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X-ray Photoemission Spectroscopy Study of Cation-Deficient La$_{0.970}$Mn$_{0.970}$O$_3$ System (양이온 결손 La$_{0.970}$Mn$_{0.970}$O$_3$의 X-ray Photoemission Spectroscopy 관측)

  • 정우환
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.50-54
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    • 1999
  • We have measured the x-ray photoemission spectroscopy of cation deficient La0.970Mn0.970O3 as a function of temperature. Detailed results on the chemical shifts and changes in Mn 2p and Lp 3d core levels due to variation of temperature have been obtained. The Mn 2p 3/2 and 1/2 main peaks and La 3d core spectrum shift to lower binding energy levels with increasing temperature. This XPS behavior is correlated with the strength of localization of Mn3+. The Jahn-Teller effect due to Mn3+ besides the conventional random potential effects is likely to localize charge carriers in La-.970Mn0.970O3.

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Ammonia Adsorption Capacity of Zeolite X with Different Cations (Zeolite X의 양이온에 따른 암모니아 흡착 성능 연구)

  • Park, Joonwoo;Seo, Youngjoo;Ryu, Seung Hyeong;Kim, Shin Dong
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.355-359
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    • 2017
  • Zeolite X with Si/Al molar ratio = 1.08~1.20 was produced using a hydrothermal synthesis method. Ion-exchanged zeolite X samples were then prepared by using metal nitrate solutions containing $Mg^{2+}$ or $Cu^{2+}$. For all zeolite X samples, X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectrometry (EDS) were used to identify the change in crystal structure. The analysis of ammonia adsorption capability of zeolite X samples was conducted through the ammonia temperature-programmed desorption ($NH_3$-TPD) method. From XRD results, the prepared zeolite X samples maintained the Faujasite (FAU) structure regardless of cation contents in zeolite X, but the crystallinity of zeolite X containing $Mg^{2+}$ and $Cu^{2+}$ cations decreased. The distribution of cation contents in zeolite X was identified via EDS analysis. $NH_3$-TPD analysis showed that the $NH_3$ adsorption capacity of $Mg^{2+}$- and $Cu^{2+}$-zeolite X were 1.76 mmol/g and 2.35 mmol/g, respectively while the $Na^+$-zeolite X was 3.52 mmol/g ($NH_3/catalyst$). $Na^+$-zeolite X can thus be utilized as an adsorbent for the removal of ammonia in future.

SOME PROPERTIES OF $D^n$-GROUPS

  • Kim, In-Su
    • Bulletin of the Korean Mathematical Society
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    • v.26 no.1
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    • pp.1-9
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    • 1989
  • In 1980 and 1983, it was proved that P $D^{2}$-groups are surface groups ([2], [3]). Since then, topologists have been positively studying about P $D^{n}$ -groups (or $D^{n}$ -groups). For example, let a topological space X have a right .pi.-action, where .pi. is a multiplicative group. If each x.memX has an open neighborhood U such that for each u.mem..pi., u.neq.1, U.cap. $U_{u}$ =.phi., this right .pi.-action is said to be proper. In this case, if X/.pi. is compact then (1) .pi.$_{1}$(X/.pi).iden..pi.(X:connected, .pi.$_{1}$: fundamental group) ([4]), (2) if X is a differentiable orientable manifold with demension n and .rho.X (the boundary of X)=.phi. then $H^{k}$ (X;Z).iden. $H_{n-k}$(X;Z), ([6]), where Z is the set of all integers.s.

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Effects of the X Chromosome on the Formation of Sex Comb and Genital Aech in the Hybrids between Drosophila simulans and D. Mauritiana (Drosophila simulans와 D. mauritiana 사이 종간잡종의 성즐과 생식궁 형성에 미치는 X 염색체의 효과)

  • 최영현;유미애;이원호
    • Korean journal of applied entomology
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    • v.35 no.3
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    • pp.216-220
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    • 1996
  • Drosophila simulans and D. mauritiana are sibling species, the former cosmopolitan and the latter restricted to the oceanic island of Mauritius. Sex comb-tooth number of male flies of D. simulans were about 9.83, while those of D. mauritiana were 12.90. Genital arch of D. simulans is large semicircular shaped expasion, while that of D. mauritiana is a narrow fingerlike expansion. We used classical genetic analysis to measure effects of genes on the X chromosome responsible for numeral and morphological differences in sex comb-tooth and genital arch between these species, respectively. For these purposes, mutant strain of D. simulans and wild type strain of D. mauritiana were hybridized and males of the FI and the backcrossed progenies were compared with two characters above mentioned. The sex comb-tooth number of F, males were about 11.79, and the genitalia of F, male were intermediate in shape between those of D. simulans and D. mauritiana. Genetic analysis of sex comb-tooth number and genital arches differing between D. simulans and D. mauritiana showed that very little diffemce was due to effect of the X chromosome.

