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A Study on the Effect of "ADAPTAGEN"$^{\textregistered}$ Korean Ginseng Components, for the Injured Mouse by X-ray($^{60}Co$) Irradiation (X-방사선($^{60}Co$)에 조사된 새앙쥐의 상해에 대한 "아답태겐"$^{\textregistered}$의 효과에 관한 연구)

  • 공태훈;유성렬
    • Journal of Ginseng Research
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    • v.15 no.3
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    • pp.171-178
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    • 1991
  • The results ok feeding experiments to the mice with ginseng extract, ginseng Powder, and ADAPTAGEN, for 30 days before X-ray irradiation and for 40 days after the X-ray irradiation at 750 rads were as follow: 1. The 50% lethals days (LD50, ) by the X-ray irradiation were 9 days at 1, 000 rads. 10 days at 900 rads, 11 days at 800 rads, 14 days at 760 rads, and 19 darts at 750 rads. Therefore, the standard radiation dose was set at 750 radb/8 min. 2. The 80% of the control group mice exposed to the X-ray radiation without ginseng feeding died in periods ranging from 14 to 24 days and the 20~30% of the ginseng extract and ginseng powder feeding groups died. But the 100% of the mice fed with ADAPTAGEN survived. 3. Testicles of the control group became smaller in weight than the nomad group by 26.5 to 29.0% and those of the ginseng extract and ginseng powder feeding group reduced by 44.6 to 60.4%. However, testicles of the ADAPTiIGEN feeding group increased in size by 77.4% to 87.1% and in weight by 61%, showing a recovery phenomenon approarhing to those of the ordinary mice. The ADAPTAGEN feeding group mice were also as active in color as the ordinary ones. 4. An electron micrograph(X8, 000X2.2) of the liver cells of the mice which had been 40 days after X-ray irradiation showed as follows; The control group appeared that is physiological action stopped due to the frequent occurrence of morphological change of the nucleus and diffusion of chromosome, reduction in microspores and expansion of microsomts, and endoplasmic change of mitochondria. The liver cells or the ADAPTAGEN feeding group were in a state similar to those of the ordinary mice restoring to normalcy In contrast, the liver cells of the ginseng extract and ginseng powder feeding groups were still far from being normal. 5. A serological analysis showed that the control group sharply decreased in albumin, Y-g1obu1in, and IgG so far as to cause dystrophy and to weaken antibody resistance but that ginseng extract and ginseng powder feeding groups, though in a little more restoring state than the control group, were still far from the normal group. The ADAPTAGEN feeding group restored to a state as comparable to the normal group in the contents of albumin ${\gamma}$-globulin, IgG and serum protein. In order words, it is noteworthy that ADAPTAGEN feeding was effective in revitalizing the destroyed cells of a living body and that it has the function of normalizing antibody components.

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De-NOX evaluation of SCR catalysts adding vanadium-graphene nanocomposite (바나듐 담지된 그래핀 나노복합체를 첨가한 SCR 촉매의 제조 및 활성 평가)

  • Jeong, Bora;Lee, Heesoo;Kim, Eok-Soo;Kim, HongDae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.252-256
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    • 2015
  • Nitrogen oxides ($NO_X$) was emitted from flue gas of stationary sources and exhaust gas of mobile sources, can leads to various environments problems. Selective Catalysts Reduction (SCR) is the most effective $NO_X$ removal system. Commercial $V_2O_5-WO_3/TiO_2$ catalysts, usually containing $V_2O_5$ 0.5~3 wt%, $WO_3$ 5~10 wt%, and $V_2O_5$ is active in the reduction of $NO_X$ but also in the desired oxidation of $SO_2$ to $SO_3$. To reduce the amount of vanadium, using graphene matrix supported vanadium to synthesize nanocomposite. Then, we fabricated to 1 inch honeycomb type of SCR catalysts adding graphene-vanadium nanocomposite. The chemical-physical characteristics and the catalytic activity were performed by XRD, XRF, BET and Micro-Reactor (MR). As a result, the De-NOX performance was showed, similar to the commercial catalyst activity as 77.8 % and using nanocomposite catalyst as 77.1 % at $350^{\circ}C$.

