• 한국초전도ㆍ저온공학회논문지
• /
• 제6권3호
• /
• pp.6-11
• /
• 2004

YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) films were deposited on MgO(100) and SrTiO$_3$(100) single crystal substrates by cold-wall type MOCVD method using continuous source supplying system. Under the deposition temperature of 740∼76$0^{\circ}C$, c-axis oriented YBCO films were obtained. In case of the YBCO films deposited on MgO (100) single crystal substrate, the critical temperature (T$_{c}$) was under 81 K regardless of the deposition conditions, whereas T$_{c}$ of the YBCO films deposited on SrTiO$_3$(100) single crystal substrate was 83∼84 K. The critical current (I$_{c}$) of the YBCO film deposited on SrTiO$_3$(100) single crystal substrate for 30 min was 49 A/cm-width and the critical current density (J$_{c}$) was 0.82 MA/$\textrm{cm}^2$ to film thickness of 0.6 ${\mu}{\textrm}{m}$. I$_{c}$ increased to 84.4 A/cm-width as the deposition time increased to 50 min, but J$_{c}$ decreased to 0.53 MA/$\textrm{cm}^2$ to film thickness of 1.8 ${\mu}{\textrm}{m}$.rm}{m}$.

• 한국초전도학회:학술대회논문집
• /
• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
• /
• pp.67-70
• /
• 1999

We have fabricated YBa$_2Cu_3O_{7-x}$ thin films by cylindrical hollow cathode sputtering. For 2 inch diameter of MgO (100) substrate, we obtained the zero resistance temperature in the range from 83 K to 86 K and thickness uniformity better than 5 % over the whole area. Also, the average deposition rate was 100nm/h which is higher than 10 times compare to conventional off-axis sputtering method. These results indicate that cylindrical hollow cathode sputtering seems to have unique capabilities for high rate and homogeneous deposition of large area thin film.

• 동굴
• /
• 제78호
• /
• pp.1-8
• /
• 2007

The combination of mechano-chemical activation (MCA)and Self-propagating High-temperature Synthesis (SHS) has widened the technical possibilities for both methods. For YBCO systems the investigation showed that a short-term MCA of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors (HTS) of YBCO composition with a grain size d <1m is developed using combination of MCA and SHS. The specific feature of the technique is formation of the $YBa_2Cu_3O_7-$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples.

• 한국정보통신학회:학술대회논문집
• /
• 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
• /
• pp.96-99
• /
• 2004

The combination of mechano-chemical activation and Self-propagating High-temperature Synthesis (SHS) has widened the possibilities for both methods. For YBCO systems the investigation showed that a short-term mechano-chemical activation of initial powders before SHS leads to single-phase and ultra-fine products. A new technique for preparation ultra-fine high-temperature superconductors of YBCO composition with a grain size d ＜1 ${\mu}{\textrm}{m}$ is developed. The specific feature of the technique is formation of the YBa$_2$Cu$_3$O$_{7-{\delta}}$ crystalline lattice directly from an X-ray amorphous state arising as a result of mechanical activation of the original oxide mixture. The technique allows the stage of formation of any intermediate reaction products to be ruled out. X-ray and magnetic studies of ultra-fine high temperature superconductors (HTS) are carried out. Dimension effects associated with the microstructure peculiarities are revealed. A considerable enhancement of inter-grain critical currents is found to take place in the ultra-fine samples.fine samples.

• Progress in Superconductivity
• /
• 제3권2호
• /
• pp.178-182
• /
• 2002

Superconducting four-element patch array antenna was designed and fabricated using $high-T_{c}$ superconducting (HTS) thin film. The array antenna has single-feed circularly polarization and a resonance frequency of 11.85 GHz fur satellite communication system. To fabricate this antenna $YBa_2$$Cu_3$$O_{7-x}$(YBCO) superconducting thin films were deposited using rf-magnetron sputtering technique. Sequential rotation technique based on radiation elements($0^{\circ}$ , $90^{\circ}$, 1$80^{\circ}$, $270^{\circ}$ phase delay) was utilized to achieve circularly polarization. Simulated and measured results, the analysis on resonant frequency(fr), return loss, and bandwidth are presented. The results show that 10 dB return loss bandwidth of the array antenna is 11.04 GHz~12.59 GHz (13.15%) and 3dB axial ratio bandwidth is 11.42~12.52 GHz (9.2%).).).

