• Journal of the Korean Wood Science and Technology
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• 제22권2호
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• pp.54-60
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• 1994

The pine bark from mechanical pulp industry was cooked with bisulfite liquor, and the chemical and physical properties of the spent liquor after cooking for 90 minutes, which allowed partial defibration were determined. Lignosulfonate or lignin-related materials in the spent liquor have a molecular weight of approximately 3,000, which is lower than that of commercial lignosulfonate (C-LS) prepared from wood. The sulfonic equivalent weight calculated by colloid titration was 307 for C-LS, 238~239 for spent liquor. The contents of lignosulfonic acid and phenolic hydroxyl groups on $C_9$ unit of lignin in the spent liquor were 0.98~0.99, and 1.51~1.66, respectively. These values were remarkably higher than those of C-LS. Especially the content of phenolic hydroxyl group was almost twice that of C-LS. The viscosity of spent liquor after freeze drying was very low compared to C-LS. The dispersing ability of spent liquor was almost equivalent to or more than that of C-LS.

• Journal of the Korean Wood Science and Technology
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• 제47권1호
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• pp.101-109
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• 2019

This paper examines the classification of five coniferous species, including larch (Larix kaempferi), red pine (Pinus densiflora), Korean pine (Pinus koraiensis), cedar (Cryptomeria japonica), and cypress (Chamaecyparis obtusa), using near-infrared (NIR) spectra. Fifty lumber samples were collected for each species. After air-drying the lumber, the NIR spectra (wavelength = 780-2500 nm) were acquired on the wide face of the lumber samples. Soft independent modeling of class analogy (SIMCA) was performed to classify the five species using their NIR spectra. Three types of spectra (raw, standard normal variated, and Savitzky-Golay $2^{nd}$ derivative) were used to compare the classification reliability of the SIMCA models. The SIMCA model based on Savitzky-Golay $2^{nd}$ derivatives preprocessing was determined as the best classification model in this study. The accuracy, minimum precision, and minimum recall of the best model (PCA models using Savitzky-Golay $2^{nd}$ derivative preprocessed spectra) were evaluated as 73.00%, 98.54% (Korean pine), and 67.50% (Korean pine), respectively.

• Journal of the Korean Wood Science and Technology
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• 제50권1호
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• pp.68-80
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• 2022

Timber boardwalk decks are widely installed in parks and scenic areas to provide pedestrians an elevated footpath as well as harmony with the surrounding natural scene. In order to extend the lifespan of boardwalks in the outdoor environment, industrially treated pine timber, such as Pinus sylvestris, is often adopted. However, accidents of pedestrians injured by damaged boardwalk decks have been constantly reported. Therefore, the mechanical behavior of two different types of treated timber was examined in this study under repeated wetting and drying. An increasing number of radial cracks appeared with increasing length and width as more cycles were performed. A loss of more than 40% of the screw withdrawal capacity was observed in both end grain and face grain for the two types of timber after twelve accelerated wet-dry cycles, which coincides with the observation of damaged timber boardwalks in the field investigation. At the same time, it was found that both the compressive and the flexural strength was not sensitive to the wet-dry cycles especially at large cycle numbers.

• Journal of the Korean Wood Science and Technology
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• 제36권6호
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• pp.88-95
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• 2008

내구성과 관련하여 구조부재의 수축문제가 목구조에서는 커다란 관심사가 되고 있다. 특히, 목재 소재를 적극 활용하는 전통공법에서는 짜맞춤 부위, 부재와 벽 등에서 발생하는 건조수축에 의한 갈라짐 등의 결함이 더욱 문제시되고 있다. 또한, 최근 기둥-보 공법에서 많이 사용되고 있는 국내산 낙엽송 집성재의 이용에 있어서도 함수율변화로 인한 수축과 팽윤에 대한 검토를 행할 필요성이 제기되고 있다. 낙엽송 소재와 접착층수를 달리한 낙엽송 집성재의 시험편에 대해 다양한 함수율상태에서의 치수변화율을 살펴보았다. 건조수축에 의한 치수변화 억제효과는 3층 이상의 접착층을 가지는 시험편에서 그 효과가 현저함을 알 수 있었다. 그리하여, 소재를 사용할 경우 최종사용조건에 맞추어 건조를 충분히 행하거나, 구조부재로 집성재를 이용함으로써 건조수축 문제를 어느 정도 해결할 수 있는 것으로 판명되었다.

