• Title/Summary/Keyword: Zirconium hydride

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Development and testing of the hydrogen behavior tool for Falcon - HYPE

  • Piotr Konarski;Cedric Cozzo;Grigori Khvostov;Hakim Ferroukhi
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.728-744
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    • 2024
  • The presence of hydrogen absorbed by zirconium-based cladding materials during reactor operation can trigger degradation mechanisms and endanger the rod integrity. Ensuring the durability of the rods in extended time-frames like dry storage requires anticipating hydrogen behavior using numerical modeling. In this context, the present paper describes a hydrogen post-processing tool for Falcon - HYPE, a PSI's in-house tool able to calculate hydrogen uptake, transport, thermochemistry, reorientation of hydrides and hydrogen-related failure criteria. The tool extracts all necessary data from a Falcon output file; therefore, it can be considered loosely coupled to Falcon. HYPE has been successfully validated against experimental data and applied to reactor operation and interim storage scenarios to present its capabilities.

Shield Material Consideration in the LAR Tokamak Reactor

  • Hong, B.G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.314-314
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    • 2010
  • For the optimal design of a tokamak-type reactor, self-consistent determination of a radial build of reactor systems is important and the radial build has to be determined by considering the plasma physics and engineering constraints which inter-relate various reactor systems. In a low aspect ratio (LAR) tokamak reactor with a superconducting toroidal field (TF) coil, the shield should provide sufficient protection for the superconducting TF coil and the shield plays a key role in determining the size of a reactor. To determine the radial build of a reactor, neutronic effects such as tritium breeding in the blanket, nuclear heating, and radiation damage to toroidal field (TF) coil has to be included in the systems analysis. In this work, the outboard blanket only is considered where tritium self-sufficiency is possible by using an inboard neutron reflector instead of breeding blanket. The reflecting shield should provide not only protection for the superconducting TF coil but also improved neutron economy for the tritium breeding in outboard blanket. Tungsten carbide, metal hydride such as titanium hydride and zirconium hydride can be used for improved shielding performance and thus smaller shield thickness. With the use of advanced technology in the shield, conceptual design of a compact superconducting LAR reactor with aspect ratio of less than 2 will be presented as a viable power plant.

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Development of Integrity Evaluation System for CANDU Pressure Tube (CANDU 압력관에 대한 건전성 평가 시스템 개발)

  • Kwak, Sang-Log;Lee, Joon-Seong;Kim, Young-Jin;Park, Youn-Won
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.843-848
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    • 2000
  • The pressure tube is a major component of the CANDU reactor, which supports nuclear fuel bundle and it's containment vessel. If a flaw is found during the periodic inspection from the pressure tubes, the integrity evaluation must be carried out, and the safety requirements must be satisfied for continued service. In order to complete the integrity evaluation, complicated and iterative calculation procedures are required. Besides, a lot of data and knowledge for the evaluation are required for the entire integrity evaluation process. For this reason, an integrity evaluation system, which provides efficient way of evaluation with the help of attached databases, was developed. The developed system was built on the basis of ASME Sec. XI and FFSG(Fitness For Service Guidelines for zirconium alloy pressure tubes in operating CANDU reactors) issued by the AECL, and covers the delayed hydride cracking(DHC). Various analysis methods are provided for the integrity evaluation of pressure tube. In order to verify the developed system, several case studies have been performed and the results were compared with those from AECL. A good agreement was observed between those two results.

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Rapid Cooling Performance Evaluation of a ZrCo bed for a Hydrogen Isotope Storage (수소동위원소 저장용 ZrCo용기의 급속 냉각 성능 평가)

