• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.185-186
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• 2002

Fretting of fuel rod cladding material, Zircaloy-4 tube, in PWR nuclear power plants must be reduced and avoided. Nowadays the introduction of surface treatments or coatings is expected to be an ideal solution to fretting damage since fretting is closely related to wear. corrosion and fatigue. Therefore. in this study the fretting wear experiment was performed using TiAlN coated Zircaloy-4 tube as the fuel rod cladding and uncoated Zircaloy-4 as on of grids, especially concentrating on the sliding component. Fretting wear resistance of TiAlN coated Zircaloy-4 tubes was improved compared with that of TiN coated tubes and uncoated tubes and fretting wear mechanisms were brittle fracture and plastic flow at lower slip amplitude but severe oxidation and spallation of oxidative layer at higher ship amplitude.

• Nuclear Engineering and Technology
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• v.21 no.4
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• pp.341-345
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• 1989

The distribution behaviors of beryllium which may produce a deleterious damage in the zircaloy cladding have been investigated by the X-ray line scanning of EPMA. The results obtained are as follows; 1) The alloy phase formed by the brazing contains ~6.3 mass % of beryllium. 2) The beryllium diffusion in the base metal (cladding and bearing pad) is recognized only in the range ~5 $\mu$m from the brazing interface.

• Journal of Welding and Joining
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• v.20 no.6
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• pp.72-72
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• 2002

Corrosion and tensile properties of zircaloy-4 cladding tube having a laser welding part in elevated temperature are studied to present the criterion of quality evaluation in nuclear reactor and find the scientific basis of SCC, with laser welding method using by coupling up cladding tube to end cap. In the result of tensile test(400℃), the fracture is not happened in the welding part but base metal and the result of corrosion test(400℃ 1500psi steam), corrosion rate of the molten zone and PMZ is a little higher than the other zone.

• Journal of Welding and Joining
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• v.20 no.6
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• pp.796-801
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• 2002

Corrosion and tensile properties of zircaloy-4 cladding tube having a laser welding part in elevated temperature are studied to present the criterion of quality evaluation in nuclear reactor and find the scientific basis of SCC, with laser welding method using by coupling up cladding tube to end cap. In the result of tensile test($400^{\circ}C$), the fracture is not happened in the welding part but base metal and the result of corrosion test($400^{\circ}C$ 1500psi steam), corrosion rate of the molten zone and PMZ is a little higher than the other zone.

• Journal of the Korean Society for Heat Treatment
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• v.18 no.2
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• pp.112-118
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• 2005

Study was focused on the effect of the cooling rate on the embrittlement behavior of Zircaloy-4 cladding simulated Loss Of Coolant Accident (LOCA) environment. Claddings were oxidized at given temperature and given time followed by various water quenching in the range of $0.6^{\circ}C$ and $100^{\circ}C$ per second. Cladding failed after water quenching above the threshold oxidation. Threshold oxidation was decreased as the cooling rate increased, which is due to the matensite structure formed during fast cooling rate.

• Journal of the Korean institute of surface engineering
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• v.35 no.6
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• pp.363-370
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• 2002

Empirical equations for the oxide thickness and the weight gain of Zircaloy-4 cladding during the oxidation in high temperature, high pressure steam have been developed. Firstly, the empirical equations for oxide thickness in 1 atm steam in 700~100$0^{\circ}C$ were made, then, the enhancement factor for the steam pressure effects on Zircaloy-4 cladding oxidation in high temperature steam was added. Based on the analysis of the weight fraction of dissolved oxygen in metal layer, empirical equations for the weight gain of Zircaloy-4 in high pressure, high temperature steam were developed. We compare the developed empirical equations with the Baker-Just correlation. The Baker-Just correlation can give a non-conservative estimation of oxidation of Zircaloy-4, depending on the steam pressure. These developed empirical equations can be used for the correct estimation of oxidation of Zircaloy-4 during accident analysis.

• Corrosion Science and Technology
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• v.2 no.6
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• pp.253-259
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• 2003

Zirconium based alloys have been extensively used as a cladding material for fuel rods in nuclear reactors, due to their low thermal neutron absorption cross-section, excellent corrosion resistance and good mechanical properties at high temperatures. However, a cladding material for fuel rods in nuclear reactors was contact water during long time at high-temperature, so it is necessary to improve the wear and corrosion resistance of the fuel cladding, At ambient environment, there are few data or paper on the characteristic of corrosion in chloride solution and acidic solution. The specimens used in this work are pure Zr and Zircaloy-4. Zircaloy-4 is a specific zirconium-based alloy containing, on a weight percent basis, 1.4% Sn, 0.2% Fe, 0.1% Cr. Pitting corrosion resistance of two alloys by ASTM G48 is higher than that of electrochemical method. Passive film formed on Zircaloy-4 is mainly composed of $ZrO_2$, metallic Sn, and iron species regardless of formation environments. Also, passive film formed on Zr alloys shows n-type semiconductic property on the base of Mott-Schottky plot.

• Proceedings of the Korean Nuclear Society Conference
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• 2003.05a
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• pp.231.2-231.2
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• 2003

• Proceedings of the Korean Nuclear Society Conference
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• 1999.05a
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• pp.278-278
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• 1999

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.05a
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• pp.88-95
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• 2002

Fretting of fuel rod cladding material, Zircaloy-4 Tube, in PWR nuclear power plants must be reduced and avoided. Nowadays the introduction of surface treatments or coatings is expected to bean ideal solution to fretting damage since fretting is closely related to wear, corrosion and fatigue. Therefore, in this study the fretting wear experiment was peformed using TiAIN coated Zircaloy-4 tube as the fuel rod cladding and uncoated Zircaioy-4 tube as one of grids, especially concentrating on the sliding component. Fretting wear resistance of TiAIN coated Zircaloy-4 tubes was improved compared with that of TiN coated tubes and uncoated tubes and the fretting wear mechanisms were delamination and plastic flow following by brittle fracture at lower slip amplitude but severe oxidation and spallation of oxidative layer at higher slip amplitude.