• Title/Summary/Keyword: X8

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Thermoluminescence from X-Ray Irradiated Beta-Eucryptite (X-선 조사된 Beta-eucryptite의 열자극 발광)

  • 김태규;이병용;최범식;강현식;추성실;황정남
    • Progress in Medical Physics
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    • v.3 no.1
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    • pp.9-18
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    • 1992
  • In this study, beta-eucryptite is fabricated and the thermal parameters of this material have been investigated. The thermoluminescence from 4MeV X-ray irradiated beta-eucryptite have been measured over the temperature range of 300K-600K. Thermoluminescence curve from X-ray irradiated beta-eucryptite shows five peaks located at 342K, 392K, 438K, 474K, and 527K. $\tau$, $\delta$ and $\omega$ of peak at 527K are 35K, 39K and 74K, respectively and this peak is found to be 2nd order kinetics. The activation energy of peak shape method is calculated to be 1.03eV and the frequency factor for 527K curve is calculated to be 3.9x10$\^$8/sec$\^$-1/. Based on the various heating rates methods, the activation energy of the peak is computed to be 1.02${\pm}$0.05eV that is similar to 1.19${\pm}$0.03eV of initial rise method. The linearity of thermoluminescence intensity and radiation flux is valid up to 50Gy and beyond higher dose the supralinearity and saturation come out.

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A Quantitative Interpretation of the Overlapped X-Ray Fluorescence Spectra by Target Transformation Factor Analysis (Target Transformation Factor Analysis에 의한 겹침 X-선 형광 스펙트라의 정량적 해석)

  • Kim Seungwon;Lee, Chul;Choi Sang Won;Kang Hyung Tae
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.720-726
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    • 1992
  • Multivariate analysis such as factor analysis was applied to interpret multivariate data, which were obtained from the overlapped X-ray fluorescence spectra. X-ray fluorescence spectra of 11 reference samples were obtained by the wavelength dispersive spectrometer at a specified range of angle such as $33.50∼34.50^{\circ}$. The data matrix was made from the spectra of 8 samples. The results of abstract factor analysis gave three factors. By the target testing with 8 elements contained in the reference samples, the three factors were found to be Pb, As and Cu. The concentration of these elements in the test samples was determined by target transformation factor analysis regardless overlapping individual peaks.

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Photoluminescence properties of $CaS_{1-x}Se_x:Eu$ phosphors ($CaS_{1-x}Se_x:Eu$ 형광체의 발광 특성)

  • Ryu, Eun-Kyoung;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.5
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    • pp.204-209
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    • 2007
  • We synthesized a series of $CaS_{1-x}Se_x:Eu$ red-emitting phosphors for application in phosphor-converted three-band white light emitting diode(LED). The photoluminescence and structural properties of $CaS_{1-x}Se_x:Eu$ were examined. The $CaS_{1-x}Se_x:Eu$ phosphors have a strong absorption at 455 nm, which is the emission wavelength of a blue LED. CaS:Eu has a red omission peak at 651 nm due to the $4f^65d^1(T_{2g}){\rightarrow}4f^7(^8S_{7/2})$ transition of the $Eu^{2+}$. The emission peak of $CaS_{1-x}Se_x:Eu$ is shifted from 651 to 598 nm with increasing Se content. $CaS_{1-x}Se_x:Eu$ can be used as wavelength-tunable red-emitting phosphors pumped by a blue LED. We also fabricated a three-band white LED by doping $SrGa_2S_4:Eu$ and $CaS_{0.50}Se_{0.50}:Eu$ phosphors onto a blue LED chip.

X-ray and Spectroscopy Studies of Mercury (II) and Silver (I) Complexes of α-Ketostabilized Phosphorus Ylides (α-케토안정화된 일리드화 인의 수은(II) 및 은(I) 착물에 대한 X-선 및 분광학적 연구)

  • Karami, K.;Buyukgungor, O.;Dalvand, H.
    • Journal of the Korean Chemical Society
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    • v.55 no.1
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    • pp.38-45
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    • 2011
  • The complexation behavior of the $\alpha$-ketostabilized phosphorus ylides $Ph_3P$=CHC(O) $C_6H_4-X$ (X=Br, Ph) towards the transition metal ions mercury (II) and Silver (I) was investigated. The mercury(II) complex {$HgX_2$ [Y]} 2 ($Y_1$=4-bromo benzoyl methylene triphenyl phosphorane; X=Cl(1), Br(2), I(3), $Y_2$=4-phenyl benzoyl methylene triphenyl phosphorane; X=Cl(4), Br(5), I(6)) have been prepared from the reaction of $Y_1$ and $Y_2$ with $HgX_2$ (X=Cl, Br, I) respectively. Silver complexes [$Ag(Y_2)_2]$ X(X=$BF_4$(7), OTf(8)) of the $\alpha$-keto-stabilized phosphorus ylides ($Y_2$) were obtained by reacting this ylide with AgX (X=$BF_4$, OTf) in $Me_2CO$. The crystal structure of complexes (1) and (4) was discussed. These reactions led to binuclear complexes C-coordination of ylide and trans-like structure of complexes $[Y_1HgCl_2]_2$. $CHCl_3$ (1) and $[Y_2HgCl_2]_2$ (4) is demonstrated by single crystal X-ray analyses. Not only all of complexes have been studied by IR, $^1H$ and $^{31}P$ NMR spectroscopy, but also complexes 1-3 have been characterized by $^{13}$CNMR.