  • Lee, Jungmin;Park, Jongchul;Koo, Daeseo;Chung, Dongyou;Yun, Sei-Hun;paek, Seungwoo;Chung, Hongsuk
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.128-135
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    • 2013
  • The nuclear fuel cycle plant is composed of various subsystems such as a fuel storage and delivery system (SDS), a tokamak exhaust processing system, a hydrogen isotope separation system, and a tritium plant analytical system. Korea is sharing in the construction of the International Thermonuclear Experimental Reactor (ITER) fuel cycle plant with the EU, Japan, and the US, and is responsible for the development and supply of the SDS. Hydrogen isotopes are the main fuel for nuclear fusion reactors. Metal hydrides offer a safe and convenient method for hydrogen isotope storage. The storage of hydrogen isotopes is carried out by absorption and desorption in a metal hydride bed. These reactions require heat removal and supply respectively. Accordingly, the rapid storage and delivery of hydrogen isotopes are enabled by a rapid cooling and heating of the metal hydride bed. In this study, we designed and manufactured a vertical-type hydrogen isotope storage bed, which is used to enhance the cooling performance. We present the experimental details of the cooling performances of the bed using various cooling parameters. We also present the modeling results to estimate the heat transport phenomena. We compared the cooling performance of the bed by testing different cooling modes, such as an isolation mode, a natural convection mode, and an outer jacket helium circulation mode. We found that helium circulation mode is the most effective which was confirmed in our model calculations. Thus we can expect a more efficient bed design by employing a forced helium circulation method for new beds.

Development of CANDU Pressure Tube Integrity Evaluation System;Its Application to Sharp Flaw and Blunt Notch (CANDU 압력관에 대한 건전성 평가시스템 개발;예리한 결함 및 둔한 노치에의 적용)

  • Gwak, Sang-Rok;Lee, Jun-Seong;Kim, Yeong-Jin;Park, Yun-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.1 s.173
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    • pp.206-214
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    • 2000
  • The pressure tube is a major component of the CANDU reactor, which supports nuclear fuel bundle and it's containment vessel. If a flaw is found during the periodic inspection from the pressure tube s. the integrity evaluation must be carried out. and the safety requirements must be satisfied for continued service. In order to complete the integrity evaluation, complicated and iterative calculation procedures are required. Besides, a lot of data and knowledge for the evaluation are required for the entire: integrity evaluation process. For this reason. an integrity evaluation system, which provides efficient of evaluation with the help of attached databases, was developed. The developed system was built on the basis of ASME Sec. XI and FFSG(Fitness For Service Guidelines for zirconium alloy pressure tubes in operating CANDU reactors) issued by the AECL, and covers the delayed hydride cracking(DHC). This system does not only provide various databases including the 3-D finite element analysis results on pressure tubes, inspection data and design specifications but also is compatible with other commercial database software. In order to verify the developed system, several case studies have been performed and the results were compared with those from AECL. A good agreement was observed between those two results.

Formation and Growth Estimation of Blister in Zr-2.5Nb Pressure Tubes based on Finite Element Analysis (유한요소해석을 이용한 지르코늄 압력관의 블리스터 생성 및 성장 해석)

  • Huh, Nam-Su;Kim, Yun-Jae;Kim, Young-Jin;Kim, Young-Seok;Cheong, Yong-Moo
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1133-1138
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    • 2003
  • The pressure tubes, which contain high temperature heavy water and fuel, are within the core of a CANDU nuclear reactor, and are thus subjected to high stresses, temperature gradient, and neutron flux. Further, it is well known that pressure tubes of cold-worked Zr-2.5Nb materials result in hydrogen diffusion, which create fully-hydrided regions (frequently called Blister). Thus a proper investigation of hydrogen diffusion within zirconium-alloy nuclear components, such as CANDU pressure tube and fuel channels is essential to predict the structural integrity of these components. In this respect, this paper presents numerical investigation of hydrogen diffusion to quantify the hydrogen concentration for blister growth of CANDU pressure tube. For this purpose, coupled temperature-hydrogen diffusion analyses are performed by means of two-dimensional finite element analysis. Comparison of predicted temperature field and blister with published test data shows good agreement.