• Journal of the Korean Wood Science and Technology
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• 제42권6호
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• pp.653-658
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• 2014

본 연구는 지역 및 계절 변화에 따른 목재의 평형함수율을 조사하기 위해 수행되었다. 국내 73개 장소에서 30년(1981~2010) 동안 축적된 기상자료와 Hailwood-Horrobin 방정식을 이용하여 목재평형함수율을 계산하였으며 계산된 목재평형함수율의 변화 추이를 조사하였다. 평년값(30년 평균값)을 사용하여 계산된 목재평형함수율은 대구가 11.5로 가장 낮았으며 흑산도가 15.8로 가장 높은 것으로 나타났다. 계절별로 살펴보았을 때 여름(6월, 7월, 8월)이 15.3으로 가장 높았으며 가을(9월, 10월, 11월) 13.7, 겨울(12월, 1월, 2월) 12.2, 봄(2월, 3월, 4월) 12.0의 순서로 평형함수율이 낮은 것을 알 수 있었다. 월별 목재평형함수율은 4월이 11.6으로 가장 낮았으며 7월이 16.1로 가장 높은 것으로 나타났다. 지역에 따른 월별 평형함수율의 편차는 제주가 3.0으로 가장 작았으며 흑산도가 8.7로 가장 큰 값을 보여주었다. 목재의 평형함수율은 목재의 수축 및 팽윤과 관련이 있다는 것을 고려할 때 월별 평형함수율의 편차가 큰 지역에서는 평균평형함수율을 고려하여 목재의 건조를 실시해야 할 것으로 보인다.

• 대한화학회지
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• 제5권1호
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• pp.7-8
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• 1961

In this study we found following fact. The properties of seed oil of Firmiana platonifola, Schott, et Endl. is quite different from that of china wood(Chinese Tung) oil. It belongs to the non-drying oil and chiefly consists of linoleo-dioleoglyceride and palmito-dioleoglyceride.

• 한국문화재보존과학회:학술대회논문집
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• 한국문화재보존과학회 2004년도 제20회 발표논문집
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• pp.115-130
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• 2004

Plant-based cultural assets using straw and grass as household goods of our people's have been used as indispensable tools for practical living for a very long time. However, only a limited number of artifacts were unearthed so far due to tile fragility of the material. For this reason, research on plant-based cultural properties had close to no progress, and the appropriateness of the PEG method, high-grade alcohol method, alcohol--ether-resin method, and Paraloid B-72 used in preserving plant-based cultural properties has not been sufficiently investigated. Therefore, this study examined the weight change rate by applying the methods of Primal MC-76 and vacuum freeze-drying used mostly as a earth-layer hardening material among PEG and acrylic resin, which are applied widely for preservation of waterlogged archaeological wood, as a means to preserve plant-based cultural properties along with the examination of the subject material, and an experiment was also performed on moisture absorption. The findings as a result were, first, the plant-based material being studied was found to be Typha (Typha orientalis Presl). Secondly, the weight change experiment applying $PEG\#400$ and $PEG\#4000$ confirmed a steady increase of weight if PEG -2Step is used for treatment. Third, in preserving all subject materials with soil, treatment with $PEG\#4000$, Primal MC-76, and vacuum freeze-drying showed that tile vacuum freeze-drying method resulted in the largest or $20\%$ reduction in weight, while Primal MC-76 resulted in $18\%$ and $PEG\#4000$ in $8\%$ of weight reduction. It was concluded that, considering the stability of soil measurement, this came to be because resin permeation was carried out along with tile drying process. Fourth, the weight changes were found to be around $10\%$ in various humidity conditions after the preservation treatment. The greatest weight change rate was seen in the case of $PEG\#4000$, particularly having chemicals gush out in a high humidity (RH $84\%$ or higher) environment. In the case of Primal MC-76 and vacuum freeze-drying methods, $6\~8\%$ weight changes were detected, and the lowest weight change was found in the case of the vacuum freeze-drying method. Fifth, as for color changes after treatment, blackening occurred most strongly with $PEG\#4000$, while Primal MC-76 and vacuum freeze-drying manifested colors closest to dry straw or grass. However, the texture of straw was not very evident in the case of Primal MC-76, due to a glossy surface, but vacuum freeze-drying was found to offer tile best result in terms of texture. Putting together the results of the above experiments, vacuum freeze-drying presented after being treated with PEG2-Step the most stabilized changes in weight, while it offered the smallest change in color as well.

