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PREFERRED ORIENTATION AND MICROSTRUCTURE OF MOD DERIVED SrBi$_{2x}$Ta$_2$O$_9$ THIN FILMS WITH Bi CONTENT x

  • Yeon, Dae-Joong;Park, Joo-Dong;Oh, Tae-Sung
    • Journal of Surface Science and Engineering
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    • v.29 no.6
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    • pp.621-627
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    • 1996
  • $SrBi_{2x}TaO_9$ ferroelectric thin films were prepared on platinized silicon substrates using MOD proces, and crystallization behavior of the films was investigated with variation of the annealing temperature and Bi content x. Crystalline phase of bismuth layered perovskite structure was formed even by baking the films at $800^{\circ}C$ for 5 minutes in air, and was not changed by annealing at temperatures raning from $700^{\circ}C$ to $900^{\circ}C$ for 1 hour in oxygen ambient. When $SrBi_{2x}TaO_9$ thin films ($0.8\lex\ie1.6$) were annealed at $800^{\circ}C$, Preferred orientation of the films along c-axis was observed with $x\ge1.2$. With increasing Bi content x, surface morphology of the films was changed from equiaxed grains to elongated grains.

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The Modification of X-ray induced Mutation in Paramecium by Pre-and Post-irradiation Treatment with Colchicine. (X-선에 의한 돌연변이 빈도에 미치는 Colchicine의 영향)

  • 강영선;강현삼
    • The Korean Journal of Zoology
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    • v.8 no.2
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    • pp.33-36
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    • 1965
  • We have carried out a study on the modification of the frequency of X-ray induced lethal and slow growing mutations by colchincine treatment before and after X-ray irradiation in Paramecium aurelia. 1. Lethal and slow-growing mutation induced by X-ray in Paramecium aurelia were reduced by colchicine treatment. 2. The effects of colchicine on the X-ray induced mutations were remarkable in the radiosensitive stages of cell division. 3. The pre-irradiation treatment with colchicine showed no significant influence on the frequency of mutations. 4. It is believed that the reduction of mutation induced by X-ray after treatment with colchicine was due to the fact that the delay of the cell division allowed more time for the pre-mutational damage to recover.

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A Chemotaxonomic Study on Geographical Variations of Korean Fucales Plants 3. Total lipid analysis by 3-dimensional TLC (한국산 모자반목 식물의 지리적 변이체에 대한 생화학적 분류 3. 삼차원적 TLC에 의한 총지질의 분석)

  • 유순애
    • Journal of Plant Biology
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    • v.31 no.2
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    • pp.83-89
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    • 1988
  • The Fucales plants have very homogenous taxonomic characteristics at order level, but show many morphological variatations at species or subspecies levels. This study is one of the serial works to obtain more taxonomic data than morphotaxonomic ones and to clarify the taxonomic ranks and characteristics of Korean Fucales plants through physiological and biochemical analyses. Total lipid compositions of Korean Fucales plants were analyzed by the 3-dimensional TLC method. Major components of phospholipids (PA, PC, PG, PE, DPG, LPE, LPC), neutral fat TG and sterols were commonly contained in each species. Unknown lipids X1, X2 and X3 were contained in genus Sargassum, but Hizikia was lacking X3 and Myagropsis was lacking both X2 and X3. The latter contained unique X8. From the view-point of the phylogeny of lipid metabolism, Sargassum might be more closely related to Hizikia than to Myagropsis. A variant of S. patens from Seongsan showed minute metabolic difference from that of the typical plant; but a variant of S. serratifolium did not show any significant difference from that of the typical plant.

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Exploring Fine Structures of Photoactive Yellow Protein in Solution Using Wide-Angle X-ray Scattering

  • Kim, Tae-Kyu;Zuo, Xiaobing;Tiede, David M.;Ihee, Hyot-Cherl
    • Bulletin of the Korean Chemical Society
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    • v.25 no.11
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    • pp.1676-1680
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    • 2004
  • We demonstrate that wide-angle X-ray scattering pattern from photoactive yellow protein (PYP) in solution using a high flux third generation synchrotron X-ray source reflects not only the overall structure, but also fine structures of the protein. X-ray scattering data from PYP in solution have been collected in q ranges from 0.02 ${\AA}^{-1}$ to 2.8 ${\AA}^{-1}$. These data are sensitive to the protein structure and consistent with the calculation based on known crystallographic atomic coordinates. Theoretical scattering patterns were also calculated for the intermediates during the photocycle of PYP to estimate the feasibility of time-resolved wide-angle X-ray scattering experiments on such proteins. These results demonstrate the possibility of using the wide-angle solution X-ray scattering as a quantitative monitor of photo-induced structural changes in PYP.

A Mossbauer Study on Al-Ferrite (Al-Ferrite의 Mossbauer 분광학적 연구)

  • 이충섭;주한식;이찬영;서정철
    • Journal of the Korean Magnetics Society
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    • v.8 no.4
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    • pp.198-202
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    • 1998
  • We have studied $Al_xFe_{3-x}O_4$ produced by direct composition method using X-ray diffraction and Mssbauer spectroscopy. The cation distribution for $Al_xFe_{3-x}O_4$ was determined by the ratio of sub-spectra absorption area. The charge state of Fe atoms in octahedral site(B-site) is $Fe^{2.5+}$ based on electron hopping, $Fe^{2+}$$(Fe^{3+},Al^{3+})$ without dependency of substituted Al amounts.

