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Ion Exchange Characteristics of Novel HDBPDA and Dowex Ion Exchange Resins (새로운 HDBPDA와 Dowex 이온교환수지의 이온교환 특성)

  • Kim, Dong Won;Kim, Chang Suk;Choi, Ki Young;Jeon, Young Shin;Jeong, Young Kyu;Yoon, Yeo Hag;Hon, Choon Pyo
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.463-469
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    • 1993
  • HDBPDA ion exchange resin, {(4, 5) : (13, 14)-Dibenzo-6, 9, 12-trioxa-3, 15, 21, -triazabicyclo [15. 3. 1]heneicosa-(1, 17, 19)(18, 20, 21) triene ion exchange resin : HDBPDA ion exchange resin} had a capacity of 3.8meq/g dry resin. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA and strongly acidic cation exchange resin, Dowex 50W-X8(200-400mesh) in water, and the various concentrations of hydrochloric acid were determined. Concentration of hydrochloric acid have almost not influenced on the distribution coefficients of alkali and alkaline earth metal ions for the HDBPDA ion exchange resin, but generally the distribution coefficient slightly increased with decreasing concentration of hydrochloric acid. The distribution coefficients of metal ions in water are larger than those in various hydrochloric acid concentration. The distribution coefficients of alkali and alkaline earth metal ions for the Dowex 50W-X8 ion exchange resin increased with decreasing hydrochloric acid concentration. Especially, the distribution coefficients of alkaline earth metal ions increased rapidly compared to those for alkali metal ions. The distribution coefficients of alkali and alkaline earth metal ions on HDBPDA ion exchange resin increased in a linear manner with decreasing acid concentration, and the slope, d log Kd/d log $M_{HCl}$ is about -0.2. Of the distribution cofficients of alkali metal ions on Dowex 50W-X8, at range of moderate hydrochloric acid concentration, the slope is about -1, while the slope for alkaline earth metal ions is about -2. However, at very low hydrochloric acid concentration, the linear variation between distribution coefficient and acid concentration was not occurred, but the slope was deviated from above values at low acid concentration.

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Characteristics of MnxSi1-xTe Compound Studied by Electron Magnetic Resonance and Other Experiments

  • Na, Sung-Ho;Kim, Heung-Chul;Park, Jung-Woo;Kim, Jang-Whan
    • Journal of Magnetics
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    • v.13 no.1
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    • pp.23-29
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    • 2008
  • The magnetic and other physical characteristics of $Mn_xSi_{1-x}Te$ have been investigated by electron magnetic resonance (EMR), X-ray diffraction (XRD) and other experiments. $Mn_xSi_{1-x}Te$ is found to have corundum structure for manganese contents up to 10% and also to be ferromagnetic for temperatures below 80 K. While ferromagnetic resonance signal coexists with the usual paramagnetic resonance signal, invariance of the g-factor inferred from the electron paramagnetic resonance signals throughout all temperature ranges clearly confirms that the manganese ions are in the electronic 3d5 state. The temperature dependence of EMR line-width is the same as other diluted magnetic semiconductors. From the EMR signals relaxation times $T_2$ and $T_1$ of $Mn_xSi_{1-x}Te$ compounds are estimated to be about $4.4{\times}10^{-10}s$ and $9.3{\times}10^{-8}s$ respectively and are found to vary slightly with temperature or composition change. Exchange narrowing of the EMR line-width becomes dominant for the sample in which the substitution ratio, x = 30%. For one sample, in which x = 0.5%, spin glass-like behavior is indicated by EMR signals for temperatures lower than 60 K. This behavior may authentic for samples within a certain range of x.