• 한국초전도저온공학회:학술대회논문집
• /
• 한국초전도저온공학회 2003년도 학술대회 논문집
• /
• pp.88-91
• /
• 2003

The crystal structure and properties of YBa$_2$Cu$_3$$O_{7-x}$(YBCO) and CeO$_2$ thin films deposited on r-plane (1(equation omitted)02) sapphire substrate by pulsed- laser deposition(PLD) have been investigated. C-axis oriented epitaxial YBCO thin films with critical temperature (Tc) of 88 K were routinely grown on (200) oriented CeO$_2$ buffer layers with thickness in the range between 20 to 80 nm. When the thickness of the (200)oriented CeO$_2$ buffer layer increases over than 80 nm, the superconducting properties of YBCO thin films on that were deteriorated. The decrease in Tc of YBCO thin films was explained by the microcrack formation in CeO$_2$ buffer layer. These results indicate that the thickness of the (200) oriented CeO$_2$ buffer layer is critical to the epitaxial YBCO thin nim growth on r-plane (1(equation omitted)02) sapphire substrate.e.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제51권12호
• /
• pp.573-577
• /
• 2002

We designed wideband HTS antennas which consists of two triangle -radiation patches using a $YBa_2Cu_3O_{7-X}$ (YBCO) superconducting thin film. The major limitation of high-Tc superconducting (HTS) microstrip antennas is the narrow bandwidth due to the high Q and thin substrate. Defining bandwidth as the frequency range over which standing wave ratio (SWR) 2:1 or less, HTS antenna bandwidths are typically 0.85 % to 1.1 %. Thus considerable effort has been focused on developing antennas for broadband operation. To calculate input impedance and design of the broadband HTS antennas a moment method technique was used. The HTS antenna fabricated in this work was designed for K-band, which is useful band for satellite to satellite communications. The bandwidth obtained was a significant 6.7 % and the other measured performance of our HTS antenna, including the bandwidth, radiation Pattern, efficiency, standing wave ratio (SWR) and return losses was reported.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 하계학술대회 논문집
• /
• pp.523-526
• /
• 2002

We designed wideband HTS antennas which consists of two triangle-radiation patches using a YBa$_2$Cu$_3$O$\sub$7-x/ (YBCO) superconducting thin film. The major limitation of high-Tc superconducting (HTS) microstrip antennas is the narrow bandwidth due to the high Q and thin substrate. Defining bandwidth as the frequency range over which standing wave ratio (SWR) 2:1 or less, HTS antenna bandwidths are typically 0.85% to 1.1%. Thus considerable effort has been focused on developing antennas for broadband operation. To calculate input impedance and design of the broadband HTS antennas a moment method technique was used. The HTS antenna fabricated in this work was designed for K-band, which is useful band for satellite-to-satellite communications. The bandwidth obtained was a significant 6.7% and the other measured performance of our HTS antenna, including the bandwidth, radiation Pattern, efficiency, standing wave ratio (SWR) and return losses was reported.

• 한국초전도저온공학회:학술대회논문집
• /
• 한국초전도저온공학회 2003년도 학술대회 논문집
• /
• pp.129-132
• /
• 2003

Yttria stabilized zirconia (YSZ) buffer layers were deposited by a metal organic chemical vapor deposition (MOCVD) technique using single liquid source for the application of YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) coated conductor. Y:Zr mole ratio was 0.2:0.8, and tetrahydrofuran (THF) was used as a solvent. The (100) single crystal MgO substrate was used for searching deposition condition. Bi-axially oriented CeO$_2$ and NiO films were fabricated on {100}〈001〉 Ni substrate by the same method and used as templates. At a constant working pressure of 10 Torr, the deposition temperatures (660~80$0^{\circ}C$) and oxygen flow rates (100~500 sccm) were changed to find the optimum deposition condition. The best (100) oriented YSZ film on MgO was obtained at 74$0^{\circ}C$ and $O_2$ flow rate of 300 sccm. For YSZ buffer layer with this deposition condition on CeO$_2$/Ni template, full width half maximum (FWHM) values of the in-plane and out-of-plane alignments were 10.6$^{\circ}$ and 9.8$^{\circ}$, respectively. The SEM image of YSZ film on CeO$_2$/Ni showed surface morphologies without microcrack.k.

• 한국세라믹학회지
• /
• 제27권3호
• /
• pp.299-310
• /
• 1990

The fabrication of Y-Ba-Cu-O films and experimental factors affecting to characteristics of films are studied in detail. Superconducting thick films are fabricated by the screen printing method. The metal-citrate precursors are obtained simply by mixing of metal nitrate with citric acid. The particle size of heat treated powders is approximately 0.3-1${\mu}{\textrm}{m}$ and the thickness of film is estimated as 30-35${\mu}{\textrm}{m}$. According to the XRD analysis, the films sintered at 870-93$0^{\circ}C$ for 10min. -6hr with P(oxygen)=1atm has the unique orthorhombic crystal symmetry indicating the 123 phae. Tc, onset is determined around 92-87。K, but it shows semiconducting behavior probably due to the oxygen deficiency in the lattice, porosity and impurities in films. Extrapolated Tc, zero is estimated as 76-50。K. For films sintered at 90$0^{\circ}C$ for 1hr, superconducting properties are observed with the room temperature resistivity of 0.025$\Omega$.cm Tc, onset at 88。K and Tc, zero at 63。K.