• 제목/요약/키워드: Zigzag structure

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Crystal Structure of Penicillin V Potassium Salt

  • Kim, Whan-Chul;Yi, Seung-Ho;Shin, Jung-Mi;Yoon, Tae-Sung
    • Bulletin of the Korean Chemical Society
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    • 제14권6호
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    • pp.713-717
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    • 1993
  • The crystal structure of the potassium salt of penicillin V has been studied by the X-ray crystallographic methods. Crystal data are as follows; potassium 3,3-dimethyl-7-oxo-6-phenoxyacetoamido-4-thia-1- azabicyclo[3.2.0]-heptane-2${\alpha}$-carboxylate, $K^+{\cdot}C_{16}H_{18}N_2O_5S^-$, $M_r$= 388.5, triclinic, Pl, a= 9.371 (1), b= 12.497 (2), c= 15.313 (2) ${\AA},\;{\alpha}= 93.74\;(2),\;{\beta}=99.32\;(1),\;{\gamma}=90.17\;(1)^{\circ},\;V=1765.7\;(2)\;{\AA}^3$, Z=4, $D_m=1.461\;gcm^{-1},\;{\lambda}(Cu\;K{\alpha})=1.5418\;{\AA},\;{\mu}=40.1\;cm^{-1}$, F(000)=808, T=296 K. The structure was solved by the heavy atom and difference Fourier methods with intensity data measured on an automated four-circle diffractometer. The structure was refined by the full-matrix least-squares method to a final R= 0.081 for 3563 observed $[I_0{\geq}2{\sigam}(I_0)]$ reflections. The four independent molecules assume different overall conformations with systematically different orientations of the phenyl groups although the penam moieties have the same closed conformations. There are intramolecular hydrogen bonds between the exocyclic amide nitrogen and phenoxy oxygen atoms. The penam moiety is conformationally very restricted although the carboxyl and exocyclic amide groups apparently have certain rotational degrees of freedom but the phenyl group is flexible about the ether bond despite the presence of the intramolecular N-H${\cdots}$O hydrogen bond. There are complicated pseudo symmetric relationships in the crystal lattice. The penam moieties are related by pseudo 20.5 screw axes and the phenyl groups by pseudo centers of symmetry. The potassium ions, related by both pseudo symmetries, form an infinite zigzag planar chain parallel to the b axis. Each potassium ion is coordinated to seven oxygen atoms in a severely distorted pentagonal bipyramid configuration, forming the infinite hydrophilic channels which in turn form the molecular stacks. Between these stacks, there are only lipophilic interactions involving the phenyl groups.

Fatigue Behavior of Cracked Al 6061-T6 Alloy Structures Repaired with Composite Patch

  • Yoon, Young-Ki;Park, Jong-Joon;Kim, Guk-Gi;Yoon, Hi-Seak
    • International Journal of Precision Engineering and Manufacturing
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    • 제2권3호
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    • pp.5-10
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    • 2001
  • Due to the development of high-strength fibers and adhesives, it is now possible to repair cracked metallic plates by bonding reinforced patches to the plate over the crack. In this study, pre-cracked aluminum 6061-T6 alloy plates repaired with bonded carbon/epoxy composite patch are applied to investigate the effect of various patch shapes on the tensile strength and the fatigue behavior of the structure. A non-patch-boned cased and 2 type-50$\times$50, 40$\times$20 mm-composite patch-bonded cases were tested to obtain fracture loads and fatigue crack growth rate. The results showed that the patch-bonded repair improves the static strength by 17% and the fatigue life by 200% compared to non-repaired case. It means that patch-boned repair is more effective in the fatigue life. It was also revealed that the patching method along crack growth direction is more efficient in cost and weight reduction. By observing the fractography, patch-bonded repair specimens demonstrated zigzag fracture patterns compared with the non-patched specimens, which shows a typical ductile fracture.

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집적암거에 의한 대류수개발에 관한 연구 (A study on the Development of Ground water by the Infiltration Gallery)

  • 한욱동
    • 한국농공학회지
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    • 제15권3호
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    • pp.3096-3106
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    • 1973
  • As a link in the chain of antidrought measure, our attempt is made to obtain basic informations on the construction of an infiltration gallary which can be supplied with irrigation water by catching of underground water in small river beds, which is economical, permanent and efficient. The experiment was made, concerning the structure of catchment conduits, by constructing a model sand tank $1.5m{\times}5m{\times}1.5m$ in dimension made of reinforced concrete. Various kinds of measuring equipment were attached to the model tank which contains a set of catchment conduits, each of them was made 30cm in diameter and 60cm in length with the ratio of sectional area to total area of influx holes 10:1, 20:1, 30:1. The average size of influx holes was fixed from 0mm to 10mm, 20mm and 30mm in diameter respectively. Obtained results are as follow; (a) In view of the water catchment capacity, manufacturing cost and the antipressure strength of the catchment conduits, it is the best method to decide the total number of influx holes 20 per sq. meter of each tile surface, and the size of influx holes 20mm in diameter, when the conduits have diameter less than 1m. (b) The greatest factor of safety against external load is to arrange the influx holes in a zigzag manner on the tile surface. The most effective formula of arrangement is $S{\geqq}\sqrt{2gd}$ where: s : spacing of opening row. g : spacing of opening line. d : diameter of influs hole.

