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Magnetic Properties and the Order-disorder Phase Transformation of (Fe1-XCoX) Pt Magnetic Thin Films

  • Na, K.H.;Park, C.H.;Na, J.G.;Jang, P.W.;Kim, C.S.;Lee, S.R.
    • Journal of Magnetics
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    • v.4 no.4
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    • pp.119-122
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    • 1999
  • Magnetic properties and crystal structures of (Fe1-XCoX) Pt (X = 0, 0.2, 0.4, 0.5, 0.6, 0.8 and 1.0) ternary thin films were investigated. The order-disorder phase transformation of FePt thin films during annealing was also studied by x-ray diffraction and M ssbauer spectroscopy. The magnetic thin films were deposited on glass substrates using a dc sputtering method and were subsequently annealed at 400~$700^{\circ}C$ in a high vacuum. The as-deposited films exhibited a high degree of the <111> preferred orientation and the preferred orientation was not destroyed even after the subsequent post annealing. The coercivity of the ($Fe_xCo_{1-x}$) Pt thin films annealed at $700^{\circ}C$ showed a minimum value at the equiatomic composition of the Fe and Co atoms. The ordered structure of the FePt alloy was thought to have formed from the disordered structure by an inhomogeneous process, which was confirmed by the asymmetric peak shapes and M ssbauer spectra.

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Sturctural Studies of InGaAs/InGaAsP Multi-quantum well Structure Grown on Corrugated InP by MOVPE (MOVPE 성장방법으로 corrugated InP 기판위에 성장된 InGaAs/InGaAsP 다층박막의 구조연구)

  • Nahm, Sahn;Jang, Dong-Hoon;Suh, Kyoung-Soo;Cho, Kyoung-Ik
    • Korean Journal of Materials Research
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    • v.6 no.6
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    • pp.651-656
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    • 1996
  • InGaAs/InGaAsP 다층박막을 corrugation이 형성된 InP 기판위에 MOVPE 방법을 이용하여 성장 시킨 후 성장조건에 따른 corrugation 높이의 변화와 석출상에 대하여 투과전자현미경을 이용하여 시킨 후 성장조건에 따른 corrugation 높이의 변화와 석출상에 대하여 투과전자현미경을 이용하여 연구하였다. Corrugation이 형성된 InP 기판을 PH3 및 AsH3가스를 동시에 공급해 주었는데 AsH3 가스의 압력이 높으면(1.8x10-2torr)많은 양의 As를 포함한 In1-xAsxP(x=0.3)석출상이 격자결함과 더불어 형성되었다. 반면에 AsH3 가스의 압력이 낮을때는 (1.0x10-3torr) corrugation의 높이가 30nm이었고, 적은 양의 As를 포함한 In1-xAsxP(x<0.1)석출상이 격자결함이 없이 형성되었다.

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The structural and dielectric properties of the $BaTiO_{3}+xNb_{2}O_{5}$ ceramics ($BaTiO_{3}+xNb_{2}O_{5}$ 세라믹스의 구조 및 유전특성)

  • 이상철;류기원;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.426-429
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    • 2001
  • The BaTiO$_3$+xNb$_2$O$_{5}$[x=6,8 , 10wt%] ceramics were prepared by conventional mixed oxide method. The structural properties of the BaTiO$_3$+xNb$_2$O$_{5}$ ceramics with the sintering temperature and addition of Nb$_2$O$_{5}$ were investigated by XRD and SEM. Increasing the sintering temperature, the 2$\theta$ value of BT (110) peak was shifted to the lower degree and intensity of the BN (310) peak was increased. Increasing the addition of Nb$_2$O$_{5}$, the intensity of BN (100) Peak was decreased and BN (310), (110) peaks were increased. The grain size of the BaTiO$_3$+Nb$_2$O$_{5}$ ceramics sintered at 135$0^{\circ}C$ were almost uniform. In the BaTiO$_3$+Nb$_2$O$_{5}$ ceramics sintered at 135$0^{\circ}C$, the dielectric constant and dielectric loss were 5424, 0.02 respectively.espectively.

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The Wear Resistance of Electroless Nickel and Electroless Composite(Ni-P-X, X: SiC, $Al_2$O$_3$, Diamond) Coating Layers (무전해 니켈도금과 무전해복합도금(Ni-P-X, X: SiC, $Al_2$O$_3$, Diamond)의 내마모성 비교)

  • Kim, M.;Chang, D. Y.;Jeong, Y. S.;Ro, B. H.;Lee, K. H.
    • Journal of Surface Science and Engineering
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    • v.27 no.4
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    • pp.193-206
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    • 1994
  • A wear behavior of electroless (Ni-P-X, X: SiC, $Al_2O_3$, Diamond) composite coating layers, formed under various conditions on commerical grade low carbon steel, has been investigated using Taber abrasion tester and scanning electron microscope. Several factors, which are type of particles, co-deposited content, particle size, distribution of particles and heat-treatment, influenced the wear resistance. The wear resistance of the composited coating layers after heat-treatment at $400^{\circ}C$ for 1 hr was increased 70 times with diamond, 15 times with SiC and 8 times with $Al_2O_3$, compared with the electroless nickel plating layer without heat-treatment.