• Journal of the Korean Wood Science and Technology
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• 제38권6호
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• pp.526-531
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• 2010

목재의 합리적인 이용을 위하여 목재 가공 또는 이용시 수분제어를 통한 건조결함 발생 최소화가 중요하다. 근적외선 분광분석법을 이용하여 재료의 물리적 화학적 성질을 신속하고 비파괴적으로 파악할 수 있다. 본 연구 에서는 근적외선 분광분석법을 이용하여 목재의 표면함수율을 측정하였다. 근적외선 분광스펙트럼에는 목재의 화학적 성분의 영향으로 인하여 노이즈가 포함될 수 있기 때문에 평활화, 미분, 표준화를 포함한 수학적 전처리를 적용한 후 회귀분석을 실시하였다. 750~2,500 nm 범위의 적외선 흡광도를 이용한 회귀모델을 통하여 목재의 표면함수율 측정이 가능함을 확인하였다. 본 연구에서 개발된 근적외선 분광분석법을 통하여 비평형상태에서 목재 수분을 정확히 탐지함으로써 건조 또는 수분흡습 중 목재 내 수분이동량을 제어할 수 있는 기술이 발전될 수 있으리라 기대된다.

• 펄프종이기술
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• 제47권4호
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• pp.96-101
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• 2015

In the previous study, we investigated the physical properties of new organic fillers made from major agricultural byproducts, including rice husks, peanut husks and garlic stems, and we estimated that rice husk was the best candidate for use as new organic fillers in paperboard. In this study, an organic filler prototype was produced with rice husk and the mill trials were carried out in a white liner chipboard (duplexboard) mill. The rice husk organic filler was added to the middle ply of SC $350g/m^2$ to determine the optimal conditions for the manufacture of rice husk organic fillers. The mill trials were performed three times and the bulk improvement and drying energy reduction were measured to identify the functionality of the rice husk organic filler compared to that of the commercial wood powder. In the first mill trial, the test failed because the surface roughness of the duplexboard had deteriorated after the rice husk organic filler was added to the OCC stock. As all of the particles remaining on the 60 mesh sieves were removed and the particle size was decreased by increasing the length of the grinding process, the surface roughness of the duplexboard did not be deteriorated in the second mill trial. However, the bulk improvement and drying energy reduction were not observed. In the final mill trial, as the particle size of the rice husk organic filler was controlled by increasing the portion of particles passing through the 60 mesh sieves and remaining 100 mesh sieves, higher bulk improvement and drying energy reduction were acquired compared to the commercial wood powder.

• 한국산학기술학회논문지
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• 제18권2호
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• pp.294-301
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• 2017

본 연구에서는 유중건조 공정으로 가축분뇨 슬러지 고형 연료를 제조하기 위한 최적 조건을 선정하는 연구를 수행하였다. 연구결과물(슬러지 고형 연료)의 특성 평가를 위하여 유증 증발량 측정 실험, 슬러지 유중건조 실험, 그리고 건조 슬러지 성형 실험을 수행하였으며, 칼로리미터와 PXRF 장비를 이용하여 고형 연료의 성능을 측정하였다. 또한, 현재 시중에서 일반적으로 사용되고 있는 목재 고형 연료와 본 연구에서 개발한 슬러지 고형 연료 사이의 열량 비교 연구를 수행하였다. 실험결과에 따르면 대량생산 및 환경 친화적 측면을 함께 고려하였을 때, 30g의 슬러지를 $130^{\circ}C$의 식물성 기름으로 25분간 처리하는 것이 고형연료 생산에 가장 적합한 조건으로 나타났다. 본 연구에서 제조한 슬러지 고형 연료의 열량은 5211kcal/kg이었으며, 이는 시중에서 널리 사용되고 있는 목재 고형 연료의 열량보다 큰 값이다. 마지막으로, PXRF 측정 결과 황을 제외한 중금속은 검출되지 않았다. 그러므로 추후 산업용 제조기술로의 개발 시 황 성분 제어 공정에 대한 추가적인 연구가 필요할 것으로 보인다.