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Application of Layered Perovskites Substituted with Co and Ti as Electrodes in SOFCs (Co 및 Ti가 치환된 Layered perovskite의 SOFC 전극에 대한 적용성 연구)

  • Kim, Chan Gyu;Shin, Tae Ho;Nam, Jung Hyun;Kim, Jung Hyun
    • New & Renewable Energy
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    • v.18 no.2
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    • pp.40-49
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    • 2022
  • In this study, the phase and electrochemical properties of Co and Ti substituted layered perovskites SmBaCo2-xTixO5+d (x=0.5, 0.7, 1.0, 1.1, 1.3, and 1.5) were analyzed, and their application as electrodes in solid oxide fuel cells (SOFCs) were evaluated. After calcination at 1300℃ for 6 h, a single phase was observed for two compositions of the SmBaCo2-xTixO5+d oxide system, SmBaCoTiO5+d (x=1.0) and SmBaCo0.9Ti1.1O5+d (x=1.1). However, the phases of SmBaCoTiO5+d (SBCTO) and SmTiO3 coexisted for compositions with x≥1.3 (Ti content). In contrast, for compositions of x≤0.7, the SmBaCo2O5+d phase was observed instead of the SmTiO3 phase. To evaluate the applicability of these materials as SOFC electrodes, the electrical conductivities were measured under various atmospheres (air, N2, and H2). SBCTO exhibited stable semi-conductor electrical conductivity behavior in an air and N2 atmosphere. However, SBCTO showed insulator behavior at temperatures above 600℃ in a H2 atmosphere. Therefore, SBCTO may only be used as cathode materials. Moreover, SBCTO had an area specific resistance (ASR) value of 0.140 Ω·cm2 at 750℃.

Automated 2D/3D Image Matching Technique with Dual X-ray Images for Estimation of 3D In Vivo Knee Kinematics

  • Kim, Yoon-Hyuk;Phong, Le Dinh;Kim, Kyung-Soo;Kim, Tae-Seong
    • Journal of Biomedical Engineering Research
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    • v.29 no.6
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    • pp.431-435
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    • 2008
  • Quantitative information of a three dimensional(3D) kinematics of joint is very useful in knee joint surgery, understanding how knee kinematics related to joint injury, impairment, surgical treatment, and rehabilitation. In this paper, an automated 2D/3D image matching technique was developed to estimate the 3D in vivo knee kinematics using dual X-ray images. First, a 3D geometric model of the knee was reconstructed from CT scan data. The 3D in vivo position and orientation of femoral and tibial components of the knee joint could be estimated by minimizing the pixel by pixel difference between the projection images from the developed 3D model and the given X-ray images. The accuracy of the developed technique was validated by an experiment with a cubic phantom. The present 2D/3D image matching technique for the estimation of in vivo joint kinematics could be useful for pre-operative planning as well as post-operative evaluation of knee surgery.

