DOI QR코드

DOI QR Code

Ammonium Ion Removal and Regeneration for Zeolite Filtration in Drinking Water Treatment

정수처리에서 제올라이트 여과를 이용한 암모니아성질소의 제거와 재생

  • 김우향 (목포해양대학교 해양시스템공학부) ;
  • 이승희 (목포해양대학교 해양시스템공학부)
  • Published : 2004.07.01

Abstract

As the concentration of ammonium nitrogen could be reached 2~3 mg/L in the winter in the river. It was clear that the excessive concentration of chlorinated organics could be produced with the increase of chlorine addition to remove ammonium nitrogen. In the innovative ammonium nitrogen removal process, zeolite adsorption is very efficient as substitute for rapid sand filtration without other adverse quality change in the water. This study is conducted to evaluate the feasibility of ammonium nitrogen removal and regeneration by zeolite adsorption in drinking water treatment. Also, the reuse possibility of zeolite is evaluated to change the removal efficiency of ammonium nitrogen through several times of regeneration. The ammonium nitrogen was not removed in sand filter, but it was almost removed in zeolite filter during 7 days. The sand and zeolite filters have a similar result of turbidity removal. Therefore, zeolite filtration was confirmed the removal of turbidity and ammonium nitrogen as a media. When compared KCl with NaCl as a chemical for zeolite regeneration, it is demonstrated that KCl was more efficient than NaCl in the ability of zeolite regeneration. The adsorption rate of ammonium nitrogen was almost not decreased in the results of several times of regeneration. It is indicated that both zeolite and regeneration solution were possible to reuse without variation of regeneration rate through this study.

Keywords

References

  1. 한국수자원공사, 1998, 금강수도 고도정수처리적용방안 연구(1,2차년도), 수자원연구소
  2. 相澤貴子, 1993, 塩素處理によゐ消毒復生成物の生成特性, 水環境學會誌, 16(12), 830-835.
  3. Symons, J. M. and K. L. Worley, 1995, An advanced oxidation process for DBP control, J. AWWA, 87(11), 66-75.
  4. Koon, J. H. and W. J. Kaufman, 1975, Ammonia removal from Municipal waste waters, WPCF, 47(82), 64-67.
  5. 노재성, 홍성수, 강호, 1990, 국산 천연제올라이트에 의한 폐수중의 암모늄이온 제거를 위한 기초연구 - 온도, pH 및 양이온의 영향, 대한환경공학회지, 12(1), 31-38.
  6. 남영우, 백현성, 1999, 천연 제올라이트에 의한 상하수의 암모니아성 질소 제거에 관한 연구(III), 한국폐기물학회지, 16(2), 151-156.
  7. 박지훈, 송창수, 정태학, 1998, 제올라이트를 이용한 암모늄 이온교환에 있어서 유기물 간섭효과, 대한환경공학회 98추계학술대회 논문집, 181-182pp.
  8. 최재완, 1996, 정수처리에서 제올라이트에 의한 암모니아 제거에 공존 양이온이 미치는 영향, 서울대학교 대학원 박사학위 논문, 12-17pp.
  9. 김양, 김덕수, 장세복, 박상윤, 1996, 포항산 천연 제올라이트와 합성 제올라이트에 의한 금속 이온의 제거, 대한환경공학회지, 18(5), 587-602.
  10. 송창수, 김희준, 정태학, 1998, 천연제올라이트의 암모늄이온교환에 미치는 입자 크기 및 온도영향에 관한 연구, 대한상하수도학회지, 12(3), 75-80.