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Monitoring of Uniconazole by Using GC-ECD and GC-MSD (GC-ECD와 GC-MSD를 이용한 유니코나졸 잔류실태조사)

  • Kim, Eun-Jeung;Hong, Chae-Kyu;Choi, Su-Jeong;Lee, Yun-Jeong;Hwang, In-Sook;Kim, Moo-Sang;Chae, Young-Zoo
    • Korean Journal of Food Science and Technology
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    • v.45 no.3
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    • pp.382-384
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    • 2013
  • We evaluated the presence of uniconazole residual pesticide in agricultural products by using multiclass pesticide multiresidue methods. Samples were collected from January to August, 2012. The pesticide was detected in 14 samples among the 3,632 samples tested. Amount of the uniconazole pesticide ranged from 0.098 to 2.2 mg/kg in the 14 samples. This method was described for the simultaneous determination of uniconazole by using gas chromatography with an electron capture detector (GC-ECD) and mass spectrometry (MS). For evaluating the GC-ECD method, uniconazole was spiked into gyeojachae at a level of 0.05, 0.5 mg/kg. The recoveries of uniconazole with the GC-ECD method ranged from 98.9-109.4%. The results indicate that our method of simultaneous analysis is applicable to uniconazole analysis.

Improvement of Determination Method for Propionic Acid in Bakery Products (빵의 프로피온산 함량 분석방법 개선)

  • Lee, Sung-Deuk;Kim, Yeon-Sun;Doo, Ok-Joo;Kim, Mi-Sun;Park, Young-Hae;Kim, Il-Young;Chae, Young-Zoo
    • Journal of Food Hygiene and Safety
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    • v.24 no.4
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    • pp.332-337
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    • 2009
  • Most propionic acid is added to food (especially breads) as preservatives and its form is sodium or calcium salt. Most countries admitted propionic acid as food preservatives but a tolerance limit is somewhat different according to countries. Recoveries of the official method for propionates reported as 50.0~60.0%. Accordingly new rapid determination method for propionates was developed using formic acid added sodium chloride (5 g) and ether (formic acid : ether = 1 : 2) as the extraction solvent to improve the official method with the complex processes. Propionate was dissolved from the samples with formic acid omitting steam distillation and ion exchange procedure. Then propionate in formic acid was extracted with ether and sodium chloride again. A $1\;{\mu}l$ aliquot of the filtrate of ether was analyzed by gas chromatograph. Recoveries from sample A and B fortified with propionic acid sodium salt were 85.0 % and 90.0 %, respectively.

Assessment for the Possibility of Water-ecosystem Restoration Applying LID Techniques in the Deokjin Park Area, Jeonju City (LID기법을 이용한 전주 덕진공원의 수생태 복원 가능성 평가)

  • Choi, Seung-Hyun;Kim, Seok-Hwi;Kim, Kangjoo
    • Economic and Environmental Geology
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    • v.48 no.6
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    • pp.477-490
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    • 2015
  • In this study, we investigated the restoration possibility of the old streams by enhancing the rainwater infiltration in the watershed of Deokjin Park, Jeonju City. This study was performed by modeling groundwater discharge to the streams under various conditions. We assessed the amount and location of groundwater recharge enhancement to restore the streams and evaluated whether the baseflows of the restored streams are sufficient to keep the water ecosystem of the Deokjin Pond. The results show that the baseflow of the streams can persist for a longer time even during the dry season when the rainwater drainage system is recovered similarly to the those before development using low impact development (LID) techniques. The enhancements of recharge in the headwater area, which is the area around the zoo and Daeji Village in the Deokjin Park watershed, is useful to increase the baseflows of the downstream reaches. Furthermore, spreaded recharge over a widespread area is better to prevent the streams from drying than the intensive recharge at a few sites.

Determination of Six Sweeteners in Children's Favorite Foods by HPLC-MS/MS (HPLC-MS/MS를 이용한 어린이 기호식품중의 감미료 분석)

  • Kim, Il-Young;Du, Ok-Ju;Lee, Sung-Dck;Park, Young-He;Kim, Mi-Sun;Bea, Chung-Ho;Chae, Young-Zoo
    • Journal of Food Hygiene and Safety
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    • v.25 no.2
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    • pp.118-121
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    • 2010
  • A HPLC-MS/MS method was developed for simultaneous determination of six sweeteners (acesulfame-K, cyclamate, saccharin, sucralose, stevioside, aspartame) in children's favorite foods. The procedure involves an extraction of the six sweeteners with 50% methanol solution, sample clean-up using the Carrez clearing reagent and filtering with cartridge filter. The HPLC separation was performed on a Hypersil Gold (150 mm ${\times}$ 2.1 mm 5 um) column using the water/acetonitrile mobile phase (95:5). Mass spectrometric analysis was carried out using the TSQ Quantum Ultra operated in negative and positive ESI/SRM. With this method, good linear relationship, sensitivity and reproducibility were obtained. The spike recoveries of six sweeteners for 2 kinds of foods spiked into 0.4 mg/ kg ranged from 87.4 to 114.7%. The detection limits were above 0.02 mg/kg. The method has been applied to determination of six sweeteners in children's favorite foods.

