• Title/Summary/Keyword: Zinc.

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Synthesis of Zinc Oxide Nanoparticle-(C60) Fullerene Nanowhisker Composite for Catalytic Degradation of Methyl Orange under Ultraviolet and Ultrasonic Irradiation

  • Ko, Jeong Won;Son, Yeon-A;Ko, Weon Bae
    • Elastomers and Composites
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    • v.55 no.4
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    • pp.321-328
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    • 2020
  • Zinc nitrate hexahydrate (Zn(NO3)2·6H2O) and sodium hydroxide (NaOH) were dissolved in distilled water and stirred for 30 min. The resulting solution was sonicated by an ultrasonic wave for 45 min. This solution was washed with distilled water and ethanol after centrifugation; next, it was placed in an electric furnace at 200℃ for 1 h under the flow of Ar gas to obtain zinc oxide nanoparticle. A zinc oxide nanoparticle-(C60) fullerene nanowhisker composite was synthesized using the zinc oxide nanoparticle solution, C60-saturated toluene, and isopropyl alcohol via the liquid-liquid interfacial precipitation method. The zinc oxide nanoparticle and zinc oxide nanoparticle-(C60) fullerene nanowhisker composite were characterized using X-ray diffraction, scanning electron microscopy, and Raman spectroscopy, and they were used for the catalytic degradation of methyl orange (MO) under ultraviolet (at 254 and 365 nm) and ultrasonic irradiation. In addition, the catalytic degradation of MO over the zinc oxide nanoparticle and zinc oxide nanoparticle-(C60) fullerene nanowhisker composite was evaluated using ultraviolet-visible spectroscopy.

Synthesis and Characterization of Zinc Phosphate Cement Powder and Cement-forming Liquid

  • Park, Choon-Keun
    • The Korean Journal of Ceramics
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    • v.3 no.4
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    • pp.269-273
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    • 1997
  • Chemical composition of cement powder influences the setting time and early compressive strength development. The setting time increases as the amounts of zinc oxide and magnesium oxide are increased. For one day compressive strength development, a cement powder with a composition 90% ZnO, 8% MgO and 2% silica resulted in the highest strength (greater than 1, 090 kg/$\textrm{cm}^2$). Cement-forming liquids also need to be buffered, with both aluminum and zinc ions, for a good consistency and a higher strength of the zinc phosphate cement. These liquids control the setting reactions.

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The effect of precipitation conditions on the particle size and size distribution of zinc oxide prepared by high temperature precipitation (고온침전반응에 의한 산화아연 제조공정에서 입자의 형상 및 입도분포에 미치는 침전조건의 영향)

  • 주창식
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.2
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    • pp.11-22
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    • 1998
  • For the purpose of preparation of monodispersed spherical zinc oxide fine particles, an experimental research on the preparation of zinc oxide particles from zinc salts solutions by high temperature precipitation reaction was performed. Zinc oxide particles were precipitated from all the precipitation solutions tested if the precipitation temperature was higher than 60$^{\circ}$. As the precipitation temperature Increased until 80$^{\circ}$, the average particle diameter of zinc oxide particles decreased and the narrower particle size distribution were obtained. Spherical zinc oxide fine particles with relatively narrow particle size distribution were precipitated from the ZnSO$_4$ solutions with NaOH as precipitant. Final pH of precipitation solution had an effect on the amount of zinc oxide precipitated, but had no effect on the their particle size or size distribution.

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Direct Determination of Serum Zinc by Atomic Absorption Spectroscopy (원자흡광분광분석법에 의한 혈청 Zn의 측정)

  • Tchai, Bum-Suk;Suk, Young-Gunn;Park, Tong-Soo
    • Journal of Nutrition and Health
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    • v.4 no.3
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    • pp.1-4
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    • 1971
  • Zinc is an essential trace element. Previos methods for the determination of zinc in serum have been difficult and reported findings must be treated with caution. The normal range of zinc in serum varies significantly according to different methods and author. The scope of this work was to establish the normal range of zinc in serum values in healthy Korean persons. Methods are described for the determination of zinc in serum diluted ten-fold with deionised water using Hitachi Model 207, atomic absorption spectrophotometer. The values of zinc in serum of 23 healthy Korean persons by atomic absorption spectroscopy ranged from 87.6 to $131.2\;{\mu}g/100\;ml$ with the mean value $109.1\;{\mu}g/100\;ml$ and standard deviation 10.86. In this method, satifactory result was obtained with regard to the coefficient variation and recoveries of added zinc in the measurenents.

