• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2018년도 춘계학술대회 논문집
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• pp.124-124
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• 2018

Polydopamine은 수중 접착력, 친환경 접착제, nanoparticle absorption 등 다양한 특성으로 많이 연구되고 있는 소재이다. 본 연구에서는 dopamine을 이용하여 수중 금속을 흡착시키는 thin film을 제작하였다. 종래의 Polydopamine coating 방법으로 wet coating 이 사용되고 있다. 하지만 wet 방식의 경우 시간이 오래 걸릴 뿐만 아니라 in-line, roll to roll 방식을 적용하는 것이 어렵기 때문에 생산적이지 않다. 이에 본 연구에서는 Atmospheric Pressure Plasma(APP)를 이용 하여 Polydopamine-like film을 coating 하였다. APP의 경우 vacuum system, solution tank가 필요 없고 in-line, roll to roll 방식을 적용 할 수 있기 때문에 더 경제적이고 생산적인 공정이다. 또한 기존의 Plasma polymerization 방법은 Plasma energy가 높기 때문에 source의 분자구조가 바뀌거나 atom 단위로 분해된다. source의 분자구조가 바뀌는 "Atomic polymerization", Neiswender-Rosskamp Mechanism이 적용되면 wet 방식 coating한 film과는 다른 특성을 갖게 된다. 하지만 APP polymerization은 Plasma energy가 vacuum plasma 보다 매우 낮기 때문에 stile polymerization mechanism을 구현 하는데 적합 하다. stile polymerization mechanism은 Plasma 내부에서 polymer source를 분해 성장 시켜서 Polymer film 얻는 것이 아닌 source의 분자구조가 깨지지 않으면서 polymer growing 시키는 방법이다. dopamine source의 분자구조를 최대한 유지하려고 하는 이유는 metal absorption과 같은 특성이 dopamine chemical structure에 영향을 받기 때문이다. 많은 논문들에서 dopamine의 catechol group이 metal absorption, adhesion force에 영향을 주는 주요 인자라고 주장하고 있기 때문이다. 그래서 본 논문에서는 Dopamine source의 형태를 보존하면서 Polymerization 하는 방법으로 APP process를 사용 하여 낮은 전압에서 Polydopamine-like film을 제작 하였다. APP system 의 Plasma 방전부 에 Dopamine source를 유입하기 위하여 본 논문에서는 Piezo Spray 방식을 사용 하였다. Dopamine을 evaporator 하는 것이 어렵고 chemical composition이 유사한 monomer를 사용해서 Plasma Polymerization으로 Dopamine 분자 구조를 재현하는 것도 어렵다. 그래서 본 연구에서는 Dopamine을 water에 immerse 하고 Dopamine solution을 mist 상태로 만들어서 Plasma discharge area에 유입하였다. 이러한 방법으로 만들어진 film은 Polydopamine film은 아니지만 Polydopamine film과 유사한 Chemical composition, chemical structure, metal absorption을 갖는 것을 FT-IR, SEM, XPS을 이용 하여 확인 하였다. Dopamine source의 보존에 대하여 명확하게 확인하기 위하여 FT-IR을 측정 하였다. 전압에 따른 Benzene ring, hydroxyl group의 비율을 확인 하였다. 낮은 전압으로 coating 된 Polydopamine-like film 일수록 hydroxyl group peak($3400{\sim}3000cm^{-1}$)과 비교하여 Benzene ring peak($1600{\sim}1580cm^{-1}$ and $1510{\sim}500cm^{-1}$)이 흡수를 더 많이 하는 것을 확인 할 수 있다. 이것은 Benzene ring이 파괴되지 않고 보존되는 것을 보여준다. Dopamine에서 Benzene ring은 absorption main factor인 catechol에 있는 chemical structure이다. 즉 Benzene ring peak이 높을수록 Catechol이 잘 보존 되었다는 의미 이다. Catechol의 보존은 absorption main factor가 보존 된다는 의미 이다. 이러한 Polydopamine-like film으로 As, Cr, Mg, Cu 200ppm solution에 대한 filtration 능력을 확인 하였다. As, Cr, Cu, Mg 의 제거율이 각각 약25%, 35%, 45%, 65%인 것을 확인 하였다. 이 수치는 시중에 판매되는 제품들과 비교했을 때 300%~500% 향상된 수치 이다.

