• 한국표면공학회지
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• 제50권2호
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• pp.108-113
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• 2017

We investigated the effect of graphite electrode geometry and combination on nanocarbon material synthesis using underwater discharge plasma(UDP). The UDP system consists of two graphite electrodes and beaker filled with de-ionized water. A high voltage of 15 kV with a frequency of 25 kHz is applied to produce UDP using an alternating-current power source. The UDP system with conical electrodes produced the largest amount of products due to the concentration of electrical fields between electrodes. In addition, hollow-shaped stationary electrode and conical-shaped moving electrode stores discharge-induced bubbles and maintains longer reaction time. We found from Raman spectroscopy and electron microscopy that high quality carbon nanomaterials including carbon nanotubes are synthesized by the UDP system.

• 한국전기전자재료학회논문지
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• 제32권6호
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• pp.458-461
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• 2019

The facile synthesis of shape-controlled Pd nanoparticles (PdNPs) with ascorbic acid as a reducing agent and cetyltrimethylammonium bromide (CTAB) as a capping agent is presented in this study. The synthesized PdNPs were characterized by UV-vis spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman Spectroscopy. The prepared PdNPs show efficient surface-enhanced Raman scattering (SERS) properties. SERS studies on the adsorption characteristics of 1,4-phenylene diisocyanide (1,4-PDI) on colloidal PdNPs have revealed that the relative peak intensity of the $(NC)_{free}$ and $(NC)_{bound}$ modes distinctly depends on the 1,4-PDI concentration as well as the shape of the PdNPs. Furthermore, we found that the PdNPs are also efficient photoelectron emitters such that the SERS spectrum of 4-nitrobenzenethiol (4-NBT) on PdNPs is readily converted to that of 4-aminobenzenethiol (4-ABT) under 632.8 nm radiation.

• Macromolecular Research
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• 제17권2호
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• pp.104-109
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• 2009

Solid-state facilitated, olefin transport membranes were prepared by complexation of poly(styrene-b-iso-prene-b-styrene) (SIS) block copolymer and silver salt. Facilitated olefin transport was not observed up to a silver mole fraction of 0.14, representing a threshold concentration, above which transport increased almost linearly with increasing silver salt concentration. This was because firstly the silver ions were selectively coordinated with the C=C bonds of PI blocks up to a silver mole fraction of 0.20, and secondly the coordinative interaction of the silver ions with the aliphatic C=C bond was stronger than that with the aromatic C=C bond, as confirmed by FT-Raman spectroscopy. Small angle X-ray scattering (SAXS) analysis showed that the cylindrical morphology of the neat SIS block copolymer was changed to a disordered structure at low silver concentrations ($0.01{\sim}0.02$). However, at intermediate silver concentrations ($0.15{\sim}0.20$), disordered-ordered structural changes occurred and finally returned to a disordered structure again at higher silver concentrations (>0.33). These results demonstrated that the facilitated olefin transport of SIS/silver salt complex membrancs was significantly affected by their coordinative interactions and nano-structural morphology.

• 한국표면공학회지
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• 제47권6호
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• pp.347-353
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• 2014

We present a synthesis of single-walled carbon nanotubes(SWNTs) for enhancement of parallel-alignment and density using chemical vapor deposition with methane feed gas. As-purchased ST-cut quartz substrates were heat-treated and line-patterned by electron-beam lithography in order to grow SWNTs with parallel alignment. We investigated the effects of various synthesis parameters such as catalyst oxidation, reduction, and synthesis conditions in order to enhance both tube density and degree of parallel alignment. The condition of $1{\AA}$ of Fe catalyst film, atmospheric oxidation at $750^{\circ}C$ for 10 min, reduction under 400 Torr for 5 min, and growth at $865^{\circ}C$ under 300 Torr yields $33tubes/10{\mu}m$, which is the highest tube density with parallel alignment. Based on the results of atomic force microscope and Raman spectroscopy, it was found that SWNTs have diameter range of 0.8-2.0 nm. We believe that the present work would contribute to the development of SWNTs-based flexible functional devices.