REMARKS ON NONSPECIAL LINE BUNDLES ON GENERAL κ-GONAL CURVES

  • CHOI, YOUNGOOK;KIM, SEONJA
    • Journal of the Korean Mathematical Society
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    • v.52 no.5
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    • pp.991-1001
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    • 2015
  • In this work we obtain conditions for nonspecial line bundles on general ${\kappa}$-gonal curves failing to be normally generated. Let L be a nonspecial very ample line bundle on a general ${\kappa}$-gonal curve X with ${\kappa}{\geq}4$ and $deg\mathcal{L}{\geq}{\frac{3}{2}}g+{\frac{g-2}{{\kappa}}}+1$. If L fails to be normally generated, then L is isomorphic to $\mathcal{K}_X-(ng^1_{\kappa}+B)+R$ for some $n{\geq}1$, B and R satisfying (1) $h^0(R)=h^0(B)=1$, (2) $n+3{\leq}degR{\leq}2n+2$, (3) $deg(R{\cap}F){\leq}1$ for any $F{\in}g^1_k $. Its converse also holds under some additional restrictions. As a corollary, a very ample line bundle $\mathcal{L}{\simeq}\mathcal{K}_X-g^0_d+{\xi}^0_e$ is normally generated if $g^0_d{\in}X^{(d)}$ and ${\xi}^0_e{\in}X^{(e)}$ satisfy $d{\leq}{\frac{g}{2}}-{\frac{g-2}{\kappa}}-3$, supp$(g^0_d{\cap}{\xi}^0_e)={\phi}$ and deg$(g^0_d{\cap}F){\leq}{\kappa}-2$ for any $F{\in}g^1_k$.

Some Extensions of Rings with Noetherian Spectrum

  • Park, Min Ji;Lim, Jung Wook
    • Kyungpook Mathematical Journal
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    • v.61 no.3
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    • pp.487-494
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    • 2021
  • In this paper, we study rings with Noetherian spectrum, rings with locally Noetherian spectrum and rings with t-locally Noetherian spectrum in terms of the polynomial ring, the Serre's conjecture ring, the Nagata ring and the t-Nagata ring. In fact, we show that a commutative ring R with identity has Noetherian spectrum if and only if the Serre's conjecture ring R[X]U has Noetherian spectrum, if and only if the Nagata ring R[X]N has Noetherian spectrum. We also prove that an integral domain D has locally Noetherian spectrum if and only if the Nagata ring D[X]N has locally Noetherian spectrum. Finally, we show that an integral domain D has t-locally Noetherian spectrum if and only if the polynomial ring D[X] has t-locally Noetherian spectrum, if and only if the t-Nagata ring $D[X]_{N_v}$ has (t-)locally Noetherian spectrum.

STABILITY OF QUADRATIC FUNCTIONAL EQUATIONS IN RANDOM NORMED SPACES

  • Schin, Seung Won;Ki, DoHyeong;Chang, JaeWon;Kim, Min June;Park, Choonkil
    • Korean Journal of Mathematics
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    • v.18 no.4
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    • pp.395-407
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    • 2010
  • In this paper, we prove the generalized Hyers-Ulam stability of the following quadratic functional equations $$cf\(\sum_{i=1}^{n}x_i\)+\sum_{j=2}^{n}f\(\sum_{i=1}^{n}x_i-(n+c-1)x_j\)\\=(n+c-1)\(f(x_1)+c\sum_{i=2}^{n}f(x_i)+\sum_{i<j,j=3}^{n}\(\sum_{i=2}^{n-1}f(x_i-x_j\)\),\\Q\(\sum_{i=1}^{n}d_ix_i\)+\sum_{1{\leq}i<j{\leq}n}d_id_jQ(x_i-x_j)=\(\sum_{i=1}^{n}d_i\)\(\sum_{i=1}^{n}d_iQ(x_i)\)$$ in random normed spaces.

Electronic Structures of half-metallic phase of ternary Fe_2TX (T = 3d transition metal and X = Al, Si) (절반금속 Fe_2TX 화합물의 전자구조 연구 (T = 3d 전이금속; X = Al, Si))

  • Park, Jin-Ho;Kwon, Se-Kyun;Byung ll Min
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.584-584
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    • 2000
  • Electronic structures of ordered Fe$_3X (X = Al, Si), and their derivative ternary alloys of Fe_2TX (T = 3d transition metal) have been investigated by using the linearized muffin-tin orbital (LMTO) band method. The role of the coupling between substituted transition metal and its neighbors is investigated by calculating the magnetic moments and local density of states (LDOS). It is shown that it is essential to include the coupling beyond nearest neighbors in obtaining the magnetic moment of Fe alloy. The preferential sites of T impurities in Fe_3X are determined from the total energy calculations. The derivative ternary alloys of Fe_2TX have characteristic electronic structures of semi-metal for Fe_2VAI and (nearly) half-metal for Fe_2TAI (T = Cr, Mn) and Fe_2TSi (T = V, Cr, Mn)

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