• Title/Summary/Keyword: Working Partial Pressure

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Effects of Deposition Conditions on the Properties of Amorphous Carbon Nitride Thin Films by PECVD (PECVD로 제조된 비정질 질화탄소 박막의 특성에 미치는 증착변수의 영향)

  • Moon, Hyung-Mo;Kim, Sang-Sub
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.150-154
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    • 2003
  • Amorphous carbon nitride films were deposited on Si(001) substrates by a plasma enhanced chemical vapor deposition technique (PECVD) using $CH_4$and $N_2$as reaction gases. The growth and film properties were investigated while the gas ratio and the working pressure were changed systematically. At 1 Torr working pressure, an increase in the $N_2$partial pressure results in a significant increase of the deposition rate as well as an apparent presence of C ≡N bonding, while little affecting the microstructure and amorphus nature of the films. In the case of changing the working pressure at a fixed $N_2$partial pressure of 98%, a film grown at a medium pressure of $1${\times}$10^{-2}$ Torr shows the most prominent C=N bonding nature and photoluminescent property.

Working partial pressure of $CO_2$ gas in aqueous solution

  • Kim Dong-Su
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.47-52
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    • 2005
  • Carbonate species in aqueous solution play an important role in the determination of chemical properties of water in relation with alkalinity, buffer capacity, biological productivity, and so on. These compounds also have reactive characteristics such as interphasal reactions between solid, liquid, and gas phases. In the absence of solid materials, the total amount and relative abundance of each carbonate species are directly influenced by the partial pressure of $CO_2$ gas in the atmosphere, which in turn significantly affects the properties of aquatic system. In the water/wastewater treatment process along with the wastes treatment and recycling process which occurring in aquatic environment, it is essential to figure out its characteristics for their optimization and one of its most influential features upon these processes is determined by carbonate species. To understand the fundamental aspect of the relationship between the partial pressure of $CO_2$ gas and chemical features of water, especially pH, the working partial pressure of pure $CO_2$ gas that produced by contacting the dry ice with water has been estimated based on equilibrium calculation. The equilibrium constants for the dissociation ot carbonic acid were determined using van't Hoff equation and the distribution diagram of carbonate species according to the pH has been constructed to substantiate the results of equilibrium calculation. The estimated working partial pressure of pure $CO_2$ gas was found to be a function of the concentration of carbonates in solution, which suggesting that Prior evaluation of the working partial pressure of gas is essential for a better understanding of aquatic interactions.

Study on Regenerative Rankine Cycle with Partial-Boiling Flow Using Ammonia-Water Mixture as Working Fluid (암모니아-물 작동유체의 부분증발유동을 적용한 재생 랭킨사이클에 관한 연구)

  • Kim, Kyoung-Hoon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.3
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    • pp.223-230
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    • 2011
  • The power cycle using ammonia-water mixture as a working fluid is a possible way to improve efficiency of the system of low-temperature source. In this work thermodynamic performance of the ammonia-water regenerative Rankine cycle with partial-boiling flow is analyzed for purpose of extracting maximum power from the source. Effects of the system parameters such as mass fraction of ammonia, turbine inlet pressure or ratio of partial-boiling flow on the system are parametrically investigated. Results show that the power output increases with the mass fraction of ammonia but has a maximum value with respect to the turbine inlet pressure, and is able to reach 22 kW per unit mass flow rate of source air at $180^{\circ}C$.

Microstructures of Anatase TiO$_2$ Thin Films by Reactive Sputtering (반응성 스퍼터링법으로 제조된 anatase TiO$_2$박막의 미세조직에 관한 연구)

  • Choe, Yong-Rak;Kim, Seon-Hwa;Lee, Geon-Hwan
    • Korean Journal of Materials Research
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    • v.11 no.9
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    • pp.751-758
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    • 2001
  • Anatase $TiO_2$ thin films as a photocatalyst were prepared by the D.C reactive magnetron sputtering process. The $TiO_2$ thin films were deposited on Si(100) substrates under the various conditions : oxygen partial pressure, working pressure, substrate temperature, D.C power, and deposition time. The morphology of the TiO$_2$ thin films showed an island structure. At early stages of film growth, amorphous phase formed. However, during the further growth, columnar crystalline $TiO_2$grains evolved. The crystallinity of the thin films depended on the oxygen partial pressure, the working pressure and the D.C. powers.