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A Case of Zinc-Deficient Parakeratotic Hyperkeratosis in a Dog (개에서 발생한 아연 결핍성 부전각화성 과각화증의 증례)

  • 나기정;김기흥;최석화;양만표
    • Journal of Veterinary Clinics
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    • v.14 no.2
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    • pp.361-364
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    • 1997
  • The paper is to report a case of zinc-deficient parakeratotic hyperkeratosis in a dog. In this dermatosis, although an available diagnosis of zinc-deficient dermatosis is to analyse the serum or hair zinc Bevels, exact analysis of zinc is difficult and unreliable due to contamination of zinc by various environmental, physiologic and disease-related factors. Diagnosis may be performed by history, physical examination and blood chemical analysis. Laboratory evaluation revealed hypercholesterolemia and low activities of serum alkaline photophatase and total protein. The dog showed thick crusts at the elbows joint, stifle joint and testis. Zinc sulfate is administered per oral to patient with application of salicylic acid added vaseline ointment on hyperkaratic lesions. The dog is successfully cured.

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A Kinetic Study on the Zinc-Nickel Plating on an Elstrolytic Sulface Bathe (황산용액 중에서 전해철표면상에 안연-니켈 합금도금에 관한 속도론적 연구)

  • 이응조;노재호
    • Journal of Surface Science and Engineering
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    • v.22 no.3
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    • pp.118-127
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    • 1989
  • The rate of electrodeposition Zinc-nickel alloy on to electrolytic ione in sulface solution both under an inter and air atmospherss has studied by use of a rotating disc geometry. The kinetics shows 1st order reaction, and the rate constants are proportional to the square root of rpm, however, they are less than the valuse suggested by Levich. The rate constants of zinc deposition approach the total mass transfer rate constants with increasing potential and deviate with increasing rotaing speed, but those of nickel deposition are constant. Below $40^{\circ}C$ the activation engrgies of zinc deposition and nikel deposition were 4.4Kcal/mol and 6.3Kcal/mol respectively. There results show that overall reaction rate of zinc-nickel plaeting is controlled by mixed reaction and zinc deposotion is more affected by mass transfer reaction than nickel. The current density for the zinc-nickel plating was less in an air atmosphere than in a nitrogen atmosphere. The cathode efficiency increased with decreasing cathode rotating speeds, potentials, and increasing temperatures. Zzinc-nickel platings are more improved in microhardnss than zinc platings.

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Physiological and Ecological Studies on the Vegetation on Ore Deposits 1. Zinc Flora and Indicator Plants on the 2nd Yunwha Mine (금속광체상에 나타나는 식물에 관한 생리생태학적 연구 1. 아연광지대의 지표종과 식생)

  • 장남기
    • Journal of Plant Biology
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    • v.20 no.1
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    • pp.45-52
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    • 1977
  • During the period of 1975-76, a survey was carried out to find out zinc indicators in the natural vegetation in Korea. The symptoms fo chlorosis were observed in flowering plants in the areas of zinc outcrop of Wolgok-A, Seokgok-9, and Sowolgok. Although 28 species were found to be chlorotic, the total quantity of chlorotic foliage observed was small. Reasons for chlorosis in the areas of zinc are deposits is considered as effects of zinc, lead, copper and calcium ions. Sedum sp. and Dianthus sinensis were confined to soil containing more than exchangeable zinc of 30 ppm and to accumulation in the plants contained at least 1,300-14,000 ppm of zinc. Therefore Sedum sp. and Dianthus sinensis might be used as zinc indicators in Korea.

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Effects of Salmonella typhymurium Lipopolysaccharide Challenge on the Performance, Immune Responses and Zinc Metabolism of Laying Hens Supplemented with Two Zinc Sources

