• Title/Summary/Keyword: X/E ratio

Search Result 390, Processing Time 0.024 seconds

Phase Separation Characteristics via Bunsen Reaction in Sulfur-Iodine Thermochemical Hydrogen Production Process (SI 열화학 수소 제조 공정에서 분젠 반응을 통한 상 분리 특성)

  • Lee, Kwang-Jin;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Journal of Hydrogen and New Energy
    • /
    • v.19 no.5
    • /
    • pp.386-393
    • /
    • 2008
  • The Sulfur-iodine(SI) thermochemical cycle is one of the most promising methods for massive hydrogen production. For the purpose of continuous operation of SI cycle, phase separation characteristics into two liquid phases ($H_2SO_4$-rich phase and $HI_x$-rich phase) were directly investigated via Bunsen reaction. The experiments for Bunsen reaction were carried out in the temperature range, from 298 to 333 K, and in the $I_2/H_2O$ molar ratio of $0.109{\sim}0.297$ under a continuous flow of $SO_2$ gas. As the results, solubility of $SO_2$, decreased with increasing the temperature, had considerable influence on the global composition in the Bunsen reaction system. The amounts of impurity in each phase(HI and $I_2$ in $H_2SO_4$-rich phase and $H_2SO_4$ in $HI_x$-rich phase) were decreased with increasing $H_2SO_4$ molar ratio and temperature. To control the amounts of impurity in $HI_x$-rich phase, temperature is a factor more important than $I_2/H2_O$ molar ratio. On the other hand, the affinity between $HI_x$ and $H_2O$ was increased with increasing $I_2/H2_O$molar ratio.

Assessment of compressibility behavior of organic soil improved by chemical grouting: An experimental and microstructural study

  • Ghareh, Soheil;Kazemian, Sina;Shahin, Mohamed
    • Geomechanics and Engineering
    • /
    • v.21 no.4
    • /
    • pp.337-348
    • /
    • 2020
  • Tropical organic soils having more than 65% of organic matters are named "peat". This soil type is extremely soft, unconsolidated, and possesses low shear strength and stiffness. Different conventional and industrial binders (e.g., lime or Portland cement) are used widely for stabilisation of organic soils. However, due to many factors affecting the behaviour of these soils (e.g., high moisture content, fewer mineral particles, and acidic media), the efficiency of the conventional binders is low and/or cost-intensive. This research investigates the impact of different constituents of cement-sodium silicate grout system on the compressibility behaviour of organic soil, including settlement and void ratio. A microstructure analysis is also carried out on treated organic soil using Scanning Electron Micrographs (SEM), Energy Dispersive X-ray spectrometer (EDX), and X-ray Diffraction (XRD). The results indicate that the settlement and void ratio of treated organic soils decrease gradually with the increase of cement and kaolinite contents, as well as sodium silicate until an optimum value of 2.5% of the wet soil weight. The microstructure analysis also demonstrates that with the increase of cement, kaolinite and sodium silicate, the void ratio and porosity of treated soil particles decrease, leading to an increase in the soil density by the hydration, pozzolanic, and polymerisation processes. This research contributes an extra useful knowledge to the stabilisation of organic soils and upgrading such problematic soils closer to the non-problematic soils for geotechnical applications such as deep mixing.

Effects of Deposition Parameters on the Bonding Structure and Optical Properties of rf Sputtered a-Si$_{1-x}$C$_{x}$: H films (RF 스퍼터링으로 증착된 a-Si$_{1-x}$C$_{x}$: H 박막의 결합구조와 광학적 성질에 미치는 증착변수의 영향)