Effect of $CaTiO_3$Additions on Microwave Dielectric Properties in $BaWO_4$-$Mg_2$$SiO_4$Ceramics ($BaWO_4$-$Mg_2$$SiO_4$세라믹스의 $CaTiO_3$첨가에 따른 고주파 유전특성)

  • 박일환;김경용;김병호
    • Journal of the Korean Ceramic Society
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    • v.38 no.3
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    • pp.280-286
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    • 2001
  • 10 이하의 저유전율을 갖는 (1-x)BaWO$_4$-xMg$_2$SiO$_4$(x=0.1~0.9) 세라믹스의 미세구조와 고주파 유전특성을 조사하였다. (1-x)BaWO$_4$-xMg$_2$SiO$_4$(x=0.1~0.9) 세라믹스는 정방정(tetragonal) 구조를 가진다. 0.1BaWO$_4$-0.9Mg$_2$SiO$_4$세라믹스는 BaWO$_4$$Mg_2$SiO$_4$의 상들이 공존하는 혼합상을 보였으며, $Mg_2$SiO$_4$가 이차사으로 형성된 것이 관찰되었다. 120$0^{\circ}C$~140$0^{\circ}C$에서 2시간 동안 소결된 (1-x)BaWO$_4$-xMg$_2$SiO$_4$(x=0.1~0.9) 세라믹스는 $\varepsilon$$_{r}$=6.37~8.21, Q.f=15000~99422 그리고 $ au$$_{f}$=73.9~48.9 ppm/$^{\circ}C$의 고주파 유전특성을 가졌다. $\tau$$_{f}$를 보정하기 위해, CaTiO$_3$(1,5 wt%)가 (1-x)BaWO$_4$-xMg$_2$SiO$_4$(x$\geq$0.9) 세라믹스에 첨가되었다. 135$0^{\circ}C$에서 2시간 동안 소결된 0.1BaWO$_4$-0.9Mg$_2$SiO$_4$+CaTiO$_3$(5 wt%) 세라믹스는 $\varepsilon$$_{r}$=7.3, Q.f=30532 그리고 $\tau$$_{f}$=-30 ppm/$^{\circ}C$의 고주파 유전특성을 얻었다. 얻었다.

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Bandgap Control of (AlxGa1-x)2O3 Epilayers by Controlling Aqueous Precursor Mixing Ratio in Mist Chemical Vapor Deposition System (미스트화학기상증착시스템의 전구체 수용액 혼합비 조절을 통한 (AlxGa1-x)2O3 에피박막의 밴드갭 특성 제어 연구)

  • Kim, Kyoung-Ho;Shin, Yun-Ji;Jeong, Seong-Min;Bae, Si-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.528-533
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    • 2019
  • We investigated the growth of $(Al_xGa_{1-x})_2O_3$ thin films on c-plane sapphire substrates that were grown by mist chemical vapor deposition (mist CVD). The precursor solution was prepared by mixing and dissolving source materials such as gallium acetylacetonate and aluminum acetylacetonate in deionized water. The [Al]/[Ga] mixing ratio (MR) of the precursor solution was adjusted in the range of 0~4.0. The Al contents of $(Al_xGa_{1-x})_2O_3$ thin films were increased from 8 to 13% with the increase of the MR of Al. As a result, the optical bandgap of the grown thin films changed from 5.18 to 5.38 eV. Therefore, it was determined that the optical bandgap of grown $(Al_xGa_{1-x})_2O_3$ thin films could be effectively engineered by controlling Al content.

Estimation of leeway of jigging fishing vessels by external factors (외력에 의한 채낚기 어선의 표류 추정)

  • Chang-Heon, LEE;Kwang-Il, KIM;Joo-Sung, KIM;Sang-Lok, YOO
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.58 no.4
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    • pp.299-309
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    • 2022
  • Among the fishing vessels operating in the coastal waters, jigging fishing vessels were considered representative vessels engaged only by wind, sea, tide, and external force. Then, a fishing vessel with a length of shorter than 10 m from July 1, 2018 to August 5, 2019 was studied to obtain a drift prediction model by multiple regression analysis. In the correlation analysis between variables for leeway of speed and direction, the speed and direction of tidal seem to be the most affected in coastal waters. Therefore, it should be considered an explanatory variable when conducting drift tests. As a result of multiple regression analysis on the predicted equations of leeway speed and direction due to the external force on the drift of the fishing vessel, p < 0.000 was considered significant in the F-test, but the coefficient of determination was 55.2% and 37.8%. The effect on the predicted leeway speed was in the order of the tidal speed and current speed. In addition, the impact on the predicted leeway direction was in the order of the tidal speed and current speed. ŷ(m/s) = - 0.0011(x1) + 0.9206(x2) + 0.0001(x3) + 0.0002(x4) + 0.0050(x5) + 0.0529(x6) + 0.2457 ŷ(degree) = 0.6672(x1) + 93.1699(x2) + 0.0585(x3) - 0.0244(x4) - 1.2217(x5) + 4.6378(x6) - 0.0837