Zn/Co ZIF derived synthesis of Co-doped ZnO nanoparticles and application as high-performance trimethylamine sensors (Co가 도핑된 ZnO 나노입자의 Zn/Co ZIF 유도 합성 및 고성능 트리메틸아민 센서로의 응용)

  • Yoon, Ji-Wook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.5
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    • pp.222-227
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    • 2018
  • $Zn_{1-x}Co_x$ Zeolitic Imidazolate Framework (ZIF) (x = 0~0.05) were prepared by the co-precipitation of $Zn^{2+}$ and $Co^{2+}$ using 2-methylimidazole, which were converted into pure and Co-doped ZnO nanoparticles by heat treatment at $600^{\circ}C$ for 2 h. Homogeneous Zn/Co ZIFs were achieved at x < 0.05 owing to the strong coordination of the imidazole linker to $Zn^{2+}$ and $Co^{2+}$, facilitating atomic-scale doping of Co into ZnO via annealing. By contrast, heterogeneous Zn/Co ZIFs were formed at $x{\geq}0.05$, resulting in the formation of $Co_3O_4$ second phase. To investigate the potential as high-performance gas sensors, the gas sensing characteristics of pure and Co-doped ZnO nanoparticles were evaluated. The sensor using 3 at% Co-doped ZnO exhibited an unprecedentedly high response and selectivity to trimethylamine, whereas pure ZnO nanoparticles did not. The facile, bimetallic ZIF derived synthesis of doped-metal oxide nanoparticles can be used to design high-performance gas sensors.

Enhanced Electrochemical Performance of NaxFe2(CN)6 Positive Electrode Materials for Lithium-ion Batteries (리튬이온 이차전지용 양극물질로서 NaxFe2(CN)6의 전기화학적 성능개선 연구)

  • Yoo, Seong Tae;Yoon, Seung Ju;Kang, Jeong Min;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.23 no.1
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    • pp.11-17
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    • 2020
  • The Prussian blue analogues of Fe2(CN)6 and NaxFe2(CN)6 are prepared by precipitation method and evaluated the electrochemical characteristics as positive electrode materials for lithium-ion batteries (LIBs) because of their low cost. Fe2(CN)6 shows a low reversible capacity of 34.6 mAh g-1, whereas sodium-containing NaxFe2(CN)6 exhibits a reversible capacity of 107.5 mAh g-1 when the discharge process proceeds first. When charging is first carried out to remove sodium in the structure, the reversible capacity of 114.1 mAh g-1 is achieved and the cycle performance is further improved. In addition, Nax-Fe2(CN)6 is synthesized at 0℃, room temperature (RT), and 60℃, respectively. Regardless of the synthesis temperature, NaxFe2(CN)6 shows similar initial reversible capacity, but the crystallite size is formed smaller and improved cycle performance when synthetic temperature is lower. The sample synthesized at 0℃ shows a reversible capacity of 86.4 mAh g-1 at the 120th cycle and maintains 76.8% of the initial capacity.

Nano-Mechanical Studies of HfOx Thin Film for Oxygen Outgasing Effect during the Annealing Process (고온 열처리 과정에서 산소 Outgasing 효과에 의한 HfOx 박막의 Nanomechanics 특성 연구)

  • Park, Myung Joon;Kim, Sung Joon;Lee, Si Hong;Kim, Soo In;Lee, Chang Woo
    • Journal of the Korean Vacuum Society
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    • v.22 no.5
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    • pp.245-249
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    • 2013
  • The $HfO_X$ thin film was deposited what it has been paid attention to the next generation oxide thin layer of MOSFET (metal-Oxide semiconductor field-effect-transistor) by rf magnetron sputter on Si (100) substrate. The $HfO_X$ thin film was deposited using a various oxygen gas flows (5, 10, 15 sccm). After deposition, $HfO_X$ thin films were annealed from 400 to $800^{\circ}C$ for 20 min in nitrogen ambient. The electrical characteristics of the $HfO_X$ thin film was improved by leakage current properties, depending on the increase of oxygen gas flow and annealing temperature. In particular, the properties of nano-mechanics of $HfO_X$ thin films were measured by AFM and Nano-indenter. From the results, the maximum indentation depth at the basis of maximum indentation force was increased from 24.9 to 38.8 nm according to increase the annealing temperature. Especially, the indentation depth was increased rapidly at $800^{\circ}C$. The rapid increasement of indentation depth was expected to be due to the change of residual stress in the $HfO_X$ thin film, and this result was caused by relative flux of oxygen outgasing during the annealing process.