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Characteristics of Large Area ITO/PET Fabricated by Vacuum Web Coater (진공 웹코터로 제작된 대면적 ITO/PET의 특성 연구)

  • Kim, Ji-Hwan;Park, Dong-Hee;Kim, Jong-Bin;Byun, Dong-Jin;Choi, Won-Kook
    • Korean Journal of Materials Research
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    • v.17 no.10
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    • pp.516-520
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    • 2007
  • Indium tin oxide, which is used as transparent conducting layer in flexible device, is deposited on PET film by a magnetron sputtering in 300 mm wide roll-to-roll process (vacuum web coating). Sheet resistance, specific resistance and transmittance is differed by sputtering parameters such as working pressures, oxygen partial pressure, and thickness of ITO layer. ITO layer is deposited about 90 nm at roll speed of 0.24 m/min and its sputtering power is 3 kW. From the XRD spectrum deposited ITO layer is verified as amorphous. Under working pressure varied from $3{\times}10^{-4}\;Torr$ to $2{\times}10^{-3}\;Torr$, sheet resistance is lowest at the working pressure of $1{\times}10^{-3}\;Torr$ and its value is from $110\;{\Omega}/{\square}$ to $260\;{\Omega}/{\square}$ at the thickness of 90 nm. Oxygen partial pressure also varies sheet resistance and is optimized at the regime from 0.2% ($1.8{\times}10^{-6}\;Torr$) to 0.6% ($6{\times}10^{-6}\;Torr$). In this oxygen partial pressure sheet resistance is lower than $150\;{\Omega}/{\square}$. As ITO layer thickness increases, sheet resistance decreases down to $21\;{\Omega}/{\square}$ and specific resistance is about $7.5{\times}10.4{\Omega}cm$ in 340 nm thickness ITO layer. Transmittance is measured at the wavelength of 550 nm and is about 90% for 180 nm thickness ITO/PET.

Design of partial emission type liquid nitrogen pump

  • Lee, Jinwoo;Kwon, Yonghyun;Lee, Changhyeong;Choi, Jungdong;Kim, Seokho
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.1
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    • pp.64-68
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    • 2016
  • High Temperature Superconductor power cable systems are being developed actively to solve the problem of increasing power demand. With increases in the unit length of the High Temperature Superconductor power cable, it is necessary to develop highly efficient and reliable cryogenic pumps to transport the coolant over long distances. Generally, to obtain a high degree of efficiency, the cryogenic pump requires a high pressure rise with a low flow rate, and a partial emission type pump is appropriate considering its low specific speed, which is different from the conventional centrifugal type, full emission type. This paper describes the design of a partial emission pump to circulate subcooled liquid nitrogen. It consists of an impeller, a circular case and a diffuser. The conventional pump and the partial emission pump have different features in the impeller and the discharge flow passage. The partial emission pump uses an impeller with straight radial blades. The emission of working fluid does not occur continuously from all of the impeller channels, and the diffuser allows the flow only from a part of the impeller channels. As the area of the diffuser increases gradually, it converts the dynamic pressure into static pressure while minimizing the loss of total pressure. We used the known numerical method for the optimum design process and made a CFD analysis to verify the theoretical performance.

