• Title/Summary/Keyword: Xe(Xenon)

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Xenon-129 NMR Method for the Study of Heterogeneous Catalysts (크세논-129 핵자기 공명 분광법을 이용한 불균일계 촉매의 연구)

  • Ryoo, Ryong
    • Applied Chemistry for Engineering
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    • v.2 no.1
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    • pp.1-11
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    • 1991
  • Xenon-129 NMR technique has been developed since 1980 as a new method for the characterization of microporous materials such as zeolites, activated carbons and alumina by using chemical shift and linewidth variations in $^{129}Xe$ NMR of adsorbed xenon gas. This NMR technique has been known to be very effective to probe the locational and the chemical changes of the supported metallic species as well as the physicochemical change of the support material. Recently, this method has been successfully applied for the characterization of amorphous materials such as activated carbons, silica and alumina. Basic principles, experimental techniques and recent applications of the $^{129}Xe$ NMR method for the study of heterogeneous catalysts are introduced in this paper.

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Analysis of Xe Plasma by LAS (레이저 흡수법을 이용한 제논 플라즈마 분석)

  • Yang, Jong-Kyung;Her, In-Sung;Lee, Jong-Chan;Choi, Yong-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.220-222
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    • 2005
  • We can classify two cases in a way to observe an atom of gas state or a molecule using the laser. First case is way to use dispersion phenomenon like Rayleigh scattering, Thomson scattering, Mie scattering, Raman Scattering. And Second case is a way to use change phenomenon like a LAS (Laser Absorption Spectroscopy), LIF (Laser Induced Fluorescent). In this paper, we have measured the meta-stable density and the distribution by using a LAS method in Xe discharge lamp. The laser absorption spectroscopy (LAS) is useful to investigate the behavior of such species. The xenon atoms in the $1S_4$ and $1S_5$ generate excited $Xe^*$(147nm) and $Xe_{2}^*$(173nm) dimers in Xe plasma. It is found that the intensity of VUV 147nm emission is proportional to that of the IR 828nm emission, and the VUV 173nm emission is roughly proportional to that of the IR 823nm emission. The laser is used CW laser that consist of AlGaAs semiconductor and energy level is used 823.16nm wavelength. We measured signal of monochrometer from the lamp center while will change a discharge electric current by 6mA in 3mA and calculated meta-stable state density of a xenon atom through a measured value.

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Comparative Measurement of Transverse Nuclear Magnetization of Polarized 129Xe and 131Xe by Spin-exchange Optical Pumping

  • Yu, Ye Jin;Min, Seong Ho;Moon, Han Seb
    • Current Optics and Photonics
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    • v.4 no.6
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    • pp.466-471
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    • 2020
  • We analyze the transverse nuclear magnetizations of 129Xe and 131Xe in a vapor cell containing natural Xe, 87Rb, and buffer gases. Th e Xe atoms are polarized th rough spin-exch ange optical pumping (SEOP) with Rb atoms under low-magnetic-field conditions. From the free-induction-decay (FID) signal, we measure the nuclear magnetization of the Xe atoms in the Xe-Rb vapor cell. Furthermore, we measure the dependence of the gyromagnetic ratio on the magnetization of 129Xe and 131Xe by examining the amplitude of the FID signal of each isotope, and we evaluate the relationship between the magnetic field gradient and transverse relaxation rate for both of the 129Xe and 131Xe isotopes.

Optimal Control of Xenon Poison In Nuclear Reactor (원자로에 있어서 Xenon 독소의 최적제어)

  • 곽은호;고병준
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.13 no.5
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    • pp.17-23
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    • 1976
  • The buildup of fission product, i.e. Xe-135 poisoning, is a prime factor in restarting a nuclear reactor from the shutdown, which was under normal operation in the high flux thermal reactor, It is caused by the high absorption crosssection of Xe-135 to thermal neutrons and its long half life, from which the thermal power is affected. It is then possible to restart a nuclear reactor after the sufficient excess reactivity to override this poisoning must be inserted, or its concentration is decreased sufficiently when its temporary shutdown is required. As ratter of fact, these have an important influence not only on reactor safety but also on economic aspect in operation. Considering these points in this study, the shutdown process was cptimized using the Pontryagin's maximum principle so that the shutdown mirth[d was improved as to restart the reactor to its fulpower at any time, but the xenon concentration did not excess the constrained allowable value during and after shutdown, at the same time all the control actions were completed within minimum time from beginning of the shutdown.

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Measurement of excited Xe($1s_4$) and Xe($1S_5$) atoms by laser absorption spectroscopy in coplanar AC-PDP

  • Oh, P.Y.;Lee, J.H.;Moon, H.S.;Hong, J.W.;Jeon, W.;Cho, G.S.;Choi, E.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.515-517
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    • 2004
  • The laser absorption spectroscopy has been used for measuresurement of the xenon atoms in the resonant $1S_4$ and metastable $1S_5$ states in coplanar AC PDP. For the purpose of improving VUV luminous efficiency and optimization of PDP cells, it is important to study behavior of excited Xe atoms in a micro-discharge cell of a coplanar AC-PDP. We measured the xenon excited density of $1S_5$ and $1S_4$ state under mixture gas of Ne-Xe(10%) with gas pressure of 350 Torr and sustaining gap distance of 150 um.