Usefulness of Non-Invasive Measurement Tool on Performance Evaluation of Inverter Type X-ray Unit (인버터식 X선장치의 성능평가 시 비접속형 측정기의 유용성)

  • Kang, Se-Sik;Kim, Chang-Soo;Ko, Sung-Jin
    • Journal of radiological science and technology
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    • v.31 no.2
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    • pp.123-127
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    • 2008
  • Purpose: As the demand of a simple and precise method increases to evaluate the performance of the inverter type x-ray unit, we evaluated the usefulness of the recently-introduced X-ray Multi-Function Test Device (moldel : Xi (unfors)-prestige). Method: We compared the performance of X-ray Multi-Function Test Device (XMFTD) which is non-inveasive type device with the performance of Dynalyzer III that has been most widely used inveasive type measure device. Result: X-ray output dose was increased a little in the XMFTD, but both devices were below the performance evaluation standard, 0.002 in the output reproducibility. Linearity of XMFTD were below 0.1 which means that Dynalyzer III showed more excellency in linearity. As the the accuracy of exposure factor, 1.8 and 2 tube voltage, 2.01 and 2.3 tube current were measured. The exposure time was also measured by 0.01 sec ${\pm}10%$. Both devices were within the acceptance of performance evaluatioin standard. Conclusion: We proved the usefulness of X-ray Multi-Function Test Device (model: Xi (unfors)-prestige) to evaluated the performance on reproductibility and linearity of X-ray output and accuracy of exposure factor of inverter type unit.

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Fabrication of X-ray monocapillary optics for soft X-ray fluorescence analysis (경 X선 형광분석을 위한 모세관 광학소자 제작)

  • Cho, Hyung-Wook;Park, Byung-Hoon;Kim, Yong-Min;Choi, Chul-Hee;Choi, Seong-Hee;Kim, Ki-Hong;Chon, Kwon-Su
    • Journal of the Korean Society of Radiology
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    • v.5 no.6
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    • pp.409-413
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    • 2011
  • An X-ray tube used an X-ray fluorescence analysis system has a low X-ray photon intensity which results in reducing measurement accuracy and increasing exposure time. These shortages can be overcame by using a monocapillary optics. A monocapillary optics was optimally designed for focusing the characteristic X-ray of tungsten (8.4 keV). The monocapillary optics can achieve a gain of 10 at the least. The monocapillary optics was fabricated by using puller and pyrex glass, raw material. In fabrication, a weigh of 45g and a temperature of $650^{\circ}$ was loaded. The total fabrication time was 460 minutes. The fabricated capillary had 87 mm in length and maximum diameter of 300 ${\mu}m$ and minimum diameter of 192 ${\mu}m$. When the fabricated monocapillary optics is applied to an X-ray fluorescence analysis system, the detection accuracy for soft elements, for example sulfur (S), will be improved.

Studies on peptides during soybean-koji preparation -part I Peptides formation during soybean-koji preparation- (콩고오지 제조중(製造中)의 peptide에 관(關)한 연구(硏究) -제1보(第一報) 콩고오지 제조중(製造中)의 peptide의 소장(消長)-)