• 비파괴검사학회지
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• 제36권6호
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• pp.443-450
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• 2016

한 개의 감지 광섬유 라인으로 분포 온도와 몇 개의 변형률을 측정할 수 있는 새로운 광섬유 센서 연구를 수행하였다. 분포 온도는 감지 광섬유의 라만 안티-스토크스 산란광을 시간영역 반사계(OTDR: optical time domain reflectometry)로 측정하고, 변형률은 광섬유 브래그 격자(FBG: fiber Bragg grating)를 사용하여 측정하였다. 분포 온도는 4 km의 단일 모드 광섬유의 감지 광섬유로부터 안티-스토크스 후방 산란광을 양방향에서 취득하고 새로이 고안된 수식으로 온도를 계산하였다. 온도 실험은 감지 광섬유의 중간쯤에서 약 50 m의 광섬유 부분의 온도를 $30^{\circ}C$부터 $70^{\circ}C$까지 $10^{\circ}C$ 간격으로 변화시키면서 실험한 결과 온도 측정 오차 범위는 $0.50^{\circ}C$이하로 확인되었다. 또한 감지 광섬유에 설치된 FBG는 변위 스테이지로 변형시키고 파장 변화를 광학 스펙트럼 분석기로 측정한 결과 각각 0.10 nm, 0.17 nm, 0.29 nm, and 0.00 nm를 얻었다. 이러한 파장 이동은 각각 $85.76{\mu}{\epsilon}$, $145.55{\mu}{\epsilon}$, $247.86{\mu}{\epsilon}$, $0.00{\mu}{\epsilon}$에 해당되었다.

• 한국진공학회지
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• 제17권1호
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• pp.51-57
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• 2008

나노크기의 Au-Si을 촉매로 급속열화학기상증착(rapid thermal chemical vapor deposition)법을 이용하여 Si(111) 기판에 성장한 Si 나노선의 구조적인 형태 변화와 광학적 특성을 연구하였다. 기상-액상-고상(vapor-liquid-solid) 성장법에 의한 Si 나노선 형성 과정에서 액상 입자인 Au-Si 나노점은 나노선 성장온도에서 촉매로 사용되었다. 이 액상 나노점이 형성된 Si 기판에 1.0Torr 압력과 $500-600^{\circ}C$ 기판 온도 하에서 $SiH_4$와 $H_2$의 혼합가스를 공급하여 Si 나노선을 형성하였다. Si 나노선 성장 후 형태를 전계방출 주사전자현미경(Field Emission Scanning Electron Microscope)으로 관찰한 결과, 대부분의 나노선이 균일한 크기로 기판 표면에 수직하게 <111> 방향으로 정렬된 것을 확인하였다. 형성된 나노선의 크기는 평균 직경이 ${\sim}60nm$이고 평균 길이가 ${\sim}5um$임을 확인하였다. 또한 고 분해능 투과전자현미경(High Resolution-Transmission Electron Microscope) 관찰을 통해 Si 나노선은 약 3nm의 비정질 산화층으로 둘러 싸여 있는 Si 단결정임이 분석되었다. 그리고 마이크로 라만 분광(Micro-Raman Scattering)법을 통한 광학적 특성 분석 결과, Si의 광학 포논(Optical Phonon) 신호 위치가 Si 나노선 구조의 영향으로 낮은 에너지 쪽으로 이동하며, Si 포논 신호의 폭이 비대칭적으로 증가함을 확인하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.51.2-51.2
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• 2015

Understanding interfacial phenomena has been one of the main research issues not only in semiconductors but only in life sciences. I have been trying to meet the atomic scale surface and interface analysis challenges from semiconductor industries and furthermore to extend the application scope to biomedical areas. Optical imaing has been most widely and successfully used for biomedical imaging but complementary ion beam imaging techniques based on mass spectrometry and ion scattering can provide more detailed molecular specific and nanoscale information In this presentation, I will review the 27 years history of medium energy ion scattering (MEIS) development at KRISS and DGIST for nanoanalysis. A electrostatic MEIS system constructed at KRISS after the FOM, Netherland design had been successfully applied for the gate oxide analysis and quantitative surface analysis. Recenlty, we developed time-of-flight (TOF) MEIS system, for the first time in the world. With TOF-MEIS, we reported quantitative compositional profiling with single atomic layer resolution for 0.5~3 nm CdSe/ZnS conjugated QDs and ultra shallow junctions and FINFET's of As implanted Si. With this new TOF-MEIS nano analysis technique, details of nano-structured materials could be measured quantitatively. Progresses in TOF-MEIS analysis in various nano & bio technology will be discussed. For last 10 years, I have been trying to develop multimodal nanobio imaging techniques for cardiovascular and brain tissues. Firstly, in atherosclerotic plaque imaging, using, coherent anti-stokes raman scattering (CARS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) multimodal analysis showed that increased cholesterol palmitate may contribute to the formation of a necrotic core by increasing cell death. Secondly, surface plasmon resonance imaging ellipsometry (SPRIE) was developed for cell biointerface imaging of cell adhesion, migration, and infiltration dynamics for HUVEC, CASMC, and T cells. Thirdly, we developed an ambient mass spectrometric imaging system for live cells and tissues. Preliminary results on mouse brain hippocampus and hypotahlamus will be presented. In conclusions, multimodal optical and mass spectrometric imaging privides overall structural and morphological information with complementary molecular specific information, which can be a useful methodology for biomedical studies. Future challenges in optical and mass spectrometric imaging for new biomedical applications will be discussed.

