• Title/Summary/Keyword: Wood Structure

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Preparation and Characterization of Cellulose Nanofibrils from Lignocellulose Using a Deep Eutectic Solvent Followed by Enzymatic Treatment

  • Eun-Ah ,LEE;Song-Yi, HAN;Gu-Joong, KWON;Jeong-Ki, KIM;Rajkumar, BANDI;Ramakrishna, DADIGALA;Ji-Soo, PARK;Chan-Woo, PARK;Seung-Hwan, LEE
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.6
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    • pp.436-447
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    • 2022
  • Lignocellulose nanofibrils (LCNFs) were prepared using a two-step deep eutectic solvent (DES) and enzymatic pretreatment followed by mechanical defibrillation, and we examined the effects of enzymatic pretreatment conditions on different characteristics of the LCNFs thus obtained. The LCNFs yielded using the two-step DES pretreatment (Enz-LCNF) exhibited a well-defibrillated entangled web-like structure with an average fiber diameter ranging from 15.7 to 20.4 nm. Furthermore, we found that the average diameter and filtration time of the Enz-LCNFs decreased with an increase in enzyme concentration and enzymatic treatment time, whereas we detected a concomitant reduction in the tensile strength of the Enz-LCNF sheets. The Enz-LCNFs were characterized by a typical cellulose I structure, thereby indicating that the enzymatic treatment causes very little damage to the crystalline form.

Historical Consideration of Lignin Models for Native Lignin Structure (리그닌 화학구조 모델의 역사적 고찰)

  • 황병호
    • Journal of Korea Foresty Energy
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    • v.23 no.1
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    • pp.45-68
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    • 2004
  • The word of lignin is derived from the Latin word 'ligum' meaning wood. Lignin is complex polymer consisting of coniferyl alcohol, sinapyl alcohol and p-coumaryl alcohol unit and has an amorphous, three dimensional network structure which is hard to be hydrolyzed by acid. Lignin is found in the cell wall of plants lignified. The mode of polymerization of these alcohols in the cell wall lead to a heterogeneous branched and cross-linked polymer in which phenyl propane units are linked by carbon-carbon and carbon-oxygen bonds. This polymerization of precursors, p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol to lignin is formed by enzymic dehydrolyzation. The reaction is initiated by an electron transfer which results in the formation of resonance-stabilized phenoxy radical. The combination of these radicals produces a variety of dimers, trimers and oligomers and so on. Lignin research has been divided into basic and practical application field. The basic studies contains biosynthesis, chemical structure, distribution in the cell wall and reactivity by reductants, oxidants and organic solvents. The application research will be approached the reaction of lignin in various pulp making involving pulp bleaching and its effect on pulp qualities. Lignin also will be studied for the production of fine chemicals, polymer products and the conservation into an energy source like petroleum oil because the amount of lignin produced in pulp making process is more than 51,000,000 tons per year in the world. Both basic and application research must lay emphasis on the development for the utilization of lignin and the pulping process. But these researches can not be completed without understanding lignin structure containing functional groups. Therefore, this paper was focused on the review of lignin formulation which has been studied since 1948 in chronological order. This review was based on monomers, dimers, trimers and tetramers of phenyl propane unit structures which were isolated and identified by different methods from various wood.ious wood.

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Thermal Resistance and Condensation in the Light-frame Timber Wall Structures with Various Composition of Insulation Layers

  • Jang, Sang Sik;Lee, Hyoung Woo
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.4
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    • pp.533-542
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    • 2019
  • As energy costs increase, more people has become interested on energy efficiency and savings in residential buildings. The two main subjects related to energy in residential buildings are insulation and condensation. There are two approaches to prevent condensation; increasing air tightness and maintaining the temperature inside of the wall structure over the dew point, which is in turn related to insulation. Even though the Korean government has highlighted the importance of energy efficiency for residential housings, and in spite of the customers' demands, the timber construction industry is still using conventional light-frame construction without even trying to improve energy efficiency. In this study, various types and combinations of wall structures were tested under cold outdoor and warm indoor temperatures to analyse the temperature gradients and to determine the possible sites of condensation in the wall structures. In addition to the experimental tests, three theoretical models were developed and their estimations of temperature change through the wall structure were compared with the actual measurements to evaluate accuracy of the models. The results of the three models agree relatively well with the experimental values, indicating that they can be used to estimate temperature changes in wall structures. The theoretical analysis of different insulation layers' combinations show that condensation may occur within the mid-layer in the conventional light-frame wall structures for any combination of inner-, mid-, and outer-layers of insulation. Therefore, it can be concluded that the addition of an inner and outer insulation layer or increasing the thickness of insulation may not be adequate to prevent condensation in the wall structure without preventing penetration of warm moist air into the wall structure.

