• Title/Summary/Keyword: Yang reaction

Search Result 1,606, Processing Time 0.033 seconds

The Link Between Stereoselectivity and Spin Selectivity in Intermolecular and Intramolecular Photochemical Reactions

  • Griesbeck, Axel G.
    • Journal of Photoscience
    • /
    • v.10 no.1
    • /
    • pp.49-60
    • /
    • 2003
  • How stereo selectivity in singlet and triplet photocycloaddition and photocyclization reactions, respectively, is linked to spin selectivity and how this link affects our understanding of photochemical reaction mechanisms, is described in this review. As illustrative examples, the Paterno-Buchi reaction and the Norrish-Yang cyclization are described with emphasis on triplet biradical structure and dynamics.

  • PDF

A Study on the Haeng Chym Pyun(行鍼篇) of the Young Chu(靈樞) ($\ll$영추.행침편(靈樞.行鍼篇)$\gg$에 대(對)한 연구(硏究))

  • No, Jin-U;Yuk, Sang-Won;Geum, Gyeong-Su
    • Journal of Korean Medical classics
    • /
    • v.12 no.2
    • /
    • pp.200-213
    • /
    • 1999
  • The Haeng Chym(行鍼) which is the sixty seventh chapter of the Young Chu(靈樞), predominantly explicates the six kinds of needling reactions. The principle ideas of this thesis can be summarized as following, the Haeng Chym is divided into three parts in this thesis. 1st part: It shows that the six kinds of reactions occur from the excess and deficiency of yin-yang(陰陽) which is due to each different constitution(體質) in the acupuncture. 2nd part: It explains the excessive visceral-qi(臟氣) which is due to congenital constitution and the needling reaction which appears among the man of overabundant yang(重陽之人). It shows needling reaction of the man who has a little yin among the man of overabundant yang. 3rd part: It explains the quick and slow of the reaction whim occurred in the acupuncture, the presence of reaction by the times of acupuncture, abnormal rising of qi, bad needling reaction in the acupuncture and the side effect by frequent acupuncture.

  • PDF

The effect of G009 on lipidperoxidation in rat liver microsome

  • Lee, June-Woo;Jeong, Hoon;Han, Man-Deuk;Kim, Su-Ung;Lee, Seung-Yong;Kim, Kee-Nam;Chung, Sung-Kyun;Baek, Seong-Jin;Song, Jae-Jin;Kim, Yong-Seok;Kang, Sang-Mo
    • Proceedings of the Korean Society of Applied Pharmacology
    • /
    • 1995.04a
    • /
    • pp.107-107
    • /
    • 1995
  • The purpose of this study was to observe the effects of the polysaccharide(G009) obtained from liquid cultured Ganoderma lucidum IY009 on the lipidperoxidation in rat liver microsome. It is well known that the polysaccharide of G. lucidum have the hepatoprotective activity, antitumor activity etc., which was thought to have the relationship to anti-lipidperoxidation. In order to the estimate the effects of anti-lipidperoxidation of the polysaccharide obtained from G. lucidum IY009, enzymatic and nonenzymatic reaction were performed, in vitro, in rat liver microsome. In enzymatic lipid peroxidation reaction by ADP/FeCl$_3$/NADPH and $CCl_4$/NADPH, G009(1mg/ml) inhibited 77.4%, 39.4%, respectively, and the nonenzymatic reaction strongly exhibited 97.4% inhibition. And also, in enzymatic and nonenzymatic inducers treated with G009, the formation of MDA was progressively greater decreased by raising G009 concentration. These results suggest that anti-lipidperoxidation by G009 treatment may be play an important part in liver protection action.