The Determination of Perfluorooctane sulfonate in Food Packing Materials by HPLC-MS/MS (식품 포장재 중의 퍼플루오르옥탄설포네이트 분석)

  • Kim, Il-Young;Kim, Au-Kyoung;Jung, Bo-Kyoung;Shin, Young;Kim, Ji-Young;Kim, Jung-Han;Chae, Young-Zoo
    • Journal of Food Hygiene and Safety
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    • v.28 no.4
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    • pp.376-380
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    • 2013
  • Determination of PFOS in instant food packing materials by LC-MS/MS was developed. The procedure involves an extraction of the Food Packing Materials with 100% methanol soxcelet extraction method. The LC separation was performed by Hypersil Gold ($150mm{\times}2.1mm$ 5 um) with mobile phases of 2 mM amoniumacetate solution and acetonitrile. The Mass spectral acquisition was done in negative ESI/SRM using the TSQ Quantum Ultra. With this method, good linear relationship, sensitivity and reproducibility were obtained. The rate of recoveries of PFOS from paper material spiked with 1.0 ug/L were 99.84%, respectively. The limit of quantitation and limit of detection were below 0.03 ug/L and 0.009 ug/L. The method had been applied to determination of PFOS in instant food packing materials.

Chemical Characteristics of Raspberry and Blackberry Fruits Produced in Korea (국내산 나무딸기류 과일의 화학적 특성)

  • Oh, Hyun-Hee;Hwang, Keum-Taek;Kim, Mu-Yeol;Lee, Hee-Kwon;Kim, Sung-Zoo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.6
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    • pp.738-743
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    • 2008
  • In this study, 20 kinds of raspberries and blackberries, cultivated or wild in Korea, were collected. Weight, moisture content, sugar content, sugar composition, pH, titratable acidity and acid composition of the fruits were determined. Weight of each of the fruits and moisture contents in the fruits were $0.9{\sim}7.8g$ and $26{\sim}62%$, respectively. The sugar contents in the fruit juices were $6.9{\sim}16.9%$ (Brix). The major sugars in the fruits were glucose ($40.7{\sim}84.0%$ (w/w) of the total sugars) and fructose ($6.5{\sim}57.5%$). Sucrose and xylose were also detected in a small quantity. pH and titratable acidity of the berry juices were $2.8{\sim}3.9%$ (w/v, citric acid) and $0.6{\sim}2.9%$, respectively. The major organic acids were citric acid ($14.6{\sim}87.5%$ (w/w) of the total acids) and malic acid ($9.6{\sim}87.1%$). Succinic, tartaric and oxalic acids were also detected in a small amount.

A Case of Podostroma Cornu-Damae Intoxication Induced Pancytopenia and Skin Desquamation: Successful Treatment with Granulocyte Colony Stimulation Factor (G-CFS) (과립구집락자극인자 투여로 치료한 범혈구감소증과 피부 박리를 보인 붉은사슴뿔버섯 중독 1례)

  • Kim, Jung Seok;Kim, Gyu Won;Chung, Jae Il;Sim, Myoung Ki;Yoon, Ki Chul;Choi, Yong Hoon;Yi, Ha Ram;Choi, In Zoo;Shim, Chan Sup;Han, Joung Ho
    • Journal of The Korean Society of Clinical Toxicology
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    • v.13 no.1
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    • pp.50-54
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    • 2015
  • Podostroma cornu-damae is a rare species of fungus belonging to the Hyocreaceae family. Its fruit body is highly toxic, as it contains trichothecene mycotoxins. The morphology is similar to that of immature Ganoderma lucidum, making identification difficult for non-experts. We experienced such a case of a 56- year-old male who picked and consumed podostroma cornu-damae, and consumed. Later that day, he developed digestive system symptoms, including nausea, vomiting, and abdominal pain. He presented to the emergency room (ER), there were no abnormal physical findings, symptoms improved after gastric lavage, and the patient voluntarily discharged himself on the same day. The following day, as the symptoms gradually deteriorated, he was admitted via the ER. He was presented with severe pancytopenia, alopecia, desquamation of skin, and acute renal failure. He recovered without any complications after conservative care, antibiotics therapy, and granulocyte colony stimulating factor administration. The most commonly reported complications of podostroma cornu-damae intoxication were reported pancytopenia, infection, disseminated intravascular coagulation, acute renal failure, etc. since Prevention is especially important because its toxicity can be lethal and there is no particular treatment to date, prevention is especially important. Promotion and education for the public are needed.