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Effects of Mo additions on the room-temperature deformation behavior of polysynthetically twinned (PST) crystals of TiAl

  • 오명훈;김민철;위당문
    • 한국재료학회지
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    • 제5권2호
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    • pp.157-168
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    • 1995
  • The effects of Mo additions on the microstructure and the room temperature deformation behavior of polysynthetically twinned (PST) crystals of TiAl were studied in order to get a basic conception for alloying additions on the two-phase TiAl compounds with the lamellar structure. It was found that the Mo additions in TiAl PST crystals increase both the yield stress and tensile elongation to fracture but the increase in yield stress deppend on the angle $\Phi$at which the lamellar boundaries lie from the loading axis. The large difference in yield stress between specimens deformed parallel($\Phi = 0^\circ$)or perpendicular($\Phi = 90^\circ$) to the loading axis and those deformed in intermediate orientations could be plained by the difference in Mo content between the TiAl and the $$Ti_{3}Al$ phases. It was also found that the Mo-doped specimens with intermediate orientation fail by cracking zigzag across to the lamellar boundaris, which is the same fracture mode as that of binary specimens with intermediate orientations tested in vacuum This suggests that Mo atoms are thought to play a role to reduce the environmental embrittlement of binary PST crystals, resulting in increasing the tensile ductility.

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Instability analysis of viscoelastic CNTs surrounded by a thermo-elastic foundation

  • Amir, Saeed;Khani, Mehdi;Shajari, Ali Reza;Dashti, Pedram
    • Structural Engineering and Mechanics
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    • 제63권2호
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    • pp.171-180
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    • 2017
  • Static and dynamic instability of a viscoelastic carbon nanotube (CNT) embedded on a thermo-elastic foundation are investigated, in this research. The CNT is modeled based on Euler-Bernoulli beam (EBB) and nonlocal small scale elasticity theory is utilized to analyze the structure. Governing equations of the system are derived using Hamilton's principle and differential quadrature (DQ) method is applied to solve the partial differential equations. The effects of variable axial load and diverse boundary conditions on static/vibration instability are studied. To verify the result of the DQ method, the Galerkin weighted residual approach is used for the instability analysis. It is observed appropriate agreement for results of two different solution methods and satisfactory accuracy with those obtained in prior studies. The results of this work could be useful for engineers and designers in order to produce and design nano/micro structures in thermo-elastic medium.

20세기 코르세트리의 구성 및 제작기법 (Immediate Constituent and Technics of Corsetry in the 20C)

  • 전혜정;김지연
    • 복식문화연구
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    • 제11권4호
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    • pp.562-577
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    • 2003
  • The object of my research is to inquiry into the immediate constituent and techniques of underwear after looking into basic theory of underwear, techniques by materials classified according to the matter of elasticity, and studying flat pattern and draping which are basis of corset and brassiere structure focusing on corsetry among underwears and production techniques. Various papers are referenced for theoretical study and the elements and techniques of underwear are analyzed based on photographical materials. This paper concludes as follows. To make the flat pattern of corset and brassiere fit to the body tightly, design dart two times without any space and draw smaller than the body. To support the breast sufficiently, move the side seam 1¼″ to the front panel and the seam should pass the apex in all occasions. For draping, dart should be added into short of elasticity materials in the past but dart is no use these days since the material today is extremely elastic. It is possible now to show the body line with only the seam or a pattern. In a case of elastic material, set the elastic direction to the grain line and have a draping as pulling from the center to the out side. As production technic, for an hem, put a zigzag stitch in elastic materials with a 10-20% short elastic band, pulling the band. Then make 3/16″-1/4″ short inseam.

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새로운 전극구조를 가진 ac-PDP의 전기 광학적 특성에 관한 연구 (I) (The study on the electrical and optical characteristics of a new structure for color ac plasma displays)

  • 이우근;신중홍;김준호;김두한;조정수;박정후
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 E
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    • pp.2227-2229
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    • 1999
  • As a direct-view flat panel displays, there are many devices, such as plasma display panels(PDPs), vacuum fluorescent displays (VFDs), and light emitting diode(LED). Among these, a PDP is the first type of panel display to be made commercially available. A 'Plasma display' is the general term for a flat display utilizing the light emission that is produced by gas discharge. However, the brightness and Luminous efficiency are still not adequate for consumer television. So, the new sustain electrode type of ac PDP was proposed. By arranging the transparent electrode of quadrangle by zigzag, the area of electrode are reduced, and the length of electrode gap is increased. It generates a high luminous efficiency(corresponding to a 40% improvement of standard type), the same discharge voltage characteristics, and the low power consumption at same luminance.