Autothermal Reforming of Propane over Ni/CexZr1-xO2 Catalysts (Ni 담지 CexZr1-xO2 촉매상에서 프로판의 자열개질반응)

  • Kong, Jin-Hwa;Park, Nam-Cook;Kim, Young-Chul
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.47-52
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    • 2013
  • In this study, the catalytic performance and characterization of $Ni/Ce_xZr_{1-x}O_2$ were investigated using an autothermal reforming (ATR) process for hydrogen production. The $Ni/Ce_xZr_{1-x}O_2$ catalysts were prepared using the following methods: the water method (CZ-W), urea water method (CZ-UW) and urea, water and ethanol method (CZ-UWA). The performance of $Ni/Ce_xZr_{1-x}O_2$ catalysts in autothermal reforming of propane for hydrogen production was studied in a fixed-bed flow reactor. Reaction tests were conducted by using a feed of $H_2O/C_3H_8/O_2$=3/1/0.37 and $300{\sim}700^{\circ}C$. The CZ-UW and CZ-UWA catalysts showed higher propane conversion and hydrogen yield than the CZ-W catalyst. The activity test confirmed that the improvement in the water-ethanol catalyst was due to the low level of carbon deposition. SEM showed that the surface carbon consisted of clusters on the used CZ-UW catalyst, which is incontrast to the nano-fiber morphology observed on the used CZ-UWA catalyst. It was found that the amount of carbon deposition depends on the preparation method. Especially the $Ni/Ce_{0.75}Zr_{0.25}O_2$ was showed higher propane conversion and hydrogen yield than the other catalysts. Also TGA showed that the resistance of carbon deposition increase to Co addition.

Taxonomical Characteristics of Tropical Species of Xylaria Collected from Taiwan (대만산 Xylaria속 열대종의 분류학적 특성)

  • Lee, Yang-Soo
    • The Korean Journal of Mycology
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    • v.27 no.1 s.88
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    • pp.73-75
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    • 1999
  • Three species of the genus Xylaria are recognized on Taiwan materials: X. allantoidea (Berk.) Fr. and X. obovata (Berk.) Fr.; including one new record X. curta Fr., having $9.0-10.8{\times}3.9-5.4\;{\mu}m$ ascospores, in Taiwan. The collection of Xylaria allantoidea from Taiwan is compared to other collections in morphological characters. The species are described from the host and in culture by a bright microscope and a scanning electron microscope.

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A GENERALIZATION OF GAUSS' TRIANGULAR THEOREM

  • Ju, Jangwon;Oh, Byeong-Kweon
    • Bulletin of the Korean Mathematical Society
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    • v.55 no.4
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    • pp.1149-1159
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    • 2018
  • A quadratic polynomial ${\Phi}_{a,b,c}(x,y,z)=x(ax+1)+y(by+1)+z(cz+1)$ is called universal if the diophantine equation ${\Phi}_{a,b,c}(x,y,z)=n$ has an integer solution x, y, z for any nonnegative integer n. In this article, we show that if (a, b, c) = (2, 2, 6), (2, 3, 5) or (2, 3, 7), then ${\Phi}_{a,b,c}(x,y,z)$ is universal. These were conjectured by Sun in [8].

MANN-ITERATION PROCESS TO THE SOLUTION OF $y=x+Tx$ FOR AN ACDRETIVE OPERATOR T IN SOME BANACH SPACES

  • Park, Jong-An
    • Communications of the Korean Mathematical Society
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    • v.9 no.4
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    • pp.819-823
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    • 1994
  • If H is a Hilbert space, then an operator $T : D(T) \subset H \to H$ is said to be monotone if $$ (x-y, Tx-Ty) \geq 0$$ for any x, y in D(T). Many authors [1], [4] obtained the existence theorem for the equation $y = x + Tx$ for x, given an element y in H and a monotone operator T. On the other hand some iterative methods were applied to the approximations for the solution of the above equation [6], [8]. For example Bruck [2] obtained the iterative solution of the above equation with an explicit error estimate as follows.

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X-선 검출기의 신호처리회로 설계

  • 남욱원;최철성;문신행
    • Bulletin of the Korean Space Science Society
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    • 1993.10a
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    • pp.23-23
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    • 1993
  • 과학로케트에 탑재되는 x-선 검출기에서 검출되는 2 kev 에서 10 kev 사이의 x-선 신호를 분석하여 데이터를 얻고, 전송하기 위한 피로를 설계하고 제작하였다. 신호처리회로의 전체적인 구성은 2 - 10 key의 x-선 에너지 및 event time을 측정하는 회로 및8-선 계수율을 측정하기 위한 카운터회로를 위주로 설계하였으며, x-선 event의 에너지가 측정에너지를 벗어나거나 상승시간이 긴 신호는 anti-coincidence 회로를 통하여 제거되고, 그 계수율이 기록되도록 설계 제작되었다. 또한 신호처리회로에서 얻은 데이터는 telemetry를 통하여 serial 형태로 전송되어야 하므로 8086 microprocessor를 이용하여 데이터를 획득하고 전송하도록 하였다. 따라서 본 실험에서 제작된 신호처리회로의 기능 및 특성에 대해 논하고자 한다.

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