• Korean Journal of Pharmacognosy
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• v.22 no.1
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• pp.33-35
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• 1991

Heavy metals may cause trouble(s) in human body. For consideration of the safety of crude drugs cultivated in Korea, we selected some medicinal plants and soils from cultivated site and estimated their heavy metal contents by inductively coupled argon plasma spectrometry (ICAP). Among heavy metals tested, the highest level of Cu and Zn were shown in plants cultivated in Kyung Ki; the highest level of Fe in those in Youngnam and the highest level of Mg and Mn in those in Youngdong. The heavy metal content s were as low as to be permeasible at least for the medicinal plants we selected. There were no significant correlations between heavy metal contents of soils and cultivated medicinal plants.

• Journal of the East Asian Society of Dietary Life
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• v.15 no.4
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• pp.465-474
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• 2005

This study was conducted to estimate the contents of heavy metals 'mercury(Hg), cadmium(Cd), lead(Pb), arsenic(As), zinc(Zn), copper(Cu), chrome(Cr) and manganese(Mn)' in root vegetables which were produced in Korea. The levels of heavy metals were determined using a mercury analyzer, an ICP(inductively coupled plasma spectrometer) and an AAS(atomic absorption spectrophotometer) after wet digestion. The values of heavy metals 'mean(minimum-maximum)' mg/kg(ppm) in root vegetables (radish, turnip, carrot, ginger, edible burdock, taro, Chinese yam, east indian lotus) were as follows ; Hg : 0.0019(0.0002${\~}$0.0062), Cd : 0.0088(ND${\~}$0.0402), Pb : 0.021(ND${\~}$0.1070), As : 0.0401(ND${\~}$0.1732), Zn : 1.865(0.4186${\~}$6.9319), Cu : 0.648 (0.1826${\~}$4.0172), Cr : 0.121(0.0132${\~}$1.2030), and Mn : 2.730(0.0477${\~}$10.0468) mg/kg. These results showed that Hg were generally similar to and Cd was lower but Ph, As, Zn, Co, Mn were little higher than the levels of those reported contents in root vegetables on retail markets in Korea. Although the tolerable limit of Cd and Hg is not set in a regulation of WHO/FAO, the tested mean levels(Pb, As, Zn, Cu) were lower than the regulated ones of WHO/FAO, Pb '0.1-2.0', As '1.0', Zn '5.0', and Cu 0.1${\~}$50 mg/kg from vegetables. Therefore, root vegetables sold in the retail markets were evaluated as safe in terns of the heavy metal contents.

• Korean Journal of Community Nutrition
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• v.16 no.5
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• pp.569-579
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• 2011

The purpose of this study was to determine the urinary Ca, P, Mg, Zn, Cu, and Mn levels and bone mineral density (BMD) in sixty-two postmenopausal women. The study was conducted through anthropometric checkup, 24-hour recall, 24-hour urine and bone mineral density using DEXA. Average age, height, weight and body fat of the subjects were respectively 65.39 years, 150.19 cm, 58.03 kg and 37.22%. The average spine and femoral neck BMD of subjects were -2.19, -3.13. The mean intakes of Ca, P and Mg were 524.7 mg, 993.10 mg, and 254.6 mg and those of Zn, Cu and Mn were 8.6 mg, 1.5 mg, and 3.5 mg. The average 24-hour urinary excretion of Ca (UCa), P (UP) and Mg (UMg) were 161.07 mg, 673.68 mg, and 99.87 mg. The average 24-hour urinary excretion of Zn (UZn), Cu (UCu) and Mn (UMn) were 366.50 ${\mu}g$, 22.57 ${\mu}g$, and 1.55 ${\mu}g$. Ca intake showed significantly positive correlations with urinary UCa (p < 0.05), UMg (p < 0.01) and spine BMD (p < 0.05). P intake showed significantly positive correlations with UCa (p < 0.05), UMg (p < 0.05) and UZn (p < 0.05). Mg intake showed significantly positive correlations with UZn (p < 0.05) and Mn intake showed significantly positive correlations with UCa (p < 0.05). Multiple regression analysis indicates that Ca intake and UMg is the most important factor to increase spine BMD. On the other hand, UCa is the most important factor to decrease spine BMD. Higher femoral neck BMD was related to UP, while lower femoral neck BMD was related to UCa. In conclusion, Dietary intake of Ca showed positive effect of spine BMD, while excessive P intake showed negative effect on BMD due to increases in UCa, UMg and UZn. Further studies are required to investigate the relationship between bone metabolism and mineral excretion.

