• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.176-179
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• 2003

The objective of this study was to investigate reductive dechlorination of aromatic hydrocarbons using zero valent metals (ZVMs) and catalysts as reactive materials for permeable reactive barriers (PRBs). A group of small aromatic hydrocarbons such as monochlorophenols, phenol, benzene were readily reduced with palladium catalyst and zero valent iron. Poly-aromatic hydrocarbons (PAHs) were also tested with the catalysts and zero valent metal combinations. The aromatic rings were reduced and partly reduced PAHs were found as the daughter compounds. Current preliminary study implicate that ZVMs and modified catalysts can be successfully applied for PRBs which currently applicable for halogenated organic compounds and some inorganic contaminants including chromium(Ⅵ) and nitrate.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.187-190
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• 2002

Reductive dechlorination of endosulfans was studied with zero valent metals (ZVMs) and bimetals in aqueous batch reactors. The effect of surfactants was evaluated. Endosulfan was successfully dechlorinated with zero valent iron. However, a bimetal, palladium coated iron (Pd/Fe) showed a highly enhanced reactivity for both endosulfan I and II indicating palladium act as a dechlorination catalyst on the iron. The effect of surfactants on degradation with ZVM has been very controvertible. Variable concentration of a nonionic surfactant, Triton X-100 and an anionic surfactant, SDS were added into the reactor with ZVM. The reaction rates of endosulfan were increased with both surfactants. In the case of Triton X-100, the reaction rate was increased with the increasing surfactant concentration up to 400 mg/L. Addition of small amount of surfactant under the CMC, the reaction rate was increased. However, the enhancing effect was diminished when a higher concentration of surfactant (1,000 mg/L) was used. Current study implicate that the surfactant adsorbed on the metal surface might increase the surface concentration of endosulfan resulting in the increased reaction rate. However, partitioning of endosulfan into the micelle formed at the high concentration of surfactant diminish the enhancing effect by reducing the contact chance between target compound and the metal surface.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.53-56
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• 2001

The degradation of tetrachloroethene (PCE) and trichloroethene (TCE) by vitamin B$_{12}$, an electron mediator was examined when zero valent metals (ZVMs) were used as built electron donors. Dechlorination of PCE and TCE by iron and zinc in the presence of vitamin B$_{12}$ showed that the zinc and vitamin B$_{12}$ combination greatly enhances the reaction rates for both PCE and TCE, but iron and vitamin B$_{12}$ result in an increase in reactivity only for PCE degradation, not for TCE degradation in comparing with meta]s only. This result indicates vitamin B$_{12}$(I) Is active towards both PCE and TCE degradation while vitamin B$_{12}$(II) is active towards both PCE. Calculated activation energies for the dechlorination of PCE in the presence of Vitamin B$_{12}$ showed that vitamin B$_{12}$ lowered the activation energy about 40-60 kJ/㏖ for the both metals.the both metals.

• Journal of Environmental Science International
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• v.31 no.1
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• pp.77-85
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• 2022

Environmental contamination by organic compounds are not only restricted to water, but extends to soil and groundwater as well. However, highly oxidized compounds, such as halogenated organics and nitro-compounds, can be detoxified employing reducing methods. Permeable reactive barrier is one of the representative technologies where zero-valent metals (ZVMs) are employed for groundwater remediation. However, organics contaminates often contaminate the unsaturated zone above the groundwater. Despite the availability of technologies like soil vapor extraction and bioremediation, removing organic compounds from this zone represents several challenges. In this study, the reduction of nitrobenzene to aniline was achieved using zero-valent iron (ZVI) under unsaturated conditions. Results indicated that the water content was an important variable in this reaction. Under dry conditions (water content = 0.2%), the reduction reaction was inhibited; however, when the water content was between 10% and 25% (saturated condition), ZVI can reduce nitrobenzene. Palladized iron (Pd/Fe) can be used to reduce nitrobenzene when the water content is between 2.5% and 10%. The reaction was evaluated over a wide range of temperatures (10 - 40 ℃), and the results indicated that increasing the temperature resulted in increased reaction rates under unsaturated conditions.

• Korean Journal of Environmental Agriculture
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• v.29 no.4
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• pp.396-401
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• 2010

Tolclofos-methyl is one of the most widely used organophosphorous pesticides in control of soil-borne diseases in ginseng field. In Korea, residues of tolclofosmethyl in ginseng and cultivation soil is quite often detecting. The objective of this study was to know the possibility for the accelerated degradation of tolclofos-methyl by various chemical treatment under soil slurry condition. The degradation of tolclofos-methyl was accelerated by zerovalent metals treatment in soil slurry. The degradation rate of tolclofos-methyl was found to be at higher zerovalent zinc than unannealed zerovalent and annealed zerovalent iron. The effect of different sizes of zerovalent iron on tolclofos-methyl degradation was showed that the smaller size of zerovalent iron, the greater the degradation rate. In aqueous solution of pH 4.0 below the degradation rate of tolclofos-methyl was very high. Under this experimental condition, tolclofos-methyl degradation was the greatest at 2% (w/v) of ZVI under 0.1 N of HCl in 24 hours, the degradation rate was 94.4%. By testing various chemicals, it was found that $Fe_2(SO_4)_3$ as iron source showed better for degrading tolclofos-methyl in $H_2O_2$ 500 mM treatment and sodium sulfite also showed the degradable possibility tolclofos-methyl in soil slurry.