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Coulometric Titration Study on the Nonstoichiometry in Copper Doped Cobaltous Oxide ((${Co_{1-x}}{Cu_x}$)$_{1-\delta}$ O (전하적정법에 의한 (${Co_{1-x}}{Cu_x}$)$_{1-\delta}$ O의 산소 부정비량 측정)

  • ;Michael Schroeder;Manfred Martin
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.799-804
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    • 2000
  • Coulometric titration experiments have been done for copper doped cobaltous oxide (Co1-xCux)1-$\delta$ O with various dopant concentrations. We present the obtained experimental data and compare our results to those of previous thermogravimetric investigation. The experimental data are fitted by theoretical calculations based on various defect models. For this modeling, we considered different types fo major defects like copper in substitutional and interstitial lattice sites as well as copper vacancy. We also introduced the copper evaporation effect during titration experiment into our consideration.

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Etch damage evaluation of $(Bi_{4-x}La_x)Ti_{3}O_{12}$ thin films using inductively coupled plasma sources (유도결합 플라즈마를 이용한 $(Bi_{4-x}La_x)Ti_{3}O_{12}$ 박막의 식각 손상)

  • Kim, Jong-Gyu;Kim, Gwan-Ha;Kim, Chang-Il
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1374-1375
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    • 2006
  • Ar/$Cl_2$ 유도결합 플라즈마 (ICP)의 가스 혼합비에 따른 $(Bi_{4-x}La_x)Ti_{3}O_{12}$ 박막의 식각 메커니즘과 식각면에서의 플라즈마 손상을 조사하였다. BLT 박막의 최대식각률은 Ar/$Cl_2$ 플라즈마에서의 Ar 가스 혼합비가 80%일 때 50.8 nm의 값을 보였다. 정전 탐침을 통해 Ar 가스의 혼합비에 따른 전자온도와 전자밀도를 관측하였다. 박막 표면의 X-ray photoemission spectroscopy 분석과 박막의 이력곡선을 통해 BLT 박막의 식각 손상은 Cl 원자와의 반응에 의한 화학적 식각 손상이 BLT 박막 표면에서의 Ar 이온충돌에 의한 물리적 손상보다 더 크다는 것을 확인 할 수 있었다.

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Analysis of resonant frequency in microstrip antennas using X-cut Quartz plates (X-cut quartz를 이용한 마이크로스트립 안테나의 해석)

  • Kang, Hyun-Il;Hwang, Hyun-Suk;Lee, Kyu-Il;Lee, Tae-Yong;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.380-381
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    • 2006
  • A technique to control the operating frequency of microstrip antenna by using the X-cut quartz substrate has been investigated experimentally and theoretically. We consider 6, 8 and 10 GHz resonance frequency in three dimensional quartz plates. Equation of linear piezoelectricity are solved for the thickness-shear approximation of X-cut quartz plates. At X-band frequencies, the microstrip antenna was voltage-controllable using the dc electric field dependence of the piezoelectric constant of X-cut quartz. This work demonstrates advantageous application for X-cut quartz plate in microstrip antenna substrates.

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The Rate of Superoxide Radical (${O_2}^-$.) Production in Normal Fenton's Reagent at Different pHs (펜톤반응에서 pH의 변화에 따른 superoxide radical (${O_2}^-$.)의 생성)

  • 김용수;공성호;김재호
    • Journal of Soil and Groundwater Environment
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    • v.7 no.2
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    • pp.73-81
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    • 2002
  • In normal Fenton's reagent, the reductive mechanism of carbon tetrachloride (CT) with superoxide radical (${O_2}^-$.) was observed and the rate of ${O_2}^-$. production was investigated as a function of $H_2O$$_2$ concentration and pH. As pH was increased, the rate of 1-hexanol degradation was rapidly decreased from 90% (at pH 3) to 5% (at pH 11). On the other hand, more degradation of carbon tetrachloride was observed at higher pH regimes indicating Fenton's reaction is an oxidant-reductant co-existing system at neutral pHs. The rate of $O_2^{-}$ . production was observed at different $H_2$$O_2$ concentrations and at different pHs. The rate increased from (45.3$\pm$7.8) x $10^{-6}$ M/s to (151.0$\pm$26.2) x $10^{-6}$ M/s ($294mM H_2$$O_2$) at pH 11: the rate 3150 increased from (22.1$\pm$3.8) x $10^{-6}$ M/s at pH 7 to (151.0$\pm$26.2) x $^10{-6}$ M/s at pH 11 with 294mM $H_2$$O_2$, These results showed that Fenton's reagent could be applied at wide pH regimes. Especially, carbon tetrachloride, which can not be easily adsorbed to soils and then can be dissolved into groundwater causing a cancer, could be efficiently treated by Fenton's reagent.reagent.