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ON 𝜙-SCHREIER RINGS

  • Darani, Ahmad Yousefian;Rahmatinia, Mahdi
    • Journal of the Korean Mathematical Society
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    • v.53 no.5
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    • pp.1057-1075
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    • 2016
  • Let R be a ring in which Nil(R) is a divided prime ideal of R. Then, for a suitable property X of integral domains, we can define a ${\phi}$-X-ring if R/Nil(R) is an X-domain. This device was introduced by Badawi [8] to study rings with zero divisors with a homomorphic image a particular type of domain. We use it to introduce and study a number of concepts such as ${\phi}$-Schreier rings, ${\phi}$-quasi-Schreier rings, ${\phi}$-almost-rings, ${\phi}$-almost-quasi-Schreier rings, ${\phi}$-GCD rings, ${\phi}$-generalized GCD rings and ${\phi}$-almost GCD rings as rings R with Nil(R) a divided prime ideal of R such that R/Nil(R) is a Schreier domain, quasi-Schreier domain, almost domain, almost-quasi-Schreier domain, GCD domain, generalized GCD domain and almost GCD domain, respectively. We study some generalizations of these concepts, in light of generalizations of these concepts in the domain case, as well. Here a domain D is pre-Schreier if for all $x,y,z{\in}D{\backslash}0$, x | yz in D implies that x = rs where r | y and s | z. An integrally closed pre-Schreier domain was initially called a Schreier domain by Cohn in [15] where it was shown that a GCD domain is a Schreier domain.

Dimesogenic Compounds with Chiral Tails: Synthesis and Liquid Crystalline Properties of a Homologous Series of a, w-Bis[4-(4'-(S)-( -)-2-methylbutoxycarbonylbiphenyl- 4-oxycarbonyl)phenoxy]alkanes

  • Choe, Lee Jun;Choe, Bong Gu;Kim, Jae Hun;Jin, Jeong Il
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.110-117
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    • 2000
  • A series of new liquid crystalline dimesogenic compounds with chiral tails was synthesized, and their thermal and liquid crystalline properties were studied. The chain length of the central polymethylene spacers (x) was varied from dimethylene (2) to decamethylene (12). These compounds were characterized by elemental analysis, IR and NMR spectroscopy, differential scanning calorimetry (DSC), and cross-polarizing microscopy. All compounds were found to be enantiotropically liquid crystalline, and the values of melting ($T_m$) and isotropization temperature ($T_i$) as well as enthalpy change (Δ$H_i$) and entropy change for isotropization (Δ$S_i$) decreased in a zig-zag fashion revealing the so-called odd-even effect as x increases. Their mesomorphic properties fall into three categories depending upon x; (a) compounds with x=2 and 4 formed two different mesophases, smectic and cholesteric phases in that order on heating, and vice versa on cooling, (b) compounds with x=3, 7, 8, 10 and 11 reversibly formed only the cholesteric phase, and (c) compounds with x=5, 6, 9 and 12 exhibited only a cholesteric phase on heating, whereas on cooling they formed two different mesophases, cholesteric and smectic phases, sequentially.

Structure and Magnetic Properties of Mechanically Alloyed Sm(Fe,Ti)$_7$ Compounds and Their Nitrides

  • Kim, H.T.
    • Journal of Magnetics
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    • v.6 no.2
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    • pp.57-60
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    • 2001
  • Mechanically alloyed $TbCu_7 -type \;Sm_{12.5}Fe_{87.5-x}Ti_x$(x=0, 2.5, 5, 7.5),and their nitrides have been studied systematically by X-ray diffraction, A.C. initial susceptibility, and pulsed magnetization measurement. In this series, the volume expansion by nitriding is 5.6%~7.3%, and the increment of the Curie temperature is in the range of 21$0^{\circ}C$~35$0^{\circ}C$. With increasing Ti content, the remanence decreases linearly due to the substitution of non-magnetic Ti, and the coercivity decreases rapidly from 34.6 kA/cm (43.5 kOe) for $\chi$=0 to 14.3 kA/cm (18 kOe) for $\chi$=7.5. In the $Sm_{12.5}Fe_{87.5-x}Ti_xN_y$ series, the best magnetic properties were obtained from .7Ti7Ny series, the best magnetic properties were obtained from $Sm_{12.5}Fe_{87.5}N_y$($\chi$=0) with $_iH_c$=34.6 kA/cm (43.5 kOe), $B_r=0.75 \;T, \;and (BH)_{max}=113.8 kJ/m^3$(10.9 MGOe).