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실리콘 v-groove를 이용한 광섬유-광검출기 어레이 모듈 제작 (Fabrication of the Optical Fiber-Photodiode Array Module Using Si v-groove)

  • 정종민;지윤규;박찬용;유지범;박경현;김홍만
    • 전자공학회논문지A
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    • 제31A권6호
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    • pp.88-97
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    • 1994
  • We describe the design, fabrication, and performance of the optical fiber-photodiode 1$\times$12 arry module using mesa-type InS10.53T GaS10.47TAS/INP 1$\times$12 PIN photodiode array. We fabricated the PIN PD array for high-speed optical fiber parallel data link optimizing quantum efficiency, operating speed sensitivity from the PIN-FET structure, and electrical AC crosstalk. For each element of the array, the diameter of the photodetective area is 80 $\mu$m, the diameter of the p-metal pad is 90 $\mu$m, and the photodiode seperation is 250 $\mu$m to use Si v-groove. Ground conductor line is placed around diodes and p-metal pads are formed in zigzag to reduce Ac capacitance coupling between array elements. The dark current (IS1dT) is I nA and the capacitance(CS1pDT) is 0.9 pF at -5 V. No signifcant variations of IS1dT and CPD from element to element in the array were observed. We calulated the coupling efficiency for 10/125 SMF and 50/125 GI MMF, and measured the responsivity of the PD array at the wavelength is 1.55 $\mu$ m. Responsivities are 0.93 A/W for SMF and 0.96 A/W for MMF. The optical fiber-PD array module is useful in numerous high speed digital and analog photonic system applications.

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Novel Class of Entanglement-Assisted Quantum Codes with Minimal Ebits

  • Dong, Cao;Yaoliang, Song
    • Journal of Communications and Networks
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    • 제15권2호
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    • pp.217-221
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    • 2013
  • Quantum low-density parity-check (LDPC) codes based on the Calderbank-Shor-Steane construction have low encoding and decoding complexity. The sum-product algorithm(SPA) can be used to decode quantum LDPC codes; however, the decoding performance may be significantly decreased by the many four-cycles required by this type of quantum codes. All four-cycles can be eliminated using the entanglement-assisted formalism with maximally entangled states (ebits). The proposed entanglement-assisted quantum error-correcting code based on Euclidean geometry outperform differently structured quantum codes. However, the large number of ebits required to construct the entanglement-assisted formalism is a substantial obstacle to practical application. In this paper, we propose a novel class of entanglement-assisted quantum LDPC codes constructed using classical Euclidean geometry LDPC codes. Notably, the new codes require one copy of the ebit. Furthermore, we propose a construction scheme for a corresponding zigzag matrix and show that the algebraic structure of the codes could easily be expanded. A large class of quantum codes with various code lengths and code rates can be constructed. Our methods significantly improve the possibility of practical implementation of quantum error-correcting codes. Simulation results show that the entanglement-assisted quantum LDPC codes described in this study perform very well over a depolarizing channel with iterative decoding based on the SPA and that these codes outperform other quantum codes based on Euclidean geometries.

CFD 시뮬레이션 기반 초임계 LNG용 사인함수 PCHE 설계 (Design of sinusoidal shape channel PCHEs for supercritical LNG based on CFD simulation)

  • 판진싱;염은섭
    • 한국가시화정보학회지
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    • 제19권3호
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    • pp.69-76
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    • 2021
  • Printed circuit heat exchanger (PCHE) is a compact heat exchanger with good heat transfer performance, high structure integrity, and reliability over a wide range of temperatures and pressures. Instead of the traditional zigzag and straight shape channel, the sinusoidal shape channel was adopted in this study to investigate the relation of thermal-hydraulic performance and waviness factors (period and amplitude). The local flow characteristics and the heat flux distribution were compared to verify the effects of period and amplitude on heat transfer performance. As the period of channel becomes shorter, the rapid change of the flow direction can produce high flow separation around the corner leading to the disturbance of the boundary layer opposite wall. The nonuniform distribution of flow velocity appeared around the corner positions can promote fluid mixing and lead to higher thermal performance. An evaluation index was used to compare the comprehensive performance of PCHE considering the Nusselt number and Fanning factor. Based on the simulation results, the optimal design parameters of PCHE channel shape were found that the channel with an equivalent bending angle of 15° offers the highest heat flux capacity.