• Applied Biological Chemistry
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• v.29 no.3
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• pp.311-317
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• 1986

This experiment was conducted to find out the minimum size of pores through that Zeolite particles moved vertically out with percolated solution in the sand column and to estimate whether they were lost through the pores in the field sandy soil. The results were as follows. 1. The amount of Zeolite loss through sand columns was increased in the order of the columns filled with $2{\sim}1>1{\sim}0.5>0.5>0.25mm$ sand particles. 2. The Zeolite particles lost through columns filled with $1{\sim}0.5$ and $0.5{\sim}0.25mm$ sand were clay fraction. 3. The pore sire that clay fraction of Zeolite mineral could migrate through was determined to be above $150{\mu}m$ and Jangchon subsoil was presumed to have possibility of Zeolite loss in consideration of its pore size distribution. 4. The suitable particle size of Zeolite for application in sandy soil was presumed to be above $2{\mu}m$.

• Journal of Animal Science and Technology
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• v.47 no.4
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• pp.555-564
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• 2005

This study was conducted to investigate the effect of dietary supplementation of zeolite on growth performance, carcass characteristics and fecal ammonia gas release in the finishing pigs. A total of 120 crossbred finishing pigs (50.2$\pm$1.4kg, Landrace$\time$Yorkshire$\time$Duroc) were assigned to 4 treatments and randomly divided into 12 groups. They were divided between early finishing period (50~80kg) and late finishing period (80-120kg). Finishing pigs were fed on a basal diet supplemented with 0, 1, 2 and 4% levels of zeolite. Average daily gain and feed conversion were significantly (P<0.05) improved by the dietary supplementation of 4% zeolite compared with other treatments during overall period. In the finishing periods, ammonia gas emission was reduced (P<0.05) in 4% zeolite treatment more than that of the other treatments. Carcass weight and back fat thicknesses were not affected by zeolite treatments. But, the appearance of A grade pork was increased by the dietary supplementation of 4% zeolite. Feed cost was linearly decreased by increasing the supplementation of zeolite. According to this study, 4% supplement of zeolite is suitable for the improvement of carcass quality and feed conversion, the reduction of fecal ammonia gas emission and feed cost per body weight gain.

• Journal of environmental and Sanitary engineering
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• v.14 no.1
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• pp.42-53
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• 1999

A study on the synthesis of zeolite from coal fly ash from power plant was carried out to reduce environmental problems and reuse industrial waste. The synthesized zeolite was proved to be Zeolite 4A type by means of the XRD and SEM analysis, and then the synthesized zeolite was used as an absorbent to remove the $NH_4^+$ ions in the wastewater and water. In the ion exchange of single $NH_4^+$ ions by the natural zeolite and the synthesized zeolite, the ion exchange reached equilibrium within 10 min. and 1hr, respectively. The amount of ion exchanged $NH_4^+$ to the unit weight of natural zeolite and zeolite 4A were 1.09 and 3.54 meq/g respectively, and the amount of $NH_4$ ion exchanged by the synthesized zeolite was higher than by the natural zeolite. The ion exchange kinetics fitted very well to the Feundlich and Langmuir isotherm. The effects of coexisting cations on the ion-exchange properties of zeolites were studied in order to apply them to water treatment. In the bisolute-system of the $NH_4^+-K^+$ and $NH_4^+-Na^+$ systems, the ion exchange capacity was smaller than the single $NH_4^+$ ion system. The effects of coexisting cations on the ion exchange system by the natural zeolite and the synthesized zeolite were found to be $K^+>Na^+$ and $Na^+>K^+>>Mg^{2+}>Ca^{2+}$, respectively.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2000.10a
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• pp.643-648
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• 2000

The purpose of this study is to remove the ammonia by using the ion exchange effect of natural zeolite (clinoptilolite in this system) and artificial zeolite and remove the organic material by using the Absorbent Biofilter. On the removal of ammonia, natural zeolite is the more effective than artificial zeolite But on the simultaneous removal of ammonia and phosphorus, artificial zeolite is the more effective than natural zeolite.

• Korean Journal of Soil Science and Fertilizer
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• v.28 no.4
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• pp.340-349
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• 1995

Effects of the zeolite particle size on the soil chemical properties and on rice growth was investigated on the pot with the loamy sand (Sadu series) and silty clay loam(Paju series) soils. All the zeolite treatments brought the increase of unhulled grain yield on the both loamy sand and silty clay loam soils. Unhulled grain yield increased with increasing the amount of zeolite applied and with decreasing the amount of particle size of zeolite applied on both soils. Unhulled grain yield increased significantly by 11.1% (22.79g/head) with 2ton/10a of smaller than $106{\mu}m$ size zeolite on the loamy sand soil and on the silty clay loam soil, yield increased by 9.3% (24.98g/head) with 1.5ton/10a of smaller than $106{\mu}m$ size zeolite. CEC, pH and contents of exchangeable cations of the soil after experiment were raised by increasing the amount of zeolite and also by decreasing the particle size of zeolite at both soil. At the heading stage, the zeolite treatments improved the growth of rice plant compared to control. The nutrient contents(T-N, Ca, Mg, K, Na), except phosphorus, in the rice plant grown on the zeolite treated soils were higher than control plot.