  • Kim, Ze-Uook
    • Applied Biological Chemistry
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    • v.6
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    • pp.79-87
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    • 1965
  • The contents of insoluble protein nitrogen, water soluble protein nitrogen anti peptides' nitrogen were determined of the samples which were taken in seven and half hours intervals during soybean-koji preparation to study changes of soybean protein, and the contents of total nitrogen and amino nitrogen were measured for the fractions resulting from molecular sieving by using Dowex 50 having various cross linkages for the peptides from soybean-koji extracts. As the results of the studies, The followings were obtained: 1. The contents of insoluble protein nitrogen and peptides' nitrogen are fairy constant at the earlier stage, where the former decreased and the latter increased markedly as mycelia grow, then rate of the decreases and the increases of them become lower at later stage after sporulation. The contents of water soluble protein are also constant at the earlier stage until covering of mycelia over the koji and increased since then until the stage of sporulation and then decreased at the later stage. 2. The amount of peptides nitrogen in each fraction obtained by the molecular sieving was almost constant at the earlier stage and the values in fractions of X-16, X-12, X-8. X-4 and X-2 increased considerably together as mycelia grow. Then the values in the fractions showed almost plateaux, after sporulalion, where the effluent fraction showed markedly increased values throughout mycelia growth.

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Relations between Composition, Temperature and Electrical Conductivity of (60-xSiO2-40Na2O-xCaO(x=0∼15wt%) Glass System ((60-x)SiO2-40Na2O-xCaO(x=0∼15wt%)조성유리계의 조성, 온도 및 전기전도도간의 상관특성)

  • Jung, Y.J.;Lee, K.H.;Kim, T.H.;Kim, Y.S.;Chin, H.J.;Ryu, B.K.
    • Korean Journal of Materials Research
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    • v.17 no.8
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    • pp.414-419
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    • 2007
  • We report the electrical conductivity of the mixed alkali silicate glasses in the system (60-x)$SiO_2-40Na_2O-xCaO(x=0\sim15wt%)$ in the temperature range from $150^{\circ}C$ to $620^{\circ}C$. In the range from $150^{\circ}C$ to glass transition temperature$(T_g)$, the electrical conductivities of glass samples had a tendency to be proportion with temperature. The glasses of containing over 7.5wt% CaO showed lower conductivities than the glasses of containing 0 and 5wt% CaO because two kinds of alkali ions$(Na^+,\;Ca^{2+})$ were obstructed each other. On the other hand, in the range from $T_g$ to $620^{\circ}C$, the electrical conductivity of glasses($7.5{\leq}x{\leq}12.5$) was unstable and decreased in some region. From XRD results, the $Na_4Ca(SiO_3)_3$ phase were observed in these glasses. This means the alkali ions didn't behave as carrier, it seems that this caused the conductivities decrease. In case of glass of containing 15wt% CaO, any crystal phase were not observed. This means the alkali ions behaved as carrier, it consequently seems the conductivity increased.

Synthesis and Electrochemical Characteristics of Carbon Coated SiOx/ZnO Composites by Sol-gel Method (졸겔법으로 제조한 탄소피복된 SiOx/ZnO 복합체의 합성 및 전기화학적 특성)

  • Baek, Gwang-Yong;Jeong, Sang Mun;Na, Byung-Ki
    • Clean Technology
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    • v.22 no.4
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    • pp.308-315
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    • 2016
  • $SiO_x/ZnO$ composites were prepared from sol-gel method for excellent cycle life characteristics. The composites were coated by PVC as a carbon precursor. ZnO removal to create a void space therein was able to buffer the volume change during charge and discharge. To determine the crystal structure and the shape of the synthesized composite, XRD, SEM, TEM analysis was performed. The carbon contents in the composites were confirmed by TGA. The pore structure and pore size distribution of the composite was measured with the BET specific surface area analysis and BJH pore size distribution. Enhanced electric conductivity by carbon addition was determined from powder resistance measurement. Electrochemical properties were measured with the AC impedance and the charge and discharge cycle life characteristics. When carbon was coated on the $SiO_x/ZnO$ sample, the electrical conductivity and the discharge capacity were increased. After removal of ZnO with HCl the surface area of the sample was increased, but the discharge capacity was decreased. $SiO_x/ZnO$ sample without acarbon coating showed very low discharge capacity, and after carbon coating the sample showed high discharge capacity. For cycle life characteristics, $C-SiO_x/ZnO$ composite (Zn : Si : C = 1 : 1 : 8) with a capacity of $815mAh\;g^{-1}$ at 50 cycle and 0.2 C has higher capacity than existing graphite-based anode materials.