• Journal of the Korean Wood Science and Technology
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• v.22 no.2
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• pp.30-36
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• 1994

Steam explosion process is one of the most efficient, pretreatment method for the utilization of lignocellulosic biomass. The carbxymethyl-cellulose(CMC) was prepared with steam exploded wood(EXW), pine(Pinus densiflora) and oak(Quercus mongolica), by standard method using isopropyl alcohol and monochloroacetic acid. The range of water solubility of carboxymethylated pine exploded wood was 45.2~66.8 % and those of oak was 60.7~84.7 %. The degree of substitution(D.S) of carboxymethylated pine exploded wood was 0.11~0.33 and oak exploded wood was 0.48~0.76. The color of carboxymethylated pine and oak exploded wood was brown-black. When carboxymethylated EXW was purified by sulfuric acid, the yield of carboxymethylated wood was lower than non-treated one. However, the color was still brown-black although after delignification. In carboxymethylated EXM prepared after delignification, the water solubility and degree of substitution(D.S) of pine were 81.4~95.9 % and 0.71~0.79, and those of oak were 76.2~89.5 % and 0.79~1.05. The values were higher than non-treated. The degree of substitution of purified carboxymethylated wood prepared with delignified EXM, pine and oak were 0.50~0.71 and 0.70~0.88. The color of carboxymethylated wood was white. In carboxymethylated wood preparde after delignification of EXM, swelling ratio and water retention value of pine were 95.9~96.5 and 580.0~751.2, those of oak were 76.2~89.5 and 124.3~307.6.

• Journal of the Korean Wood Science and Technology
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• v.39 no.2
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• pp.187-195
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• 2011

In this study, dilute acid pretreatment of $Liriodendron$ $tulipifera$ was performed for enzymatic hydrolysis. As the pretreatment temperature was increased, enzymatic hydrolysis and enzyme adsorption yield also increased. The highest enzymatic hydrolysis yield was 57% (g/g) and enzyme adsorption was 44% (g/g). Enzymatic hydrolysis yield was determined with weight loss of pretreated biomass by enzyme, and enzyme adsorption was a percentage of enzyme weight attaching on pretreated biomass compared with input enzyme weight. When $L.$ $tulipifera$ was pretreated with 1% sulfuric acid at $160^{\circ}C$ for 5 min., hemicellulose was significantly removed in pretreatment, but the lignin contents were constant. Other changes in surface morphology were detected on biomass pretreated at $160^{\circ}C$ by a field emission scanning electron microscope (FESEM). A large number of spherical shapes known as lignin droplets were observed over the entire biomass surface after pretreatment. Hemicellulose removal and morphological changes improved enzyme accessibility to cellulose by increasing cellulose exposure to enzyme. It is thus evidence that enzyme adsorption is a significant factor to understand pretreatment effectiveness.

• Applied Chemistry for Engineering
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• v.23 no.5
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• pp.456-461
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• 2012

To verify the utilization of biomass as energy, the combustion characteristic has been studied by an experimental combustion furnace under an isothermal and non-isothermal combustion. The wood pellet, rice straw and rice husk were used as biomass samples in this work. The characteristics of emission gases, dusts and residues from biomass combustion have been analyzed and compared with those of reuse derived fuel (RDF). From isothermal combustion experiments, it was found that the incomplete combustion of rice straw was greater that that of rice husk, wood pellet and RDF. This is due to the fact that the combustion reaction rate of the rice straw was faster than that of other samples, and the oxygen concentration in rice straw combustion was rapidly decreasing. It was also found that $NO_{X}$ concentration of emission gas from wood pellet combustion was the lowest. From non-isothermal combustion experiments, it was found that all samples were burned before $900^{\circ}C$. Also, the temperature range of $NO_{X}$ emission was similar to that of CO emission, on the other hand, $SO_{2}$ was emitted at a higher temperature than that of CO emission.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.372-377
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• 2019

