonous loading was the majority (77.1%) because of the basal metabolism of the phytoplankton. The amount of the DOC discharged to downstream of the dam was similar to the allochthonous load into the reservoir. However, the POC was removed by approximately 96.6% in the reservoir mainly by the sedimentation. The POC sedimentation flux was 36.21 g-C/㎡/yr. In terms of space, the contribution rate of the autochthonous organic carbon loading was high in order of the riverine zone, the transitional zone, and the lacustrine zone. The results of the study provide important information on the TOC management in the watersheds with extensive stagnant water, such as dam reservoirs and weir pools.

Effects of Cultivars and Seeding Dates on Chemical Composition and Energy Content of Switchgrass (Panicumvirgatum L.) in Republic of Korea

  • Ji, Do-Hyeon;Kim, Byong-Wan;Sargolzehi, Mohammad Mahdi;Kang, Shin-Gon;Lee, Bae-Hun;Peng, Jing-Lun;Nejad, Jalil Ghassemi;Min, Doo-Hong;Sung, Kyung-Il
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.34 no.3
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    • pp.179-186
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    • 2014
  • The objective of this study was to determine the best performing switchgrass (Panicumvirgatum L.) cultivar with three different seeding dates as a bioenergy source in Republic of Korea. Split-plot in time with three replications was performed and three switchgrass cultivars, Carthage (CT), Cave-in-Rock (CIR), and Forestburg (FB) were used in this experiment from 2009 to 2012. Plots were seeded on April 23, May 4, and May 13, 2009 and were harvested once in November each year. No fertilizer was applied to the field for the first year; however, in second and third years (June 2010 and May 2011, respectively), N, $P_2O_5$ and K2O fertilizers were applied in 67,45 and 90 kg $ha^{-1}$, respectively. Soil pH (5.9) and climate condition including temperature ($10.4{\sim}17.5^{\circ}C$) and precipitation (89.4~109.8 mm $month^{-1}$) were suitable for switchgrass cultivation. Total dry matter yields were higher in CT and CIR compared to FB and were 16.9, 15.9, and 4.5 ton $ha^{-1}$, for CT, CIR, and FB, respectively (p<0.0001). The samples were analyzed for dry matter (DM), crude protein (CP), neutral detergent fiber (NDF), acid detergent fiber (ADF), crude fiber (CF), ether extract (EE), and ash. No significant differences in energy content (p = 0.96) and chemical composition among cultivars (p>0.05) were found. Seeding dates did not affect DM yield (ton $ha^{-1}$), chemical composition and energy content significantly (p>0.05). Significant difference was observed for heights among CT, CIR, and FB (177.59, 169.98, and 94.89 cm, respectively, p = 0.0002). In conclusion, based on soil characteristics and climate condition in Korea compared to other countries, switchgrass can be cultivated successfully. Considering dry matter yield and energy content of these three cultivars of switchgrass CT and CIR adapted better to climate in Middle Eastern of Republic of Korea than Forestburg for bioenergy purpose.