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Electrical Properties of Plasma According to Gas Pressure and RF Power of Xe-Inductively Coupled Plasma (유도결합형 제논의 가스압력 및 RF전력에 따른 플라즈마의 전기적 특성)

  • Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.12a
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    • pp.43-47
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    • 2006
  • In this paper, parameters of electron temperature and density for the mercury-free lighting-source were measured to diagnosis and analyze in Xe based inductively coupled plasma (ICP). As results at several dependences of 20~100mTorr Xenon pressure, the brightness of discharge tube was higher (4,900 $cd/m^2$) than other conditions when Xe pressure was 20mTorr and RF power was 200W. In that case, the electron temperature and density were 3.58eV and $3.56{\times}10^{12}cm^2$, respectively. The key parameters of Xe based ICP depended on Xe pressure more than RF power that could be verified. A high electron temperature and low electron density with a suitable Xe pressure are indispensible parameters for Xe based ICP lighting-source.

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Spatiotemporal Behavior of the Excited Xe Atom Density in the $1s_5$ Metastable State According to the Hoof-type Electrode Structure in an Alternating-current Plasma Display Pane

  • Kim, Yong-Hee;Hong, Young-June;Choi, Joon-Ho;Cho, Byeong-Seong;Uhm, Han-Sub;Choi, Eun-Ha
    • Journal of Information Display
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    • v.11 no.4
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    • pp.149-153
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    • 2010
  • To improve the luminescence characteristics of high-efficiency alternating-current plasma display panels (AC-PDPs), we developed a new hoof-type electrode structure, and we studied the spatiotemporal behavior of the density of the excited Xenon atom in the $1s_5$ metastable state via laser absorption spectroscopy. Using this structure, the maximum density of the excited Xenon atom per cell was improved by 2.4 times that when the conventional electrode structure was used.

Hyperpolarized 129 NMR Study of TiO2 Nanotubes

  • Lee, Sang-Man;Lee, Soon-Chang;Mehrotra, Vandana;Kim, Hae-Jin;Lee, Hee-Cheon
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.511-514
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    • 2012
  • A continuous flow hyperpolarized (HP) $^{129}Xe$ NMR spectroscopy was employed for the first time to investigate $TiO_2$ nanotubes (Ti-NTs) synthesized from commercial nanoparticles with different reaction times. A single peak attributing to channels for Ti-NTs was observed for variable temperature HP $^{129}Xe$ NMR spectra. It was also noted that there is alteration in value for heat of adsorption, ${\Delta}H$ from $12.6{\pm}1.3$ to $16.4{\pm}0.4kJ/mol$ and variation in chemical shift of the xenon adsorbed in channels, ${\delta}_s$ from $120{\pm}2\sim135{\pm}9ppm$ which were closely correlated to channel length and it was shown that P25-24 Ti-NTs with longest channel is most favorite Ti-NTs for Xe adsorption.

The Analysis of Electron Transport Coefficients in Kr and Xe Atom Gas (Kr과 Xe 원자기체의 전자수송계수의 해석)

  • Jeon, Byung-Hoon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.8
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    • pp.104-108
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    • 2008
  • Accurate sets of electron collision cross sections and the electron transport coefficients for atoms and molecules are necessary for quantitative understanding of plasma phenomena Kr and Xe atom are used in many industrial applications, such as in PDP and fluorescent induction lamps(FILs). Therefore, we analysed and calculated the electron transport coefficients, the electron drift velocity W, the longitudinal and transverse diffusion coefficient $ND_L$ and $ND_T$, and the ionization coefficient $\alpha$/N in pure Kr and Xe gases over the wide E/N range from 0.001 to 500[Td] at 1[Torr] by two-tenn approximation of the Boltzmann equation.

The Studies of Irradiation Hardening of Stainless Steel Reactor Internals under Proton and Xenon Irradiation

  • Xu, Chaoliang;Zhang, Lu;Qian, Wangjie;Mei, Jinna;Liu, Xiangbing
    • Nuclear Engineering and Technology
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    • v.48 no.3
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    • pp.758-764
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    • 2016
  • Specimens of stainless steel reactor internals were irradiated with 240 keV protons and 6 MeV Xe ions at room temperature. Nanoindentation constant stiffness measurement tests were carried out to study the hardness variations. An irradiation hardening effect was observed in proton- and Xe-irradiated specimens and more irradiation damage causes a larger hardness increment. The Nix-Gao model was used to extract the bulk-equivalent hardness of irradiation-damaged region and critical indentation depth. A different hardening level under H and Xe irradiation was obtained and the discrepancies of displacement damage rate and ion species may be the probable reasons. It was observed that the hardness of Xe-irradiated specimens saturate at about 2 displacement/atom (dpa), whereas in the case of proton irradiation, the saturation hardness may be more than 7 dpa. This discrepancy may be due to the different damage distributions.