Leaching ($60^{\circ}C$, 5 min) and wet torrefaction ($200^{\circ}C$, 5 min) of empty fruit bunch (EFB) were carried out to improve the fuel properties; each liquid fraction was reused for leaching and wet torrefaction, respectively. In the leaching process, potassium was effectively removed because the leaching solution contained 707.5 ppm potassium. Inorganic compounds were accumulated in the leaching solution by increasing the reuse cycle of leaching solution. The major component of the leached biomass did not differ significantly from the raw material (p-value < 0.05). Inorganic compounds in the biomass were more effectively removed by sequential leaching and wet torrefaction (61.1%) than by only the leaching process (50.1%) at the beginning of the liquid fraction reuse. In the sequential leaching and wet torrefaction, the main hydrolysate component was xylose (2.36~4.17 g/L). This implied that hemicellulose was degraded during wet torrefaction. As in the leaching process, potassium was effectively removed and the concentration was accumulated by increasing the reuse cycle of wet torrefaction hydrolysates. There was no significant change in the chemical composition of wet torrefied biomass, which implied that fuel properties of biomass were constantly maintained by the reuse (four times) of the liquid fraction generated from leaching and wet torrefaction.

• Korean Journal of Agricultural Science
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• v.49 no.2
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• pp.317-330
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• 2022

Recently, the policy regarding climate change in Korea and overseas has been to promote the utilization of forest biomass to achieve net zero emissions. In addition, with the implementation of the unused forest biomass system in 2018, the size of the Korean market for manufacturing wood pellets and wood chips using unused forest biomass is rapidly expanding. Therefore, it is necessary to estimate the total amount of unused forest biomass that can be used as an energy source and to identify the capacity that can be continuously produced annually. In this study, we estimated the actual forest area that can be produced of logging residue and the potential amount of unused forest biomass resources based on GT (green ton). Using a forest functions classification map (1 : 25,000), 5th digital forest type map (1 : 25,000), and digital elevation model (DEM), the forest area with a slope of 30° or less and mountain ridges of 70% or less was estimated based on production forest and IV age class or more. The total forest area where unused forest biomass can be produced was estimated to be 1,453,047 ha. Based on GT, the total amount of unused forest biomass potential resources in Korea was estimated to be 117,741,436 tons. By forest type, coniferous forests were estimated to be 48,513,580 tons (41.2%), broad-leaved forests 27,419,391 tons (23.3%), and mixed forests 41,808,465 tons (35.5%). Data from this research analysis can be used as basic data to estimate commercial use of unused forest biomass.

• Korean Journal of Agricultural Science
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• v.49 no.2
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• pp.357-366
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• 2022

Biochar can be obtained by using various types of biomass under an oxygen-limited condition. Biochar can be utilized for various applications such as soil improvement, waste management, growth promotion, and adsorption. Wood vinegar is produced by the process of pyrolysis wood biomass and is used as a growth promoter, for soil improvement, and as a feed additive. When wood vinegar is treated on soil, it acts to control soil pH, improve nutrient availability, and alleviate N₂O and NH₃ volatilization. The objective of this study was to evaluate the effect of biochar and wood vinegar on the growth of perilla and soil quality. The experiment was conducted by using a Wagner pot (1·5,000 a^-1) in a glass greenhouse. The biochar was produced by pyrolysis at 450℃ for 30 minutes using rice husk and rice straw. Wood vinegar was diluted to 1 : 500 (v·v^-1) and used in this experiement. In the results of a cultivation experiment, co-application of biochar and wood vinegar enhanced the growth of perilla. In particular, rice husk biochar affected the leaves of the perilla, and rice straw biochar influenced the stems of the perilla. In addition, soil quality after treatment with biochar and wood vinegar applied together was highest compared to other units. Therefore, it is anticipated that co-application of biochar and wood vinegar will be more productive and improve soil quality compared to individual utilization of biochar and wood vinegar.