A Note on Ileodictyon gracile(Clathraceae) in Korea

  • Ka, Kang-Hyeon;Hur, Tae-Chul;Ryoo, Cheon-In
    • Mycobiology
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    • v.32 no.1
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    • pp.54-56
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    • 2004
  • During the study of mushroom flora in Hongneung Arboretum, Ileodictyon gracile was confirmed as new to Korea and described based on morphological and microscopic characteristics in here. This species has subhypogeous, clathrate structure, and obovoid spores. The clathrate structures have $4{\sim}12$ polygonal meshes.

DPPH Radical Scavenging Activity of Phenolic Compounds Isolated from the Stem Wood of Acer tegmentosum (산겨릅나무 목질부에서 분리한 페놀성 화합물의 DPPH 라디칼 소거활성)

  • Kwon, Dong-Joo;Kim, Jin-Kyu;Bae, Young-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.1
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    • pp.104-112
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    • 2011
  • There have been few reports on the constituents and biological activity of stem bark of $Acer$ $tegmentosum$, and no phytochemical and biological studies have been reported for stem wood of $A.$ $tegmentosum$. Two flavan 3-ols (1 and 2), three phenolic acid/alcohols (3~5), and two coumarins (6 and 7) were isolated from the stem wood of $A.$ $tegmentosum$ by repeated column chromatography. The structure of isolated compounds were identified as (+)-catechin (1), (-)-epicatechin (2), $p$-hydroxybenzaldehyde (3), syringic alcohol (4), $p$-tyrosol (5), scopoletin (6), and cleomiscosin A (7) on the basis of spectroscopic evidences such as $^1H$-NMR, $^{13}C$-NMR, 2D-NMR and MS spectrum. $p$-Hydroxybenzaldehyde (3), syringic alcohol (4), scopoletin (6), and cleomiscosin A (7) have not been reported from this plant so far. (+)-Catechin (1) and (-)-epicatechin (2) showed the higher 1, 1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging activity than butylated hydroxyanisole (BHA) used as a positive control.

Pore Characterization in Cross Section of Yellow Poplar (Liriodendron tulipifera) Wood

  • Jang, Eun-Suk;Kang, Chun-Won;Jang, Sang-Sik
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.1
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    • pp.8-20
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    • 2019
  • This study was conducted to analyze the pore structure of Yellow poplar. Cross-sectional surfaces of heartwood and sapwood of Yellow poplar (Liriodendron tulipifera) were observed by SEM, and the true density of the heartwood, intermediate wood and sapwood were measured by gas pycnometery, while gas permeability and pore size of heartwood, intermediate wood and sapwood were measured by capillary flow porometery. The pores were classified as through pore, blind pore and closed pore. It was determined that the permeability was increased due to the content and size of through pore being increased although the total porosity of specimen showed slight difference from pith to bark. The content of through pore porosity was 33.754 % of heartwood and 47.810 % of sapwood, showed an increasing trend from pith to bark, however, those for the blind pore porosity and closed pore porosity were 27.890 % and 19.492 % for heartwood and 19.447 % and 4.660 % for sapwood, showed a decreasing trend from pith to bark. The max pore size of specimens was increased by about 5 times from $5.927{\mu}m$ to $31.334{\mu}m$, and mean flow pore size was increased by about 315 times from $0.397{\mu}m$ to $12.437{\mu}m$ from pith to bark.

Lignin Degradation of Pine Wood by Unidentified Decay Fungi and Observation by Scanning Electron Microscope (미동정 부후균에 의한 소나무재의 Lignin 분해와 주사전자현미경(SEM)을 이용한 관찰)

  • Park, Heon;Min, Kyeong-Heui
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.4
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    • pp.71-80
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    • 2003
  • The lignin degrading fungi were isolated from decayed woods and fruiting bodies gathered in forest area. Lignin degradation ability was investigated by Klason lignin of microbial treated pine wood. Among selected fungi, CJ-6 had 49.48% Klason lignin loss which was greater than 40.58% shown by Trametes versicolor that it is known as a typical lignin degrading fungus. Also, the biodegradation process and morphological features of degraded pine wood by selected fungi were observed with the scanning electron microscope. At the stage of 20 days incubation, mycelia invasion was observed without any failure of wood structure. At 60 days, wood decay was gone in some degree and one part of tracheid and ray wall was destroyed. At 100 days, tracheid wall was severely destroyed, and distinction between ray cell was difficult as cell wall was decayed much.