  • 한승전;권혁상;이혁모
    • Journal of Surface Science and Engineering
    • /
    • v.25 no.5
    • /
    • pp.271-281
    • /
    • 1992
  • Amorphous hydrogenated silicon carbide(a-Si1-xCx : H) films have been prepared by the rf sputtering using a silicon target in a gas mixture of Argon and methane with varying methane gas flow rate(fCH) in the range of 1.5 to 3.5 sccm at constant Argon flow rate of 30sccm and rf power in the range of 3 to 6 W/$\textrm{cm}^2$. The effects of methane flow rate and rf power on the structure and optical properties of a-Si1-xCx : H films have been analysed by measuring both the IR absorption spectrum and the UV transmittance for the films. With increasing the methane flow rate, the optical band gap(Eg) of a-Si1-xCx : H films increases gradually from 1.6eV to the maximum value of 2.42eV at rf power of 4 W/$\textrm{cm}^2$, which is due to an increases in C/Si ratio in the films by an significant increase in the number of C-Hn bonds. As the rf power increases, the number of Si-C and Si-Hn bonds increases rapidly with simultaneous reduction in the number of C-Hn bonds, which is associated with an increase in both degree of methane decomposition and sputtering of silicon. The effects of rf power on the Eg of films are considerably influenced by the methane flow rate. At low methane flow rate, the Eg of films decreased from 2.3eV to 1.8eV with the rf power. On the other hand, at high methane flow rate, that of films increased slowly to 2.4eV.

  • PDF

A Comparative Study on the Evaluation of the Wear Resistance in Zr-xNb-xSn Alloys

  • Lee, Young-Ho;Kim, Hyung-Kyu;Jung, Youn-Ho
    • KSTLE International Journal
    • /
    • v.4 no.2
    • /
    • pp.47-51
    • /
    • 2003
  • Sliding wear tests have been carried out in room temperature air and water in order to compare the wear resistance of Zr-xNb-xSn alloys of various alloying elements (Nb and Sn). The main focus was to quantitatively compare the wear properties of the recently developed Zr-xNb-xSn alloys with the commercial ones using the evaluation parameters of the wear resistance with the consideration of the worn area. As a result, the recently developed alloys had a similar wear resistance compared with the commercial ones. The dominant factor governing the wear resistance was the protruded volume of the wear debris that was formed on the worn area in the air condition, but the accommodation of the plastic deformation on the contact area in water. In addition, the worn area size appeared to be very different depending on the tested alloys. To evaluate the wear resistance of each test specimen, the ratio of the wear volume or the protruded volume to the worn area ($D_e$ or $D_p$) is investigated and proposed as the evaluation parameters of the wear resistance.

Electrical properties of S$SrBi_{2x}Ta_2O_9$ thin films with Bi content (Bi 함량에 따른 $SrBi_{2x}Ta_2O_9$ 박막의 전기적 특성)

  • 연대중;권용욱;박주동;오태성
    • Journal of the Korean Vacuum Society
    • /
    • v.8 no.3A
    • /
    • pp.224-230
    • /
    • 1999
  • $SrBi_{2x}Ta_2O_9$ (SBT) thin films were prepared on platinized silicon substrates by MOD process, and their ferroelectric and leakage current characteristics were investigated. The grain size of the MOD derived SBT films increased with increasing the BI/Ta mole ration. Although the SBT films with x of 0.8~1.2 were composed of the equiaxed grains, the elongated grains were also observed for the SBT films with x of 1.4 and 1.6. The SBT film with x of 1.2 exhibited the optimum ferroelectric properties of 2PR : 9.79 $\muC/\textrm{cm}^2$ and Ec : 24.2kV/cm at applied voltage of 5V. The leakage current density of the SBT films increased with increasing the BI/Ta mole ratio. With post annealing process, 2Pr and $E_c$of the SBT film with x of 1.2 increases 11.3 $\muC/\textrm{cm}^2$ and 39.6kV/cm, respectively. decrement of the leakage current density by post annealing process increased remarkably with increasing the Bi/ta mole ratio, and the SBT film with x=1.6 exhibited the lowest leakage current density after post annealing process.