• 한국세라믹학회지
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• 제34권2호
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• pp.188-194
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• 1997

TMCS(Trimethylchlorosilane)로 표면개질한 습윤겔을 에탄올에 재분산시켜 코팅용 재분산 실리카 졸을 제조하였고 제조된 졸을 실리콘 기판에 스핀 코팅한 후 상압 하에서 건조(8$0^{\circ}C$) 및 열처리(>25$0^{\circ}C$)하여 열처리온도에 따른 박막의 물성 변화를 관찰하였다. 습윤겔의 재분산시 안정한 재분산 실리카 졸의 제조를 위한 최적 재분산 조건을 습윤겔:에탄올=1g110$m\ell$로 하였고, 이렇게 제조된 재분산 실리카 졸의 농도와 점도는 각각 0.11 M, 2.0-2.2cP였으며 평균 졸 입자크기는 약 30nm정도였다. 1500rpm, 10회 스핀 코팅한 후 8$0^{\circ}C$에서 2시간 건조, 45$0^{\circ}C$에서 2시간 열처리에 의하여 굴절율이 약 1.14, 두께가 400nm정도인 균열이 없는 박막을 얻을 수 있었다.

• 한국강구조학회 논문집
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• 제28권2호
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• pp.97-108
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• 2016

금속용사 또는 도장은 강구조물의 방식에 널리 사용되고 있다. 금속용사와 도장의 복합피복방식법은 혹독한 부식환경하에 놓인 강구물의 새로운 일반적 피복방식법으로 선택되고 있다. 본 연구에서는 아연, 아연-15%알루미늄 합금, 알루미늄, 알루미늄-5%마그네슘 합금의 4종류 금속용사 후 실링 처리한 시편, 4종류 금속용사 후 중방식 도장한 시편과 도장한 시편에 대해 175일간의 NORSOK M-501 부식촉진실험, 250일간의 해수 Wet/dry 반복 부식실험, 3년간의 해양환경 옥외노출실험을 실시하였다. 그 결과, 외관관찰에 근거하여 각 방식법의 내후성능을 비교, 검토하였다.

• 펄프종이기술
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• 제48권3호
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• pp.107-114
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• 2016

Terra Alba Wallpaper was manufactured by coating inorganic terra alba paint on white base paper, and the surface of the coated layers were microscopically observed. Eco Terra Alba used the functional wall paper in this study was prepared by mixing inorganic Terra Alba and calcium carbonate. Terra Alba showed particle shape. The concentration of inorganic components, pH, and the viscosity of the coating solution were 92.0%, 7.82, 1286 cPs, respectively. The bar coater whit No 3 wire resulted in the least thickness of wet coating layer and coating thickness such $22.5{\mu}m$ with covered all the surface. Bar coater with No. 12 wire leaded to $48.4{\mu}m$ thickness. The coating layers above $43{\mu}m$ thickness showed the cracks on the wall paper surface after coating.

• 한국재료학회지
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• 제23권1호
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• pp.72-80
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• 2013

Recently, consumption of magnesium alloys has increased especially in the 3C (computer, communication, camera) and automobile industries. The structural application of magnesium alloys has many advantages due to their low densities, high specific strength, excellent damping and anti-eletromagnetic properties, and easy recycling. However, practical application of these alloys has been limited to narrow uses of mild condition, because they are inferior in corrosion resistance and wear resistance due to their high chemical reactivity and low hardness. Various wet and dry processes are being used or are under development to enhance alloy surface properties. Various conversion coating and anodizing methods have been developed in a view of eco-friendly concept. The conventional technologies, such as diffusion coating, sol-gel coating, hydrothermal treatment, and organic coating, are expected to be newly applicable to magnesium alloys. Surface treatments for metallic luster or coloring are suggested using the control of the micro roughness. This report reviews the recent R&D trends and achievements in surface treatment technologies for magnesium alloys.

• Corrosion Science and Technology
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• 제3권3호
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• pp.98-101
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• 2004

The corrosion behavior of Al-Fe coatings was studied in the wet-seal atmosphere of molten carbonate fuel cells (MCFC). Fe-8Al, Fe-16Al, Fe-25Al, Fe-36Al, and Fe-70Al (in at.%) specimens were tested in Li/K carbonate at $650^{\circ}C$ by a single cell test and an immersion test. In general, the corrosion resistance of the Al-Fe coatings was enhanced due to the formation of a protective $LiAlO_2$ layer. However, when the Al-Fe coatings didn't have sufficient content of aluminum enough for maintaining the protective layer, the corrosion resistance of the Al-Fe coatings was severely degraded by the growth of non-protective scales like $LiAlO_2$. The test results revealed that the aluminum contents in the coatings should be higher than 25 at.% in order to form and maintain the protective $LiAlO_2$ layers.