• The Korean Journal of Mycology
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• v.21 no.1
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• pp.23-27
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• 1993

Ion effects on $11{\alpha}-hydroxylation$ of progesterone and $5{\alpha}-reduction\;of\;11{\alpha}-hydroxyprogesterone$ by Rhizopus nigricans were investigated. Metal ions such as $Cu^{2+},\;Cd^{2+},\;Co^{2+},\;Mn^{2+},\;Zn^{2+},\;Fe^{2+},\;Mg^{2+},\;Fe^{3+}\;and\;Na^+$ reduced the $11{\alpha}-hydroxylation$ activity, while $K^+$ stimulated the same reaction. Enzyme activity for the $5{\alpha}-reduction$ of $11{\alpha}-hydroxyprogesterone$ was increased in the presence of $Fe^{2+},\;Mn^{2+},\;Mg^{2+},\;Co^{2+},\;Zn^{2+},\;Fe^{3+},\;K^+\;and\;Na^+$, whereas it was decreased in the presence of $Cd^{2+}\;and\;Cu^{2+}$. Potassium ion of $10^{-3}\;M\;$ of concentration was found to be effective for the promotion of $11{\alpha}-hydroxylation$. On the other hand, cadmium ion of $10^{-4}\;M$ was proved to suppress the $5{\alpha}-reduction$ reaction. Progesterone is reported to be transformed into $11{\alpha}-hydroxyprogesterone$ which, in turn, is converted further into $11{\alpha}-hydroxy-allopregnane-3$, 20-dione by R. nigricans. From this point of view, the highest yield of $11{\alpha}-hydroxyprogesterone$ could be obtained when potassium ion of $10^{-3}\;M$ was given initially followed by addition of cadmium ion of $10^{-4}\;M$ to limit conversion of 11{\alpha}-hydroxyprogesterone into $11{\alpha}-hydroxy-allopregnane-\;3$, 20-dione.

• Economic and Environmental Geology
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• v.36 no.2
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• pp.111-121
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• 2003

The objective of this study is to investigate the physical and chemical properties for environmental assessment of water system affected by acid mine drainage (AMD) from coal mining activities in the Youngwol, Jungseon and Pyungchang areas in Korea. During November 2000 to July 2002, 6 times of water samples were collected season-ally from acid mine drainage and nearby streams at 13 coal mines in the study area. The physical and chemical properties including pH, Eh, TDS, salinity, bicarbonates and DO were measured in the field. Eighteen cations includ-ing Al, Ca, Fe, Mg, Mn and Zn, and 6 anions including nitrates and sulfates were also analyzed by ICP-AES and If, respectively. Acid water from the Jungam coal mine has typical characteristics of AMD with very low pH(3∼4) and high TDS(1,000∼5,000 mg/1). Relatively high concentrations(mg/kg) of heavy meals, especially for Al(380), Fe(80), Mn(44) and Zn(8), were found in water samples from the Jungam coal mine area. Water samples from the Seojin, Sebang and Sungjin coal mines also contained over 50 mg/l of Al, >100 mg/1 of Fe and )10 mg/1 of Mn. In addition to anioins, over 1,000 mg/l of sulfate was found in several water samples. Seasonally, the concentrations of metals and sulfates varied; wet season samples were relatively higher in metals and sulfates than dry season samples. It is needed to establish the proper remediation and environmental monitoring of the AMD continuously.