  • PDF

Lattice strain effects on superconductivity in $La_{2-x}Sr_{x}CuO_{4}$ single-crystalline films grown by IR-LPE technique

  • Tanaka, I.;Islam, A.T.M.N.;Wataudhi, S.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.13 no.4
    • /
    • pp.172-175
    • /
    • 2003
  • We have investigated effects of the lattice mismatch between the LPE films and the substrates. We have grown $La_{2-x}Sr_{x}CuO_{4}$(x=0.1 to 0.15) single crystalline films on single crystalline substrates having different lattice parameter ratio c/a e.g., $La_{2-x}Sr_{x}Cu_{1-y}Zn_{y}O_{4},\;La_{2-x}Ba_{x}CuO_{4},\; LaSrAlO_{4}\;and\;La_{2-x}Sr_{x}Cu_{1-y}Al_{y}O_{4}$ etc., using the IR-LPE technique. The superconducting properties of the grown films were found to vary significantly depending on the lattice mismatch with different substrates.

Theoretical Calculation and Experimental Verification of the Hf/Al Concentration Ratio in Nano-mixed $Hf_xAl_yO_z$ Films Prepared by Atomic Layer Deposition

  • Kil, Deok-Sin;Yeom, Seung-Jin;Hong, Kwon;Roh, Jae-Sung;Sohn, Hyun-Cheol;Kim, Jin-Woong;Park, Sung-Wook
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • v.5 no.2
    • /
    • pp.120-126
    • /
    • 2005
  • We have proposed a characteristic method to estimate real composition when multi component oxide films are deposited by ALD. Final atomic concentration ratio was theoretically calculated from the film densities and growth rates for $HfO_2$ and $Al_2O_3$ using ALD processed HfxAhOz mms.W e have transformed initial source feeding ratio during deposition to fins] atomic ratio in $Hf_xAl_yO_z$ films through thickness factors ($R_{HFO_2}$ ami $R_{Al_2O_3}$) ami concentration factor(C) defined in our experiments. Initial source feeding ratio could be transformed into the thickness ratio by each thickness factor. Final atomic ratio was calculated from thickness ratio by concentration factor. It has been successfully confirmed that the predicted atomic ratio was in good agreement with the actual measured value by ICP-MS analysis.

Dietary Requirement of True Digestible Phosphorus and Total Calcium for Growing Pigs

  • Ruan, Z.;Zhang, Y.-G.;Yin, Y.-L.;Li, T.-J.;Huang, R.-L.;Kim, S.W.;Wu, G.Y.;Deng, Z.Y.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.20 no.8
    • /
    • pp.1236-1242
    • /
    • 2007
  • Sixty healthy growing pigs ($Duroc{\times}Landrace{\times}Yorkshire$ with an average BW of 21.4 kg) were used to determine the true digestible phosphorus (TDP) requirement of growing pigs on the basis of growth performance and serum biochemical indices. Pigs were assigned randomly to one of five dietary treatments (12 pigs/diet), representing five levels of TDP (0.16%, 0.20%, 0.23%, 0.26% and 0.39%). There were three replications per treatment, with four pigs (2 barrows and 2 gilts) in each replication (2 pigs/pen) A randomized-block design was used, with pen as the experimental unit. Experimental diets were formulated to provide the 5 TDP levels with a total calcium (Ca) to TDP ratio of 2:1, and offered to pigs at 5% BW for 28 d. The total Ca contents of the five diets were 0.33, 0.38, 0.45, 0.51 and 0.79%, respectively. During the 28-d experimental period, the ADG of pigs was affected by dietary TDP levels as described by Equation 1: y = $-809,532x^4+788,079x^3-276,250x^2+42,114x-1$,759; ($R^2$ = 0.99; p<0.01; y = ADG, g/d; x = dietary TDP, %). The feed:gain ratio for pigs was affected by dietary TDP levels as described by Equation 2: y = $3,651.1x^4-3,480.4x^3+1,183.8x^2-172.5x+10.9$ ($R^2$ = 0.99; p<0.01; y = feed:gain ratio; x = dietary TDP, %). Total P concentrations in serum were affected by dietary TDP levels as described by Equation 3: y = $-3,311.7x^4+3,342.7x^3-1,224.6x^2+195.6x-8.7$ ($R^2$ = 0.99; p<0.01; y = total serum P concentration and x = dietary TDP, %). The highest ADG (782 g/d), the lowest feed:gain ratio (1.07), and the highest total serum P concentration (3.1 mmol/L) were obtained when dietary TDP level was 0.34%. Collectively, these results indicate that the optimal TDP requirement of growing pigs is 0.34% of the diet (e.g., 5.1 g/day for a 30-kg pig that consumed 1.5 kg feed daily) at a total Ca to TDP ratio of 2:1.