Classification of Insects Collected in Historical Wooden Building (목조 고건축물에서 채집된 곤충의 분류)

  • Jeong, In-Soo;Lee, Yang-Soo;Lee, Hee-Kwon
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.2
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    • pp.52-57
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    • 2003
  • This research is to collect, classify and identify the insects boring tunnels into wood or damaging wooden frame structure. Intensive insect collections have been carried at the historical local schools annexed to the confucian shrine from March to September 2001. Ten species of Coleoptera, 15 species of Hymenoptera, 6 species of Hemiptera, 4 species of Ditera and 1 species of Demaptera were recorded. Most species of Coleoptera and Hymenoptera have the manducatory apparatus in the mouth-part that cause severe damage in wood, and showed the highest population among the genera recorded. Further research should be considered on the identification of wood demage insects at the species level among present collection and their mechanism of wood demage in the wood.

Physical Properties of Larch(Larix kaemferi Carr.) Treated by High Temperature Steaming (고온수증기 처리에 의한 낙엽송재의 물성변화)

  • Kim, Jung-Hwan;Lee, Weon-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.4
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    • pp.1-7
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    • 2002
  • This study deals with physical properties of Larch(Larix kaemferi Carr.) treated by steaming at temperatures above 100℃. Treatment conditions of this experiment were operated at regular intervals of 10℃ at temperature up to 130℃ for 10, 30 and 60 minutes by using the auto-clave. The Bending strength and compressive strength along the grain were slightly decreased with increasing the treating temperatures. There was no significant relations between wood strength and steaming temperatures. At the range from 120℃ to 130℃ of steaming temperature, it was considered that the change of composition and structure in cell wall was changed due to release of stresses. Water absorption characteristics were not affected by steaming temperature. In this experiment limits, it was concluded that physical properties of wood by steaming treatment were affected more largely by wood density than by treating temperature.

The Effect of Indoor Wood Environment on Depression and Anxiety (실내 목재환경이 우울 및 불안에 미치는 영향)

  • Park, Yena;Hwang, Jihyun;Chae, Jeong-ho
    • Anxiety and mood
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    • v.18 no.2
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    • pp.56-64
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    • 2022
  • Objective : Creating a psychologically stable indoor environment is a significant factor in modern life. This study was conducted to confirm which type of wood interior decorating environment was beneficial for improving depression and anxiety. Methods : A total of 59 participants will randomly assign to each accommodation by dividing the rest of the three setting with the same structure with 0% wood interior decorating environment, 45% wood environment, and 90% wood environment. The Psychological evaluation measured at three time points, was before exposure to the wood environment (T1), 45 minutes after exposure to the wood environment (T2), and 20 hours after exposure to the wood environment (T3). Results : As a result of examining the effect of the wood interior use ratio on psychological variables, After about 20 hours (T3), there were significant differences in mood state_vigor-activity(𝛘2=7.253, p<0.05), mood state_tension-anxiety (𝛘2=7.041, p<0.05), mood state_anger-hostility(𝛘2=8.318, p<0.05), and state anxiety (𝛘2=7.680, p<0.05). State anxiety also showed a significant difference in T2 (𝛘2=8.811, p<.05). As a result of analyzing the effect on satisfaction and subjective impression, there was a significant difference in satisfaction (𝛘2=6.300, p<0.05) and 'pleasant (𝛘2=6.930, p<0.05), airy (𝛘2=6.628, p<0.05), masculine (𝛘2=6.906, p<0.05), ordinary(𝛘2=6.662, p<0.05), natural (𝛘2=13.924, p<0.001), calm (𝛘2=13.106, p<0.001), safe (𝛘2=7.755, p<0.05)'. Conclusion : The wood interior decorating environment had a positive effect on anxiety and mood, such as lowering depressive and anxious mood and increasing positive changes and as the ratio of wood decoration increased, it had a greater positive effect on emotions.