• Journal of Bio-Environment Control
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• v.19 no.2
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• pp.70-76
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• 2010

To investigate the ground water quality status for paprika hydroponics for export, its pH, EC (electrical conductivity) and inorganic ion concentrations were analyzed in Gangwan-do (27 samples), Gyeonsangnam-do (77 samples) and Jeollanam-do (54 samples) from November 2008 to September 2009. The average values of several components in ground water were as follows; 7.20 (6.57~7.54) in pH, 0.31 (0.05~0.49) $dS{\cdot}m^{-1}$ in EC, 97.81 (35.37~161.11) in $HCO_3$, 5.68 (0.45~15.48) in T-N, 0.67 (0.15~0.70) in P, 2.53 (0.59~6.70) in K, 35.68 (4.15~80.70) in Ca, 7.35 (1.46~14.87) in Mg, 17.89 (3.31~34.82) in Na, 0.01 (0~0.05) in Fe, 0.09 (0~0.51) in Mn, 0.06 (0~0.07) in Zn, and 0.03 (0~0.10) $mg{\cdot}L^{-1}$ in Cu, respectively. The values of pH, EC, $HCO_3$, Ca, Mg and Na in ground water were different depending on areas and farms. Frequency rates were 92.6% of pH 5.0~8.0, 89.3% of EC < 0.5 $dS{\cdot}m^{-1}$, 69.5% of $HCO_3$ < 100, 97.5% of Na < 30, 88.5% of Ca < 40, 97.5% of Mg < 20, 90.1% of Fe < 0.05, 99.6% of Mn < 0.6, and 98.3% of Zn < 0.5 $mg{\cdot}L^{-1}$, respectively, which can be used for nutrient fertilizers in hydroponics. The percentage of suitable water quality was 46.3% as 70 sites among the all analyzed ions. The pH value showed high significance of correlations with EC, Mg, $HCO_3$, Na, and Fe. Also the EC value showed high positive significance with T-N, K, Ca, Mg, $HCO_3$, Na and Mn.

• Journal of the Mineralogical Society of Korea
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• v.17 no.4
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• pp.309-325
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• 2004

The Cannington Ag-Pb-Zn deposit, northwest Queensland, Australia developed around the host rocks composing banded and migmatitic gneisses, sillimanite-garnet schist and amphibolite. Three crystal habits of sillimanite, gahnite (Zn-spinel) and garnet porphyroblasts occurred on the host rocks of the Cannington deposit could be used to delineate metamorphism that closely associated with Zn-mineralization in the deposit. Linkages the metamorphism to Zinc-mineralization is determined in four chemical systems, KFMASH (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$), KFMASHTO (K$_2$O-FeO-MgO-Al$_2$O$_3$-SiO$_2$-$H_2O$-TiO$_2$-Fe$_2$O$_3$), NCKFMASH (Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$) and MnNCK-FMASH (MnO-Na$_2$O-CaO-K$_2$O-FeO-MgO-AlO$_3$-SiO$_2$-$H_2O$), using THERMOCALC program (version 3.1; Powell and Holland 1988). Partial melting in MnNCKFMASH and NCKFMASH systems occurs at lower temperature than in the KFMASH and KFMASHTO systems. The partial melting temperature decreases with increasing of Na/(Na+Ca+K) of the bulk rock compositions in the MnNCKFMASH system. The host rocks have melted ca 15 vol.% in the MnNCKFMASH system at peak metamorphic conditions (634$\pm$62$^{\circ}C$ and 4.8$\pm$1.3 kbar), but partial melting have not occurred in KFMASHTO system. Based on calculations of sillimanite isograd in different systems and sillimanite modal pro-portion, prismatic and rhombic sillimanite and gahnite porphyroblasts including prismatic sillimanite inclusion probably have resulted from pressure and temperature increasing through partial melting (from 550～$600^{\circ}C$, 2.0～3.0 kbar to 700～75$0^{\circ}C$, 5.0～7.0 kbar), furthermore have experienced N-S then W-E crustal shortening during D$_1$ and D$_2$ deformation. Consequently, Zinc mineralization related to gahnite growth occurred during D$_2$ and was redistributed and upgraded by partial melting and retrograde metamorphism into structural and rheological sites during shearing in D$_3$.