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Design of an Organic Simplified Nuclear Reactor

  • Shirvan, Koroush;Forrest, Eric
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.893-905
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    • 2016
  • Numerous advanced reactor concepts have been proposed to replace light water reactors ever since their establishment as the dominant technology for nuclear energy production. While most designs seek to improve cost competitiveness and safety, the implausibility of doing so with affordable materials or existing nuclear fuel infrastructure reduces the possibility of near-term deployment, especially in developing countries. The organic nuclear concept, first explored in the 1950s, offers an attractive alternative to advanced reactor designs being considered. The advent of high temperature fluids, along with advances in hydrocracking and reforming technologies driven by the oil and gas industries, make the organic concept even more viable today. We present a simple, cost-effective, and safe small modular nuclear reactor for offshore underwater deployment. The core is moderated by graphite, zirconium hydride, and organic fluid while cooled by the organic fluid. The organic coolant enables operation near atmospheric pressure and use of plain carbon steel for the reactor tank and primary coolant piping system. The core is designed to mitigate the coolant degradation seen in early organic reactors. Overall, the design provides a power density of 40 kW/L, while reducing the reactor hull size by 40% compared with a pressurized water reactor while significantly reducing capital plant costs.

Numerical Modeling on the Dual Propellant Combustion in a Closed Vessel (밀폐용기 내 입자 혼합물(ZPP와 THPP)의 연소에 대한 수치해석적 모델링 및 해석)

  • Han, Doo-hee;Sung, Hong-gye;Kwon, Mi-ra;Ahn, Gil-hwan;Kim, Jun-hyung;Ryu, Byung-tae
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.451-455
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    • 2017
  • The reactive Eulerian-Lagrangian code is utilized to simulate combustion of ZPP/THPP in a closed vessel. In the paper, ignition delay of THPP is mainly studied since ZPP and THPP are isolated by a boron nitride wall. Only a numerical case study is conducted as experimental observation is inaccessible. Results showed THPP ignition delay affects initial shock strength thus not only the first peak become weak, but also the frequency of a pressure oscillation is slowed.

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Electrorefining of CuZr Alloy Using Ba2ZrF8-LiF Electrolyte

  • Lee, Seong Hun;Choi, Jeong Hun;Yoo, Bung Uk;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.27 no.12
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    • pp.672-678
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    • 2017
  • In the production of zirconium cladding tube, a pickling acid solution is used to remove surface contaminants, which generates tons of pickling acid waste. The waste pickling solution is a valuable resource of Hf-free Zr. Many studies have investigated separating the Hf-free Zr source from the waste pickling acid. The results showed that $Ba_2ZrF_8$ precipitates prepared from the waste pickling acid were useful as an electrolyte for the electrorefining of Zr in molten salt. In the present work, electrorefining was performed in a $Ba_2ZrF_8-LiF$ binary electrolyte to recover Zr from a Hf-free CuZr ingot anode prepared by electroreduction. Before electrorefining, two pretreatments are performed. First, electrolyte melting was carried out to determine the eutectic temperature, and second, the electrolyte was treated to eliminate impurities, mainly hydride. After electrorefining, the cathode deposits were analyzed by $O_2$ gas analyzer and SEM-EDX to explore the possibility of recovering nuclear-grade Zr metal. Moreover, the anode was analyzed by SEM-EDX to determine the Zr dissolution depth.

Finite Element Analysis of Hydrogen Concentration for Blister Growth Estimation of CANDU Pressure Tube (CANDU 압력관의 블리스터 성장 예측을 위한 유한요소 수소 확산 해석)

  • Huh, Nam-Su;Kim, Yun-Jae;Kim, Young-Jin;Kim, Young-Seok;Cheong, Yong-Moo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.2
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    • pp.189-195
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    • 2004
  • The pressure tubes, which contain high temperature heavy water and fuel, are within the core of a CANDU nuclear reactor, and are thus subjected to high stresses, temperature gradient, and neutron flux. Further, it is well known that pressure tubes of cold-worked Zr-2.5Nb materials result in hydrogen diffusion, which create fully-hydrided regions (frequently called Blister). Thus a proper investigation of hydrogen diffusion within zirconium-alloy nuclear components, such as CANDU pressure tube and fuel channels is essential to predict the structural integrity of these components. In this respect, this paper presents numerical investigation of hydrogen diffusion to quantify the hydrogen concentration fur blister growth of CANDU pressure tube. For this purpose, coupled temperature-hydrogen diffusion analyses are performed by means of two-dimensional finite element analysis. Comparison of predicted temperature field and blister with published test data shows good agreement.