• Journal of Bio-Environment Control
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• v.5 no.1
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• pp.43-49
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• 1996

This study was conducted to investigate the effects of artificial zeolite and various ion exchangers supplemented in rockwool on the ion exchangability of muskmelon. The results obtained were as follows ; Plant height was higher in the treatment of Ca type artificial zeolite as of 131.2cm than that of control as of 124cm, and same trends were shown in fresh weight of leaf and stem. Fruit weight was increased by supplement of artificial zeolite, but there were no significant differences in the sugar degree and external appearance as influenced by supplementing artificial zeolite. Supplement of artificial zeolite stabilized the pH and increased the ion exchange capacity of nutrient solution. Nutrient absorption was more favorable and led to growth promotion. This study was demonstrated that supplement of artificial zeolite in rockwool slab was improved the stabilization of root environment and increased ion uptake of muskmelon plant.

• Polymer(Korea)
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• v.33 no.3
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• pp.243-247
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• 2009

Cellulose diacetate (CDA) was plasticized with triacetine (TA) and epoxidized soybean oil (ESO) in a high speed mixer. Composites of plasticized CDA and zeolite were prepared by a melting process. The $T_g$ value, $106^{\circ}C$ of the plasticized CDA was confirmed by DMA analysis. The $T_g$ value of the CDA with 50% zeolite was $125^{\circ}C$. As the content of zeolite was increased from 10 to 50% the modulus of the composite was increased from 1.7to 3.6 GPa by two times over the plasticized CDA, and its tensile strength was increased to 62 MPa and then decreased down 51 MPa, and its elongation was increased to 10% and then decreased down 3.2%. In the SEM image, the compatibility between CDA and zeolite was observed. Increasing the amount of zeolite in the composites resulted in further enhancement of the $CH_3COOH$ absorption effects.

• Environmental Analysis Health and Toxicology
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• v.6 no.3_4
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• pp.143-148
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• 1991

This study was carried out to develop the low-priced adsorbent by synthesizing the zeolite of high cation exchange capacity with the natural zeolite and to examine the adsorbing ability of this zeolite. The dominant clay minerals were clinoptilolite and mordenite in natural zeolite, while phillipsite in the synthesized zeolite. Adsorption reaction of $NH_4^{+}$on zeolite was reached equilibrium after 2 hrs. The amount of adsorption was increased with increasing the concentration of $NH_4^{+}$or the pH of suspension. The cation exchange capacity of zeolite was slightly decreased below pH 4.0 by acidic treatment. It was estimated that the ability of the synthesized zeolite to remove noxious ions was better than that of the natural zeolite.

• Journal of Environmental Science International
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• v.13 no.7
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• pp.661-665
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• 2004

As the concentration of ammonium nitrogen could be reached 2～3 mg/L in the winter in the river. It was clear that the excessive concentration of chlorinated organics could be produced with the increase of chlorine addition to remove ammonium nitrogen. In the innovative ammonium nitrogen removal process, zeolite adsorption is very efficient as substitute for rapid sand filtration without other adverse quality change in the water. This study is conducted to evaluate the feasibility of ammonium nitrogen removal and regeneration by zeolite adsorption in drinking water treatment. Also, the reuse possibility of zeolite is evaluated to change the removal efficiency of ammonium nitrogen through several times of regeneration. The ammonium nitrogen was not removed in sand filter, but it was almost removed in zeolite filter during 7 days. The sand and zeolite filters have a similar result of turbidity removal. Therefore, zeolite filtration was confirmed the removal of turbidity and ammonium nitrogen as a media. When compared KCl with NaCl as a chemical for zeolite regeneration, it is demonstrated that KCl was more efficient than NaCl in the ability of zeolite regeneration. The adsorption rate of ammonium nitrogen was almost not decreased in the results of several times of regeneration. It is indicated that both zeolite and regeneration solution were possible to reuse without variation of regeneration rate through this study.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.7
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• pp.4675-4681
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• 2014

This study examined the $H_2S$ removal characteristics, such as breakthrough time, adsorption capacity, and adsorption rate of adsorbents between Zeolite 3A and DETOX in terms of the $H_2S$ inflow concentration and adsorption temperature. The adsorption capacity of Zeolite 3A increased with increasing mass flow rate of hydrogen sulfide($H_2S$) inflow, but the breakthrough time decreased. On the other hand, both the adsorption capacity and breakthrough time of DETOX decreased with increasing mass flow rate of $H_2S$ inflow. The adsorption capacity and breakthrough time of Zeolite 3A decreased with increasing adsorption temperature but those of DETOX increased. The adsorption capacity of DETOX was higher than that of Zeolite 3A by a factor of 2.5 - 16.4 because the collision frequency that overcomes the activation energy barrier increased with increasing adsorption temperature. For Zeolite 3A and DETOX, the adsorption rate of $H_2S$ increased with increasing mass flow rate of $H_2S$ inflow and adsorption temperature. The adsorption rate of $H_2S$ for Zeolite 3A was 4 times as much as that for DETOX. For the removal of $H_2S$ in biogas, DETOX had an advantage over Zeolite 3A because DETOX had a much longer breakthrough time and greater adsorption capacity in the temperature range of 308~318K than Zeolite 3A.