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Medical Information Privacy Concerns in the Use of the EHR System: A Grounded Theory Approach (의료정보 프라이버시 염려에 대한 근거이론적 연구: 전자건강기록(EHR) 시스템을 중심으로)

  • Eom, Doyoung;Lee, Heejin;Zoo, Hanah
    • Journal of Digital Convergence
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    • v.16 no.1
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    • pp.217-229
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    • 2018
  • Electronic Health Record (EHR) systems are widely adopted worldwide in hospitals for generating and exchanging records of patient information. Recent developments are moving towards implementing interoperable EHR systems that enable information to be shared seamlessly across healthcare organizations. In this context, this paper explores the factors that cause medical information privacy concerns, identifies how people react to privacy invasion and what their perceptions are towards the acceptance of the EHR system. Interviews were conducted to draw a grounded theory on medical information privacy concerns in the use of EHRs. Medical information privacy concerns are caused by perceived sensitivity of medical information and the weaknesses in security technologies. Trust in medical professionals, medical institutions and technologies plays an important role in determining people's reaction to privacy invasion and their perceptions on the use of EHRs.

Dystocia Causing Postrenal Azotemia in a Captive Spotted Hyena (Crocuta Crocuta) (점박이 하이에나에서 신후성 질소혈증을 유발한 난산 증례)

  • Han, Jae-Ik;Kim, Jeong-Ho;Lee, Sook-Jin;Lee, Jong-Won;Han, Sang-Hui;Na, Ki-Jeong;Kim, Ill-Hwa;Kang, Hyun-Gu
    • Journal of Veterinary Clinics
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    • v.27 no.5
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    • pp.614-617
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    • 2010
  • A 3-year-old, female spotted hyena (Crocuta crocuta) was referred with dystocia. The hyena had been in labor for over 5 days, but she failed to expel the infant. The blood biochemistry profiles showed severe azotemia. During caesarian section, we confirmed that the uterus had expanded and contained 1 dead, decayed infant, which compress the urethra, leading to the expansion of the urinary bladder and that the dead fetus was nearly 3 kg in weight (approximately 5% of the maternal weight). Thus, we confirmed that the dystocia caused by oversized fetus and malposture, and the severe azotemia resulted in compression of the urethra by fetus in the hyena. This report is the first to show that the dystocia can induce postrenal azotemia in female spotted hyenas.

Evaluation of Residual Pesticides in Fresh Ginseng Collected in Seoul

  • Kim, Tae-Rang;Park, Ki-Hwan;Jang, Mi-Ra;Choi, Young-Hee;Kim, Eun-Hee;Choi, Chae-Man;Park, Sung-Kyu;Yu, In-Sil;Hwang, In-Sook;Han, Ki-Young;Kim, Moo-Sang;Kim, Jung-Hun;Chae, Young-Zoo
    • Journal of Applied Biological Chemistry
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    • v.56 no.1
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    • pp.29-35
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    • 2013
  • This study was performed to analyze 48 kinds of pesticide residues using gas chromatography (GC)/nitrogen phosphorous detector, GC/micro electron capture detector, GC/mass selective detector, and high performance liquid chromatograph/diode array detector in 186 fresh ginseng samples collected in the Seoul area from 2010 to 2011. Fresh ginseng dietary intakes were estimated using the data from the 2009 Korea National Health and Nutrition examination survey. Residual pesticides were detected in 79 samples (42.5%) with eight different fungicides. Only 20 samples (10.8%) exceeded the maximum residue limits (MRLs) for pesticides registered by the Korea Food & Drug Administration. Among them, tolclofos-methyl residues (10.2%) exceeded the MRL for fresh ginseng in 18 ginseng seedlings and one of the two-year old fresh ginseng plants, and the residual level in just one ginseng seedling violated the MRL for pyrimethanil. The results showed that residual pesticides levels in marketable fresh ginseng around Seoul were relatively safe. The percent acceptable daily intake (%ADI) was calculated using pesticide residues in fresh ginseng and dietary intakes of fresh ginseng. The risk caused by pesticide residues in fresh ginseng was very low.