Synthesis and Densification Behavior of Al Doped (La0.8Ca0.2)(Cr0.9Co0.1)O3(LCCC) Ceramics for SOFC Interconnects (SOFC 연결재용 Al이 도핑된 (La0.8Ca0.2)(Cr0.9Co0.1)O3(LCCC)계 세라믹스의 합성 및 치밀화 특성)

  • Lee, Ho-Young;Kang, Bo-Kyung;Lee, Ho-Chang;Heo, Young-Woo;Kim, Jeong-Joo;Kim, Jae-Yuk;Lee, Joon-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.5
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    • pp.392-397
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    • 2012
  • In the $(La_{0.8}Ca_{0.2})(Cr_{0.9}Co_{0.1})O_3$ (LCCC), which has been using as interconnector materials in SOFC, Al ions were substituted for Co because ionic radius of Al is similar to that of Co. Because of the almost identical ionic radius of Al and Co, the substitution was not thought to be affect the tolerance factor of LCCC, and the densification behavior, high temperature electrical conductivity and thermal expansion coefficient were examined as a function of Al concentration. In the cases of the x= 0 and x= 0.02 in $(La_{0.8}Ca_{0.2})(Cr_{0.9}Co_{0.1-x}Al_x)O_3$ (x= 0~0.1), the samples showed the relative densities above ${\geq}95%$ when those were sintered at ${\geq}1,350^{\circ}C$. In the case of the $x{\geq}0.06$ the sintered density deteriorated greatly at lower sintering temperatures. High temperature electrical conductivity of the samples decreased as the content of Al increased. Since the valence state of Al ion is unchangeable, while Cr or Co ions contribute to the electrical conduction by changing those valence states, Al substitution resulted in the decreased electrical conductivity. Al doping of LCCC was an effective way of decreasing the thermal expansion coefficient (TEC).

Multi-band directional antenna for satellite communications (위성 통신용 다대역 안테나)

  • Cheong, Chi-Hyun;Jeong, Hye-Mi;Kim, Kun-Woo;Bae, Ki-Hyoung;Tae, Hyun-Sik;Evtyushkin, Gennadiy
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.12
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    • pp.1223-1231
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    • 2010
  • The design is presented for a SATCOM antenna capable of simultaneous multi-band (X/Ku/Ka-Band) communications without replacement of feed horns or change of other parts in the application as a ground satellite terminal for large data transfer. The antenna is the offset configuration and consists of a dual-band(X/Ka-band) feed horn, a single-band(Ku-band) feed horn, a frequency selective surface(FSS) sub-reflector and a parabolic main-reflector. The antenna has a main reflector defining a prime focus and a frequency selective surface sub-reflector defining an image focus. A dual-band feed and a single-band feed are provided at each of the prime focus and image focus. The antenna is designed using 3D EM simulator and the gains measured in X/Ku/Ka-band of the complete antenna assembly is more than 31.6dBi, 36.8dBi, 40.8dBi, and the cross polarization is 21.7dB, 26.6dB, 25.2dB, respectively.