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Enhancement of electromechanical properties in lead-free (1-x)K0.5Na0.5O3-xBaZrO3 piezoceramics

  • Duong, Trang An;Nguyen, Hoang Thien Khoi;Lee, Sang-Sub;Ahn, Chang Won;Kim, Byeong Woo;Lee, Jae‒Shin;Han, Hyoung‒Su
    • Journal of Sensor Science and Technology
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    • v.30 no.6
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    • pp.408-414
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    • 2021
  • This study analyzes the phase transition behavior and electrical properties of lead-free (1-x)K0.5Na0.5NbO3-xBaZrO3 (KNN-100xBZ) piezoelectric ceramics. The stabilized crystal structures in BaZrO3-modified KNN ceramics is clarified to be pseudocubic. The polymorphic phase transition from the orthorhombic to pseudocubic phases can be observed with KNN-6BZ ceramics considering the optimized piezoelectric constant (d33). Electromechanical strain behaviors are discussed. Accordingly, the enhancement of strain value at x = 0.08 (composition) may originate from the coexistence of ferroelectric domains and polar nanoregions. A schematic of domains for KNN, KNN-8BZ, and KNN-15BZ ceramics has been proposed to describe the relationship between the stabilized relaxor and changes in electrical properties.

Zr-7Cu Alloy Design According to Sn Content for Bio-Metallic Materials (금속 생체재료를 위한 Sn 함량에 따른 Zr-7Cu 합금설계)

  • Kim, Min-Suk;Kim, Chung-Seok
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.690-696
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    • 2021
  • The purpose of this study is to develop a zirconium-based alloy with low modulus and magnetic susceptibility to prevent the stress-shielding effect and the generation of artifacts. Zr-7Cu-xSn (x = 1, 5, 10, 15 mass%) alloys are prepared by an arc melting process. Microstructure characterization is performed by microscopy and X-ray diffraction. Mechanical properties are evaluated using micro Vickers hardness and compression test. The magnetic susceptibility is evaluated using a SQUID-VSM. The average magnetic susceptibility value of the Zr-7Cu-xSn alloy is 1.176 × 10-8 cm3g-1. Corrosion tests of zirconium-based alloys are conducted through polarization test. The average Icorr value of the Zr-7Cu-xSn alloy is 0.1912 ㎂/cm2. The elastic modulus value of 14 ~ 18 GPa of the zirconium-based alloy is very similar to the elastic modulus value of 15 ~ 30 GPa of the human bone. Consequently, the Sn added zirconium alloy, Zr-7Cu-xSn, is very interesting and attractive as a biomaterial that reduces the stress-shielding effect caused by differences of elastic modulus between human bone and metallic implants. In addition, this material has the potential to be used in metallic dental implants to effectively eliminate artifacts in MRI images due to low magnetic susceptibility.

An empirical study on the X-ray attenuation capability of n-WO3/n-Bi2O3/PVA with added starch

  • Oliver, Namuwonge;Ramli, Ramzun Maizan;Azman, Nurul Zahirah Noor
    • Nuclear Engineering and Technology
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    • v.54 no.9
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    • pp.3459-3469
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    • 2022
  • Matrix composites of n-WO3/n-Bi2O3/PVA with different loadings of n-WO3/n-Bi2O3 mixtures (0-15 wt%) and starch (0 and 3 wt%) were fabricated by using melt-mixing method. The X-ray attenuation capability were evaluated based on mass attenuation coefficient (μ/⍴) using a general diagnostic X-ray machine at 40-100 kVp. The effect of starch addition on the dispersion of the fillers in the PVA matrix were observed by using FESEM through morphological analysis. The fabricated samples have shrunken and caused their thickness to be decreased (0.35 mm-0.55 mm) after the drying process even though fixed thickness (2.0 mm) was set initially. The density and HVL values of the samples with 3 wt% starch was seen lower than samples without starch (0 wt%), however the former have provided improvement in filler dispersion and better X-ray attenuation capability compared to the latter. As conclusion, the matrix composite of n-WO3/n-Bi2O3/PVA with 15 wt% of n-Bi2O3, 8 wt% of n-WO3 and 3 wt% starch can be selected as the best promising candidate for X-ray shielding materials.