Optimal Sputtering Parameters of Transparent Conducting ITO Films Deposited on PET SUbstates

  • Kim, Hyun-Hoo;Shin, Sung-ho
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.2
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    • pp.23-27
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    • 2000
  • Indium in oxide(ITO) films have been deposited on PET and glass substrates by DC reactive magnetron sputtering without post-deposition thermal treatment, The high quality for microstructure, electrical and optical properties of the as-deposited ITO films on unheated substrates is dominated by the sputtering parameters, The influence of the working gas pressure, DC power and oxygen partial pressure has been systematically investigated, The lowest DC power, and oxygen partial pressure has been systematically investigated, The lowest resistivity of ITO films deposited on PET substrates was 6$\times$10$^{-4}$ $\Omega$cm. It has been obtained at a working pressure of 3 mTorr and DC power of 30 W. The sheet resistance and optical transmittance of these film were 22 $\Omega$/square and 84% respectively. The best values of figures of merit for the electrical and optical characteristics such as T/ $R_{sh}$ and $T^{10}$ / $R_{sh}$ are approximately 38.1 and 7.95($\times$10$^{-3}$ $\Omega$$^{-1}$ ), respectively.

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A Study on the Organic Rankine Cycle Using R245fa (냉매(R245fa)를 이용한 유기랭킨 사이클에 관한 연구)

  • Cho, Soo-Yong;Cho, Chong-Hyun;Kim, Jinhan
    • The KSFM Journal of Fluid Machinery
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    • v.16 no.3
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    • pp.10-17
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    • 2013
  • The organic Rankine cycle has been widely used to convert the renewable energy such as the solar energy, the geothermal energy, or the waste energy etc., to the electric power. Some previous studies focused to find what kind of refrigerant would be a best working fluid for the organic Rankine cycle. In this study, R245fa was chosen to the working fluid, and the cycle analysis was conducted for the output power of 30kW or less. In addition, properties (temperature, pressure, entropy, and enthalpy etc.) of the working fluid on the cycle were predicted when the turbine output power was controlled by adjusting the mass flowrate. The configuration of the turbine was a radial-type and the supersonic nozzles were applied as the stator. So, the turbine was operated in partial admission. The turbine efficiency and the optimum velocity ratio were considered in the cycle analysis for the low partial admission rate. The computed results show that the system efficiency is affected by the partial admission rate more than the temperature of the evaporator.

Influences of Oxygen Partial Pressure and Annealing Time on Microstructure and Magnetic Properties of Hexagonal Barium-Ferrite Thin Films (Hexagonal Barium-Ferrite 박막의 미세구조와 자기적 특성에 미치는 산소분압과 열처리 시간의 영향)

  • 김웅수;김동현;남인탁;홍양기
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.285-290
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    • 2000
  • BaM thin films were prepared by using RF magnetron sputtering system at room temperature, and then successively annealed to crystallize at 850$\^{C}$ using RTA. The structure and magnetic properties of post-annealed BaM films have been investigated using XRD and VSM, respectively. The dependences of partial oxygen gas pressure (Po2) on the characteristics of BaM films were investigated. Although mixing of spinel and BaM phase only was identified in 0.5 mTorr oxygen partial pressure, BaM phase only was identified in the range from 1 to 3 mTorr oxygen partial pressure. The saturation magnetization and perpendicular coercivity of BaM thin films decreases with increase of Po2 in the range of Pot between 0.5 and 3 mTorr.

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Transparent cryogenic thermosiphon using $N_2\;and\;CF_4$ mixture as the working fluid

  • Lee, Ji-Sung;Jeong, Sang-Kwon;Ko, Jun-Seok;Kim, Young-Kwon;Jung, Se-Yong;Han, Young-Hee
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.2
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    • pp.37-40
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    • 2009
  • A mixed working fluid has a potential to widen the operation temperature range of the thermosiphon. In this study, the thermosiphon using $N_2\;and\;CF_4$ mixture as the working fluid is fabricated and tested to verify its transient thermo hydraulic characteristic. A transparent pyrex glass tube was used for the thermosiphon itself and the vacuum chamber was also fabricated by glass to visualize the internal state of thermo siphon. Onset of condensation temperature was related to the partial pressure of $CF_4$. Two solidifications were observed and condensate temperature range of mixed working fluid was from 160K to 70.7K with $N_2$ 25% composition.