Ecological Studios on the Bark Beetles on Plum and Apricot (자두와 살구나무에 기생하는 나무좀의 생태에 관한 연구)

  • Yoon J. K.;Kim K. C.;Cheon S. J.;Kim Y. S.
    • Korean journal of applied entomology
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    • v.21 no.2 s.51
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    • pp.78-86
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    • 1982
  • The ecological studies were conducted to identify some bark-beetles on apricot and plum trees in Jeonnam province. Harmful bark-beetles caught from apricot and plum trees were identified as Scolytus seulensis. Xyleborus atratus., X. germanus, X. rubricollis and X. saxeseni. The seoul barkbeetle emerged during the period from early May to late October $1980\~1981$, it happens twice in a year, with the peak July 10 and August 25 in 1950, July 15 and August 20 in 1981. A daily peak emerged for adults was at 11 AM to 1 PM. Distribution of holes on the apricot stems varied; more than 100 holes per meter in Henderson (Apricot) and Y-49057 (Apricot), 12 holes per meter in Derbyroyal (Apricot). Comparatively more holes were found in the European variety, and the cardinal distribution was in the order of east, south, west and north. The longer the longth of the mother-gallery, the greater number of egg-gallery found. Optimum temperature for mating was $27^{\circ}C$. The time for mating was longer during May-June than July-August. The fruit weight of damaged plum tree reached 12.25g around four weeks after flowering; where as that of normal tree increased up to 63.5g at harvest time. The natural enemy of the seoul bark beetle was Eurytoma sp. They were found as mature larva or pupa and they emerged from early May to the middle of June. Adult longevity was about a week.

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Electrochemical Characteristics of Cr Added Li4Ti5O12 Prepared by Sol-gel Method (졸-겔법으로 합성한 Cr 첨가 Li4Ti5O12의 전기화학적 특성)

  • Kim, Sun-Ah;Cho, Woo-Ram;Jeong, Koo-Hyun;Cho, Byung-Won;Na, Byung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.14 no.1
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    • pp.27-32
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    • 2011
  • The electorchemical properties of $Li_4Ti_5O_{12}$ added with Cr was tested. The addition or substitution of atoms to $Li_4Ti_5O_{12}$ are expected to modify the crystal structure, and therefore to change the electrochemical performances of $Li_4Ti_5O_{12}$. After the spinel structure $Li_4Ti_{5-x}Cr_xO_{12}$ (x = 0~0.2) were obtained via sol-gel method, the gel was heated in a muffle furnace at $800{\sim}850^{\circ}C$ for 12 h in air. The physical properties of the samples were characterized by TG-DTA, XRD, SEM, FT-IR, and the electrochemical properties were tested with battery cycler at 0.01~2.0 V range. The $Li_4Ti_5O_{12}$ exhibited 169.9 mAh/g at 1C and capacity recovery was 97.5% of the initial capacity at 0.1C. $Li_4Ti_{4.9}Cr_{0.1}O_{12}$ (Cr 1% added) showed best performance of 193.8 mAh/g at 1C and the capacity recovery was increased to 98.8% of the initial capacity at 0.1C.

LONG-TERM X-RAY VARIABILITIES OF THE SEYFERT GALAXY MCG-2-58-22 : SECULAR FLUX DECREASE AND FLARES

  • CHOI CHUL-SUNG;DOTANI TADAYASU;CHANG HEON- YOUNG;YI INSU
    • Journal of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.1-7
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    • 2002
  • We have studied the long-term X-ray light curve (2-10 keV) of the luminous Seyfert 1 galaxy MCG-2-58-22 by compiling data, from various X-ray satellites, which together cover more than 20 years. We have found two distinct types of time variations in the light curve. One is a gradual and secular decrease of the X-ray flux, and the other is the episodic increase of X-ray flux (or flare) by a factor of 2-4 compared with the level expected from the secular variation. We detected 3 such flares in total; a representative duration for the flares is $\~$2 years, with intervening quiescent intervals lasting $\~$6-8 years. We discuss a few possible origins for these variabilities. Though a standard disk instability theory may explain the displayed time variability in the X-ray light curve, the subsequent accretions of stellar debris, from a tidal disruption event caused by a supermassive black hole in MCG-2-58-22, cannot be ruled out as an alternative explanation.