Evaluation on Bankruptcy Prediction Model of Hospital using the comparative Analysis of Financial Index (재무지표 비교 분석에 의한 병원도산예측모형 평가)

  • Kim, Jae-Myeong;Ahn, Young-Chang
    • Health Policy and Management
    • /
    • v.15 no.4
    • /
    • pp.81-109
    • /
    • 2005
  • According to many recent studies suggesting that cash flow analysis method tends to be more effective than traditional financial index analysis method to predict corporate bankruptcy, this study applies the cash flow analysis method to hospital business to identify the significant variables which can distinguish between superior hospitals and bankruptcy hospitals. The author analyzed recent 3 years, i.e. from the year of 2000 to the year of 2002, financial statements of 31 bankrupt hospitals In 2003, and the same number of superior hospitals through using Multiple Discriminant Analysis and Logit Analysis. The results are belows; First, the study releases that Logit Analysis is more likely to be effective than Multiple Discriminant Analysis. Second, this research also shows that traditional financial index analysis method is more superior compare to cash flow analysis method for hospital bankruptcy predict model. Finally, this study suggest that the significant variables, which can distinguish superior hospitals from bankrupt hospitals, are Operating/Current Liabilities$(Y_2)$, CFO/Equity$(Y_5)$ for cash flow analysis method and Net Worth to Total Assets Ratio$(X_1)$, Quick Ratio $(X_3)$, Return on Assets$(X_6)$, Growth Rate of Patient Revenues$(X_{16})$ for traditional financial index analysis method.

Evaluation of a Solar Flare Forecast Model with Cost/Loss Ratio

  • Park, Jongyeob;Moon, Yong-Jae;Lee, Kangjin;Lee, Jaejin
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.40 no.1
    • /
    • pp.84.2-84.2
    • /
    • 2015
  • There are probabilistic forecast models for solar flare occurrence, which can be evaluated by various skill scores (e.g. accuracy, critical success index, heidek skill score, true skill score). Since these skill scores assume that two types of forecast errors (i.e. false alarm and miss) are equal or constant, which does not take into account different situations of users, they may be unrealistic. In this study, we make an evaluation of a probabilistic flare forecast model (Lee et al. 2012) which use sunspot groups and its area changes as a proxy of flux emergence. We calculate daily solar flare probabilities from 1996 to 2014 using this model. Overall frequencies are 61.08% (C), 22.83% (M), and 5.44% (X). The maximum probabilities computed by the model are 99.9% (C), 89.39% (M), and 25.45% (X), respectively. The skill scores are computed through contingency tables as a function of forecast probability, which corresponds to the maximum skill score depending on flare class and type of a skill score. For the critical success index widely used, the probability threshold values for contingency tables are 25% (C), 20% (M), and 4% (X). We use a value score with cost/loss ratio, relative importance between the two types of forecast errors. We find that the forecast model has an effective range of cost/loss ratio for each class flare: 0.15-0.83(C), 0.11-0.51(M), and 0.04-0.17(X), also depending on a lifetime of satellite. We expect that this study would provide a guideline to determine the probability threshold for space weather forecast.

  • PDF