• Economic and Environmental Geology
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• v.56 no.4
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• pp.409-419
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• 2023

Acid mine drainage(AMD) treatment is classified as both passive and active treatment. During the treatment, about 5,000 tons of neutralization sludge is generated as a by-product per year in Korea. This study was conducted to evaluate the characteristics of sludge generated from physico·chemical treatment processes as an active treatment from 5 different sources (D, H, S, T, Y) and the possibility of the sludges being recycled. The sludges have a pH range of 5.86 ~ pH 7.89, and a water content range of 51% ~ 82%. Most of particle sizes were less than 25 ㎛. In analysis of inorganic elements, the concentration of Al, Fe, and Mn were between 1,189 mg/kg ~ 129,344 mg/kg, 106,132 mg/kg ~ 338,011 mg/kg, and 3,472 mg/kg ~ 11,743 mg/kg, respectively. The concentration of As and Zn in sludge-T, Cd in sludge-D, Ni in sludge-H, Zn in sludge-S, and Cd in sludge-Y exceeded the soil contamination standards of Korea. The results from 2 separate kinds of leaching test, the Korea Standard Leaching Test(KSLT) and Toxicity Characteristic Leaching Procedure(TCLP), showed that all the sludges met the Korea groundwater standards. From the XRD and SEM-EDS analysis, the peaks of calcite and quartz were found in the sludges. The sludge also had a high proportion of Fe and O, and the majority of the composition was amorphous iron hydroxide.

• Journal of the Korean Society of Food Science and Nutrition
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• v.14 no.3
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• pp.289-295
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• 1985

This experiment aimed to find out the most effective condition of drawing method when making tea by determination of the contents of minerals infused from four kinds of green tea samples of market with its different drawing time and temperature. The mineral contents in 100 grams of raw green tea leaves revealed $1737{\sim}3000\;mg$ potassium, $178{\sim}205\;mg$ magnesium, $171{\sim}201\;mg$ calcium, $54{\sim}71\;mg$ manganese, $24{\sim}50\;mg$ sodium, $11.6{\sim}12.3\;mg$ iron, $3.4{\sim}5.3\;mg$ copper and $4.6{\sim}5.9\;mg$ zinc. The values showed some variation in their contents according to the kinds of raw green tea samples. The decreasing order of the amounts of minerals infused from the green tea samples was K, Zn, Mg, Mn, Fe, Na, Cu and Ca. The amount of minerals infused from the green tea leaves increased with increase in the drawing time and temperature. The total infusion amount of minerals was remarkably larger when drawing time was three minutes with three times repetition than when it was eight minutes without repetition at the same temperature.

• Journal of Mushroom
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• v.3 no.3
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• pp.100-104
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• 2005

We investigated mineral difference from mushroom Phellinus linteus and Phellinus baumii on mulberry, oak and elm. ICP test, The major mineral components were K, Ca, and Fe, while Mg, Na, P, Cr, Mn, Cu and Zn were determined as micro mineral components. In case of P.linetus and P.baumii the component of K was shown as 699.0mg/100g and 630mg/100g, in oak, 340.7mg/100g and 314.6mg/100g in elm, and 311.6mg/100g and 311.6mg/100g in mulberry respectively. In Ca, mulberry fruiting body were shown about 2 times highest and expecially in case of Na was oak fruiting body were shown as 10 times highest as against the others sample groups. In micro mineral components, Zn component was shown very diffeence about sample groups. We concluded that the highest mineral component of K was shown in mushroom cultivated on oak of both P.linetus and P.baumii. As a results, mineral component has showed very difference on cultivated to timber. According to the results of mineral component we concluded that Phellinus linteus and Phellinus baumii has mineral component different depending on timber.