• Journal of Photoscience
• /
• 제10권1호
• /
• pp.49-60
• /
• 2003

How stereo selectivity in singlet and triplet photocycloaddition and photocyclization reactions, respectively, is linked to spin selectivity and how this link affects our understanding of photochemical reaction mechanisms, is described in this review. As illustrative examples, the Paterno-Buchi reaction and the Norrish-Yang cyclization are described with emphasis on triplet biradical structure and dynamics.

• 대한한의학원전학회지
• /
• 제12권2호
• /
• pp.200-213
• /
• 1999

The Haeng Chym(行鍼) which is the sixty seventh chapter of the Young Chu(靈樞), predominantly explicates the six kinds of needling reactions. The principle ideas of this thesis can be summarized as following, the Haeng Chym is divided into three parts in this thesis. 1st part: It shows that the six kinds of reactions occur from the excess and deficiency of yin-yang(陰陽) which is due to each different constitution(體質) in the acupuncture. 2nd part: It explains the excessive visceral-qi(臟氣) which is due to congenital constitution and the needling reaction which appears among the man of overabundant yang(重陽之人). It shows needling reaction of the man who has a little yin among the man of overabundant yang. 3rd part: It explains the quick and slow of the reaction whim occurred in the acupuncture, the presence of reaction by the times of acupuncture, abnormal rising of qi, bad needling reaction in the acupuncture and the side effect by frequent acupuncture.

• Bulletin of the Korean Chemical Society
• /
• 제23권11호
• /
• pp.1651-1654
• /
• 2002

• 한국응용약물학회:학술대회논문집
• /
• 한국응용약물학회 1995년도 춘계학술대회
• /
• pp.107-107
• /
• 1995

The purpose of this study was to observe the effects of the polysaccharide(G009) obtained from liquid cultured Ganoderma lucidum IY009 on the lipidperoxidation in rat liver microsome. It is well known that the polysaccharide of G. lucidum have the hepatoprotective activity, antitumor activity etc., which was thought to have the relationship to anti-lipidperoxidation. In order to the estimate the effects of anti-lipidperoxidation of the polysaccharide obtained from G. lucidum IY009, enzymatic and nonenzymatic reaction were performed, in vitro, in rat liver microsome. In enzymatic lipid peroxidation reaction by ADP/FeCl$_3$/NADPH and $CCl_4$/NADPH, G009(1mg/ml) inhibited 77.4%, 39.4%, respectively, and the nonenzymatic reaction strongly exhibited 97.4% inhibition. And also, in enzymatic and nonenzymatic inducers treated with G009, the formation of MDA was progressively greater decreased by raising G009 concentration. These results suggest that anti-lipidperoxidation by G009 treatment may be play an important part in liver protection action.

• 한국운동역학회지
• /
• 제18권1호
• /
• pp.129-135
• /
• 2008

본 연구는 댄스스포츠 라틴댄스 룸바 Backward Walk 동작시 지면반력에 어떠한 영향을 미치는가를 규명하기 위해 지면반력기를 이용하여 결과를 도출하였다. 우수선수와 비우수선수간 t-test를 통해 비교하여 오른발의 동작시 수직(Fz)지면반력의 착지와 이지에서 유의한 차이를 보였고, 왼발에서는 수직(Fz), 좌우(Fx), 에서 착지와 수직(Fz), 좌우(Fx) 이지에서 유의차가 나타났다. 우수선수와 비우수선수간의 차이는 오른발에서 수직(Fz) 지면반력 이외 다른 방향에서는 유의차가 나타나지 않았으며, 왼발은 지면반력의 전후(Fy) 이지에서 유의한 차이가 없음이 밝혀졌다. 이는 일반적으로 왼발 운동능력이 트레이닝을 통하여 훈련된 우수선수 집단에서 더 발달되었음을 알 수 있다. 따라서 이러한 지면 반력의 차이를 이해하고, 비우수선수 및 초보자들의 경우 동작의 반복훈련 및 트레이닝을 통하여 양발을 균형 있게 발달시킴으로써 정확한 동작 수행이 도움을 줄 것으로 사료된다.

• Bulletin of the Korean Chemical Society
• /
• 제33권9호
• /
• pp.3122-3124
• /
• 2012

• 한국결정성장학회:학술대회논문집
• /
• 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
• /
• pp.33-39
• /
• 1997

• 대한화학회지
• /
• 제32권4호
• /
• pp.291-296
• /
• 1988

염화벤질류와 피리딘사이의 반응을 DMF 용매내에서 반응시켜 반응온도를 $40^{\circ}$와 $50^{\circ}C$로 하고, 압력은 여러 압력으로 변화시켜 속도 상수를 구하였다. 이들 상수로 부터 활성화부피, 활성화압축율 계수, 활성화엔탈피, 활성화자유에너지를 구하였다. ${\Delta}V^{\neq}$와 ${\Delta}{\beta}^{\neq}$의 값은 모두 음이며, ${\Delta}H^{\neq}$는 양의 값을 ${\Delta}S^{\neq}$는 큰 음의 값을 얻었다. 이러한 사실로 부터 치환체 및 압력에 따른 초기상태와 전이상태를 비교 검토하여 이 반응은 이분자 반응임을 추정할 수 있다.

• Applied Microscopy
• /
• 제45권2호
• /
• pp.89-94
• /
• 2015

This article briefly reviews the results of recently reported research on high-temperature Pb-free solder alloys and the research trend for characterization of the interfacial reaction layer. To improve the product reliability of high-temperature Pb-free solder alloys, thorough research is necessary not only to enhance the alloy properties but also to characterize and understand the interfacial reaction occurring during and after the bonding process. Transmission electron microscopy analysis is expected to play an important role in the development of high-temperature solders by providing accurate and reliable data with a high spatial resolution and facilitating understanding of the interfacial reaction at the solder joint.

• Journal of Pharmaceutical Investigation
• /
• 제22권1호
• /
• pp.23-31
• /
• 1992

A novel O-diethylaminoethyl chitosan (DEAE-chitosan) was synthesized via Schiff's reaction between chitosan and benzaldehyde. $C_2$ amino group was protected via Schiffs base reaction with benzaldehyde to form N-benzylidene chitosan. After reaction with diethylaminoethyl chloride, Schiffs base was removed by reacting O-diethylaminothyl-N-benzylidene chitosan and hydrochloric acid. Tensile strength of DEAE-chitosan was improved due to the incorporation of bulky side group in $C_6$ position of chitosan. DEAE-chitosan showed a pH-dependent swelling characteristics. Release rate of riboflavin was dependent on the water content of DEAE-chitosan that is a function of crosslinking degrees.