  • PDF

Analysis of the Ground Reaction Forces by the Dancesport Rumba Backward Walk Step (댄스스포츠 라틴댄스 룸바 Backward Walk 동작시 지면반력 변인 분석)

  • Yoo, Hye-Suk;In, Hee-Kyo;Choi, In-Ae
    • Korean Journal of Applied Biomechanics
    • /
    • v.18 no.1
    • /
    • pp.129-135
    • /
    • 2008
  • This research was examined the effect of Backward Walk on ground reaction force and we achieved it by using ground reaction force machine during the Backward Walk activity with Latin and Rumba dance. We find that it was significant difference of vertical(Fz) ground reaction force of right foot in touchdown and toe-off and vertical(Fz), horizontal(Fx), front-rear(Fy) ground reaction force of left foot. There was not significant differences in vertical ground reaction force between superior athlete and unskilled athlete, but there was a significant difference in left foot. Through this, we know that the sports capability of left foot which has been developed through the training is better in superior athlete group. Therefore understanding of difference in ground reaction force and repeated training can help the unskilled athlete and beginner to accomplish the accurate movement.

Kinetics of the Reaction of Benzyl Chlorides with Pyridine in DMF under High Pressure (고압하에서 DMF 용매내에서 피리딘과 염화벤질류의 반응에 대한 속도론적 연구)

  • Kee Joon Choi;Young Hoon Lee;Jin Burm Kyong;Jeong Rim Kim
    • Journal of the Korean Chemical Society
    • /
    • v.32 no.4
    • /
    • pp.291-296
    • /
    • 1988
  • Rates of the reaction for p-nitrobenzyl chloride, benzyl chloride and p-methylbenzyl chloride with pyridine in DMF solvent have been measured by an electric conductivity method at $40^{\circ}\;and\;50^{\circ}C$ under various pressures. From those rate constants, the activation parameters ${\Delta}V^{\neq},\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S^{\neq},\;{\Delta}G^{\neq}$) were evaluated. ${\Delta}V^{\neq}\;and\;{\Delta}{\beta}^{\neq}$ are both negative valued, but ${\Delta}H^{\neq}$ is positive and ${\Delta}S^{\neq}$ is large negative value. From the evaluation of the initial state and transition state which was resulted from substituents and pressure, it was found that this reaction proceeds through bimolecular reaction.

  • PDF

Development of High-Temperature Solders: Contribution of Transmission Electron Microscopy

  • Bae, Jee-Hwan;Shin, Keesam;Lee, Joon-Hwan;Kim, Mi-Yang;Yang, Cheol-Woong
    • Applied Microscopy
    • /
    • v.45 no.2
    • /
    • pp.89-94
    • /
    • 2015
  • This article briefly reviews the results of recently reported research on high-temperature Pb-free solder alloys and the research trend for characterization of the interfacial reaction layer. To improve the product reliability of high-temperature Pb-free solder alloys, thorough research is necessary not only to enhance the alloy properties but also to characterize and understand the interfacial reaction occurring during and after the bonding process. Transmission electron microscopy analysis is expected to play an important role in the development of high-temperature solders by providing accurate and reliable data with a high spatial resolution and facilitating understanding of the interfacial reaction at the solder joint.

Controlled Drug Delivery through O-Diethylaminoethyl Chitosan Membrane (O-디에칠아미노에칠 키토산막을 통한 약물방출조절)

  • Kim, Jin-Hong;Lee, Young-Moo
    • Journal of Pharmaceutical Investigation
    • /
    • v.22 no.1
    • /
    • pp.23-31
    • /
    • 1992
  • A novel O-diethylaminoethyl chitosan (DEAE-chitosan) was synthesized via Schiff's reaction between chitosan and benzaldehyde. $C_2$ amino group was protected via Schiffs base reaction with benzaldehyde to form N-benzylidene chitosan. After reaction with diethylaminoethyl chloride, Schiffs base was removed by reacting O-diethylaminothyl-N-benzylidene chitosan and hydrochloric acid. Tensile strength of DEAE-chitosan was improved due to the incorporation of bulky side group in $C_6$ position of chitosan. DEAE-chitosan showed a pH-dependent swelling characteristics. Release rate of riboflavin was dependent on the water content of DEAE-chitosan that is a function of crosslinking degrees.

  • PDF