• Title/Summary/Keyword: Zinc fluosilicate salts

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Fluidity and Hydration Properties of Cement Paste Added Zinc Fluosilicate(ZnSiF6, aq.) (규불화아연(ZnSiF6, aq)이 첨가된 시멘트의 유동성과 수화특성)

  • Kim, Do-Su;Khil, Bae-Su;Lim, Heon-Seong;Nam, Jae-Hyun;Rho, Jae-Seong
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.178-183
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    • 2002
  • Zinc fluosilicate ($ZnSiF_6$, 15% aqueous solution) was prepared using zinc oxide (ZnO) and fluosilicic acid ($H_2SiF_6$) by soluiton synthetic method. The fluidity and hydration properties of cement which was added $ZnSiF_6$ (aq.) as an additive for cement were studied. At water to cement ratio (W/C) equals to 0.45, the initial fluidity and slump loss of cement paste which the addition of $ZnSiF_6$ (aq.) was increased from 1.0% to 4.0% based on cement weight were investigated. Initial fluidity of cement paste was measured by mini-slump test and slump loss was examined by measuring the fluidity variation of cement paste with time elapsed from 0 min to 120 min at intervals 30 min. Also, the effect of $ZnSiF_6$ addition on the setting and hydration of cement paste when $ZnSiF_6$ increased in the addition range 1.0% to 3.0% were investigated. The fluidity of cement paste which was added 2.1% $ZnSiF_6$ (aq.) presented the highest value among all addition ranges. The setting time of cement paste was retarded gradually and the heat evolution of hydrated cement was reduced with the increasing of $ZnSiF_6$ addition.