• 대한원격탐사학회지
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• 제29권4호
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• pp.415-421
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• 2013

본 연구에서는 다파장 라만 라이다 시스템을 이용하여 대기 중의 비구형 순수 황사입자와 구형 오염 입자가 혼합된 황사 입자의 단산란 알베도를 산출할 수 있는 방법론을 제시하고, 실제 대기 관측 사례 분석 자료로부터 정확도를 검증하고자 하였다. 편광소멸도는 황사와 비황사와의 혼합정도에 반비례함을 응용하여 편광소멸도 값으로부터 황사비를 산출하고 이를 이용하여 황사와 비황사로 황사층을 구분하였다. 산출된 비황사의 두 파장(355, 532 nm)의 소산계수와 세 파장(355, 532, 1064 nm)의 후방산란계수를 이용하여 역행렬 분석을 수행하여 비황사의 고도별 단산란알베도를 도출하였다. 황사와 비황사의 가중치를 소산계수값으로부터 산출하고 각 가중치를 황사와 비황사에 적용하여 황사 층 전체의 고도별 단산란알베도를 산출하였다. 단, 황사의 단산란알베도는 순수황사로 가정하여 발원지에서 측정된 순수황사가 나타내는 0.96의 값을 적용하였다. 본 연구로부터 개발된 분석방법은 기존의 원격탐사 기술의 한계점을 극복하여 황사의 이동시 타 오염입자와의 혼합에 따른 광학적 특성의 변화에 대한 정밀한 자료를 제공할 수 있을 것으로 기대된다.

• Current Optics and Photonics
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• 제7권5호
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• pp.562-568
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• 2023

We designed a combined nanostructure of inverted pyramidal pits and nanoparticles, which can obtain much stronger field enhancement than traditional periodic pits or nanoparticles. The field enhancement |E|/|E₀| is greater than 10 in a large area at 750-820 nm in incident wavelength. |E_max|/|E₀| is greater than 60. Moreover, the hot spot is obtained outside the pits instead of localized inside them, which is beneficial for experiments such as surface-enhanced Raman scattering. The relations between resonant wavelength and structural parameters are investigated. The resonant wavelength shows a linear dependence on the structure's period, which provides a direct way to tune the resonant wavelength. The excitation of a propagating surface plasmon on the periodic structure's surface, a localized surface plasmon of nanoparticles, and a standing-wave effect contribute to the enhancement.

• 분석과학
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• 제18권6호
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• pp.460-468
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• 2005

The biotin-avidin complex, as a model recognition system, has been constructed through N-hydroxysuccinimide(NHS) reaction on a variety of substrates such as a smooth Au film, electrochemically roughened Au electrode and chemically modified mica. Stepwise self-assembled monolayers (SAMs) of biotin-avidin system were characterized by surface-enhanced resonance Raman scattering (SERRS) spectroscopy, atomic force microscopy (AFM) and surface plasmon resonance (SPR). A strong SERRS signal of rhodamine tags labeled in avidin from the SAMs on a roughened gold electrode indicated the successful complex formation of stepwise biotin-avidin recognition system. AFM images showed the circular shaped avidin aggregates (hexamer) with ca. $60{\AA}$ thick on the substrate, corresponding to one layer of avidin. The surface coverage and concentration of avidin molecules were estimated to be 90% and $7.5{\times}10^{-12}mol/cm^2$, respectively. SPR technique allowed one to monitor the surface reaction of the specific recognition with high sensitivity and precision.