• New & Renewable Energy
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• v.20 no.1
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• pp.145-174
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• 2024

Addressing climate change necessitates evidence-based policies grounded in science. The use of forest biomass for energy production is based on a broad scientific consensus at the international level. However, some environmental groups in South Korea are opposing this system of energy production. Through this study, the authors aim to reduce unnecessary confusion and foster an atmosphere conducive to meaningful evidence-based policies. We have classified the issue into eight categories: biological carbon cycle, carbon debt, nature-based solutions, air emissions, cascading principles and sustainability certification, forest environmental impacts, climate change litigation, and the behavior of environmental groups and public perception. Consequently, the following key points were derived: (1) the actions of some environmental groups seem to follow a similar pattern to denialist behavior that denies climate change and climate science; (2) the quality of evidence for campaigns that oppose the use of forest biomass for energy production is low, with a tendency to overgeneralize information, high uncertainty, and difficulty in finding new claims.; (3) most of the public believes that forest biomass energy is necessary, and the governments of major countries are aware of its importance. Significantly, Forest biomass for energy is based on an overwhelming level of scientific consensus recognized internationally.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.4
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• pp.51-58
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• 2008

Unit costs for energy production in bioenergy facilities are dependent upon both fixed cost for facility construction and operational costs including biomass feedstock supply. With the increase of capacity, unit fixed cost could be decreased while supply cost tends to increase due to the longer transportation distance. It is desirable to take into account biomass availability in planning bioenergy facilities. A cumulative curve relationship was proposed to relate biomass availability and cumulative products of biomass amount and transportation distance. Optimum size of gasification facilities was affected by collection cost, biomass cumulative relationship. Based on biomass availability of Icheon-City, optimum sizes were about $400kW_{th}$ for gas production, and about $200kW_{el}$ for power generation. Unit cost of bioenergy production could be substantially reduced by reducing collection cost through supplying biomass from diverse sources including land development areas where significant amount of waste wood is generated. When planning bioenergy facilities, however, biomass availability and spatial distribution are key factors in determining the size of capacity.

• Journal of the Korean Wood Science and Technology
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• v.35 no.1
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• pp.1-10
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• 2007

This study was reviewed on the bioethanol production from biomass resources and feedstock supply in America. U.S. Department of Energy (USDE) and the u.s. Department of Agriculture USDA) are both strongly committed to expand the role of biomass as an energy source. They support biomass fuels and products as a way to reduce the need for oil and gas imports, to strengthen the nation's energy security and environmental quality. And it was envisioned a 20 percent replacement of the current U.S.transportation fuel consumption in 2030. Also it was reviewed policies to encourage the expanding of Bio-based fuel use to replace gasoline, such as Clean Air Act, Federal Clean Fuel Program and American Jobs Creation Act. In feedstock supply it was assumed forest biomass will be supplied in 368 million dry tons yearly and the agriculture derived biomass adopted by new technologies and land use change will be supplied in 998 million dry tons, including highly 818 million dry tons of lignocellulosic biomass such as perenial crops (hybrid trees, grasses) corn stover, other crop residues. This amount is 5 times to the amount from based current agricultural technology and crop land.

• Journal of Korean Society of Forest Science
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• v.105 no.4
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• pp.463-471
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• 2016

The purpose of this study was to develop allometric equations for identifying the amount of wood and building biomass statistics of L. tulipifera by density, biomass expansion factors and root ratio. For this purpose, total of 40 trees were sampled, which were used consideration the area and the DBH class. As a results, the wood density was $0.43g{\cdot}cm^{-3}$, biomass expansion factors were 1.2, root ratio was 0.2 and uncertainty were 3.9%, 4.6%, 24.1%, respectively. Allometric equations for above ground of L. tulipifera trees were $W=0.060D^{2.524}$. Total and underground allometric equations were $W=0.063D^{2.578}$, $W=0.010D^{2.591}$, respectively.