• 한국전기전자재료학회논문지
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• 제18권12호
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• pp.1106-1110
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• 2005

We fabricated (110) silicon hard master by using anisotropic wet etching for embossing. The etching chemical for the silicon wafer was a TMAH $25\%$ solution. The anisotropic wet etching produces a smooth sidewall surface and the surface roughness of the fabricated master is about 3 nm. After spin coating an organic-inorganic sol-gel hybrid material on a silicon substrate, we employed hot embossing technique operated at a low pressure and temperature to form patterns on the silicon substrate by using the fabricated master. We successfully fabricated the multi-mode planar optical waveguides showing low propagation loss of 0.4 dB/cm. The surface roughness of embossed patterns was uniform for more than 10 times of the embossing processes with a single hydrophobic surface treatment of the silicon hard master.

• 한국염색가공학회지
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• 제26권4호
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• pp.322-330
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• 2014

The phospholipid-based MPCE(2-Methacryloxyethyl Phosphoryl Chlorine) copolymer was mixed with wet polyurethane for coating of nylon fabrics. The substitution rate of water in coagulation bath with DMF was changed under control of the size of formed hydrophilic microporous cell enable to manufacture excellent breathable, anti-bacterial and moisture control fabrics. Biocompatible property, vapor permeability, hydrostatic pressure, moisture management and anti-bacterial property were investigated for treated nylon fabrics. In result, increased moisture transmission rates, decreased water resistance and outstanding moisture control property could be confirmed by enhanced hydrophilicity of wet-coated nylon fabric with MPCE copolymer.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1995년도 봄 학술발표회 논문집
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• pp.396-401
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• 1995

Epoxy coated reinforcing steels (ECRs) were acquired from ten sources and coatings from each source were initially characterized in terms of defects, thickness, solvent extraction weight loss and hardness. Testing involved exposure in three aqueous solutions at elevated temperature (8$0^{\circ}C$) and in chloride-contaminated concrete slabs under outdoor exposure, It was found that the density and size of coating defects was the promary factor affecting ECR performance. The equivalent circuit analysis using electrochemical impedance spectroscopy (EIS) data indicated that the impedance response for well-performing ECR specimens showed no signs of active degradation at the interface although diffusional processes similar to those noted for poorly performing bars occurred here. Experimental results also indicated a relationship between corrosion behavior and bar source. Weight loss upon solvent extraction correlated with impedance reduction from hot water exposure. Coating defects during most of the tests, especially in high pH solutions containing chloride ions. ECRs with excessive coating defects, either initially present or ones which developed in service, performed poorly in every test category regardless of source. Forms of coating failure were extensive rusting at defects, blistering, wet adhesion loss, cathodic delamination, underfilm corrosion and coating cracks. These occurred sequentially or concurrently, depending on the condition of the ECR and nature of the environment

• Corrosion Science and Technology
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• 제5권1호
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• pp.33-38
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• 2006

Current coating practice requires the thickness of anti-corrosion organic coatings to be over $250{\mu}m$ for immersion parts of ships and offshore structures and the corrosion resistance of these coatings has been evaluated by destructive and qualitative analysis. Recently, Electrochemical Impedance Spectroscopy(EIS) method has been employed, as an alternative, to evaluate corrosion resistance of organic coatings. This method is characterized as being nondestructive, reproducible, and quantitative in evaluating aging of organic coatings. In this study, EIS method was adopted to quantitatively and effectively select the coating systems having optimized protective performance. Evaluations of several epoxy and epoxy/polyurethane coating systems typically used for ships and offshore structures were carried out in wet($50^{\circ}C$, $90^{\circ}C$) and dry(room temp.) environments to accelerate the degradation of the organic coatings. These results were compared with the conventional scribed(scratched) test results. The plausible prediction model for determining the remaining life-time of coating systems was also proposed based on variations of impedance data, FT-IR and $T_g$ measurements results.