  • Cheng, Tingshui;Guo, Yuming
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.12
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    • pp.1717-1724
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    • 2004
  • The study was conducted to determine the effect of Salmonella typhymurium lipopolysaccharide (LPS) challenge on egg-laying performance, inflammatory response, zinc metabolism in layer fed diets supplemented with organic or inorganic zinc since 3-wk-old. The three dietary treatments were corn-soybean meal basal diet without supplemental zinc or with supplemental zinc at 60 mg/kg zinc from $ZnSO_4$ or zinc amino acid complex (ZnAA). At the age of 58 wk-old, twelve hens from each dietary treatment were allotted into two sub-groups. On day 1, 3, 5, 7 of the $58^{th}$ week of age, six birds of one sub-group were injected intraperitoneally (i.p.) with 2 ml LPS (1.0 $\ell$/ml) or sterile saline. Neither zinc source ${\times}$ immune challenge interaction nor zinc source effect on egg production performance was observed (p>0.05), LPS-challenge decreased egg production (p<0.04) and increased percentage of cracked eggs (p <0.01). With LPS challenged, the fever response of hens fed ZnAA peaked and subsided earlier than in hens fed $ZnSO_4$ or basal diet. Serum IL-1$\beta$ at 3 h was higher (p<0.01), but lower (p<0.001) at 12 h post-challenge with LPS in hens fed ZnAA than $ZnSO_4$. In salinetreated groups, serum IL 1$\beta$ was higher in hens fed ZnAA than the basal diet at 3 h post-injection (p<0.01). LPS-challenged birds had lower serum zinc and higher zinc sequestered in liver and spleen (p<0.001). In saline-treated birds, there was no difference in zinc concentration of serum, liver and spleen among different dietary treatments (p>0.05). Supplementation of 60 mg/kg zinc from either ZnAA or $ZnSO_4$ significantly (p<0.05) elevated metallothionein (MT) concentration in liver and spleen. MT concentration in liver of birds fed ZnAA diet was higher than in those fed $ZnSO_4$ diet (p<0.05). The magnitude of increase of hepatic and splenic MT due to LPS challenge was higher by supplementation of ZnAA than $ZnSO_4$. The results suggest that zinc amino acid complex enhanceed MT synthesis and zinc sequestered in liver and spleen and increased the sensitivity to immune response due to LPS challenge.

Zinc and Zinc Related Enzymes in Precancerous and Cancerous Tissue in the Colon of Dimethyl Hydrazine Treated Rats

  • Christudoss, Pamela;Selvakumar, R.;Pulimood, Anna B.;Fleming, Jude Joseph;Mathew, George
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.2
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    • pp.487-492
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    • 2012
  • Trace element zinc deficiency or excess is implicated in the development or progression of some cancers. The exact role of zinc in the etiology of colon cancer is unclear. To cast light on this question, an experimental model of colon carcinogenesis was applied here. Six week old rats were given sub cutaneous injections of DMH (30 mg/kg body weight) twice a week for three months and sacrificed after 4 months (precancer model) and 6 months (cancer model). Plasma zinc levels showed a significant decrease (p<0.05) at 4 months and a greater significant decrease at 6 months (p<0.01) as compared with controls. In the large intestine there was a significant decrease in tissue zinc levels (p<0.005) and in CuZnSOD, and alkaline phosphatase activity (p<0.05) in the pre-cancerous model and a greater significant decrease in tissue zinc (p<0.0001), and in CuZnSOD and alkaline phosphatase activity (p<0.001), in the carcinoma model. The tissue zinc levels showed a significant decrease in the small intestine and stomach (p<0.005) and in liver (p<0.05) in the cancer model. 87% of the rats in the precancer group and 92% rats in the cancer group showed histological evidence of precancerous lesions and carcinomas respectively in the colon mucosa. This study suggests that the decrease in plasma zinc, tissue zinc and activity of zinc related enzymes are associated with the development of preneoplastic lesions and these biochemical parameters further decrease with progression to carcinoma in the colon.

Histochemically-reactive Zinc in the Rat Dorsal Root Ganglion (DRG) Neurons: Zinc Selenium Autometallography (랫드 척수신경절내 zinc의 분포양상: Zinc Selenium Autometallography)

  • Kim, Yi-Suk;Jo, Seung-Mook
    • Applied Microscopy
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    • v.40 no.1
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    • pp.15-19
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    • 2010
  • The present study was designed to demonstrate ionic zinc in the rat DRG by means of zinc selenium autometallography($ZnSe^{AMG}$). Ganglion cells varied in size from 15 to 100 ${\mu}m$. The smaller neurons were strongly stained with AMG, whereas the larger cells were weakly stained. Each large ganglion cell was surrounded by perineuronal satellite cells, showing apparent AMG staining. We demonstrated for the first time the existence of zinc-containing satellite cells in the rodent DRG. Using electron microscopy, fine AMG grains were observed scattered in the somata of the DRG neurons, especially small cells. However, much lower concentrations of the AMG grains occupied in the large cells, and these were mostly localized in lysosome-like organelles. These results indicate that zinc may be involved in sensory transmission in the DRG level.