• Title/Summary/Keyword: Weight shift

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Synthesis and Swelling Kinetics of a Cross-Linked pH-Sensitive Ternary Copolymer Gel System (pH-민감성 삼성분계 공중합체 젤의 합성 및 팽윤 속도론)

  • Zafar, Zafar Iqbal;Malana, M.A.;Pervez, H.;Shad, M.A.;Momma, K.
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.219-229
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    • 2008
  • A pH sensitive ternary copolymer gel was synthesized in the presence of ethylene glycol dimethacrylate (EGDMA) as a crosslinking agent through radical polymerization of vinyl acetate (VA), acrylic acid (AA) and methyl acrylate(MA) with a weight ratio of 1 : 1.3 : 1. A number of experiments were carried out to determine the swelling behavior of the gel under a variety of pH conditions of the swelling medium. As the pH of the swelling medium was changed from 1.0 to 8.0 at $37^{\circ}C$, the gel showed a shift in the pH-dependent swelling behavior from Fickian (n=0.3447) to non-Fickian (n=0.9125). The resulting swelling parameters were analyzed using graphical and statistical methods. The results showed that the swelling of the gel was controlled by the pH of the medium, i.e. $n=n_o{\exp}(S_{C}pH)$, where n is the diffusion exponent, $n_o(=28.9645{\times}10^{-2})$ is the pre-exponential factor and $S_C$(=0.1417) is pH sensitivity coefficient. The swelling behavior of the gel was also examined in aliphatic alcohols. The results showed that the rate of swelling increased with increasing number of carbon atoms in the alcoholic molecular chain.

Buried Fiber Optic Intrusion Sensor (매설형 광섬유 침입자 센서)

  • Park, Jae-Hee;Kim, Myung-Gyoo;Sohn, Byung-Ki
    • Journal of Sensor Science and Technology
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    • v.5 no.6
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    • pp.1-6
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    • 1996
  • The feasibility of producing a practical buried fiber optic sensor with high sensitivity for detecting intruders is demonstrated. Experiments were carried out with the use of an all fiber Michelson interferometer, the sensing arm of which was buried in sand. When the sensing arm was buried 8 inches deep in sand, the pressure length product required for a half fringe shift in: the sensor output was $1.09\;kPa{\cdot}m$. The relation between the applied weight and the phase change was almost linear. Experimental results indicated that the sensitivity of the optical fiber sensor was sufficient to detect people on foot and vehicles passing over the buried fiber.

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Synthesis and Characterization of Poly(lactic-co-mandelic acid)s by Direct Solution Polycondensation (직접 용액 축중합에 의한 Poly(lactic acid-co-mandelic acid)의 합성 및 특성 조사)

  • 김완중;김지흥;김수현;김영하
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.431-436
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    • 2000
  • To improve the thermal and mechanical properties of homo poly(L-lactic acid), DL-mandelic acid, one of the natural $\alpha$-hydroxy acid with aromatic ring as the side-chain residue was used as the comonomer. Copolymers with different contents of mandelic acid were prepared and characterized. The resulting copolymers were mostly amorphous. As the amount of mandelic acid in the monomer feed increased, the molecular weight of the resulting polymers tended to decrease linearly. T$_{g}$ and T$_{d}$ of the copolymer, however, were found to shift toward higher temperature, suggesting the improved thermal stability by increasing content of mandelic acid moiety. Tensile measurements of cast films showed somewhat improved values in the copolymers with mandelic acid content of 5 and 10 wt%.%.%.

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Cure Kinetics and Dynamic Mechanical Properties of an Epoxy/Polyoxypropylene Diamine System (에폭시/폴리옥시프로필렌 디아민계의 경화 반응속도 및 동역학 특성 분석)

  • Huang, Guang-Chun;Lee, Jong-Keun
    • Polymer(Korea)
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    • v.35 no.3
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    • pp.196-202
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    • 2011
  • The cure kinetics of a bisphenol A epoxy resin and polyoxypropylene diamine curing agent system are investigated in both dynamic and isothermal conditions by differential scanning calorimetry (DSC). In dynamic experiments, the shift of exothermic peaks obtained at different heating rates is used to obtain activation energy of overall cure reaction based on the methods of Ozawa and Kissinger. Isothermal DSC data at different temperatures are fitted to an autocatalytic Kamal kinetic model. The kinetic model is in a good agreement with the experimental data in the initial stage of cure. A diffusion effect is incorporated to describe the later stage of cure, predicting the cure kinetics over the whole range of curing process. Also, dynamic mechanical analysis is performed to evaluate the storage modulus and average molecular weight between crosslinkages.

Cloning, Purification, and Structural Characterization by 1D 1H-NMR of the PDZ domain of the Shank3 protein (Shank3 PDZ 도메인의 동정, 정제 및 1차 NMR 구조분석)

  • Sung, Mee-Sook
    • Journal of Life Science
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    • v.17 no.3 s.83
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    • pp.345-349
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    • 2007
  • We wished to create a set of small molecular weight PDZ domain ligands that may be used in functional studies on the proteins AF6, PSD-95 and Shank. As a starting point, the Shank3 PDZ domain was cloned, purified, and characterized the structure of Shank3 PDZ domain by 1D $^1H-NMR$. The chemical shift dispersion of the proton signals indicates that the purified Shank3 PDZ protein is very pure and globally well folded. Currently, we are working on improving the yield of the protein production for complete NMR structural analysis of the Shank3 PDZ domain.

The Porosity and the Dyeability of Polyester Fiber Treated with Sodium Hydroxide Aqueous Solution (알칼리 감량 폴리에스테르 섬유의 기공도와 염색성)

  • 김병인;김태경;임용진;조광호;조규민
    • Textile Coloration and Finishing
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    • v.12 no.6
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    • pp.380-388
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    • 2000
  • The porosity of polyester fibers treated with sodium hydroxide aqueous solution was investigated using a nitrogen porosimeter, and the dyeability of the treated fibers was discussed in terms of the porosity. In pore distribution, the polyester fibers treated with sodium hydroxide aqueous solution were characterized by higher amount of pores below $10\AA$ than those of the untreated fibers, and by shift of the pore size having maximum accumulated volume from $10\AA$ for the untreated fibers to $5~6\AA$. As the weight loss of the polyester fibers treated with sodium hydroxide aqueous solution increased, BET surface area and total pore volume increased linearly, but average pore size, showing some different aspect, increased steeply at earlier stage and then approached the maximum value. The dye uptakes of the polyester fibers treated with sodium hydroxide aqueous solution increased with the BET surface area, the total pore volume and the average pore size. The alkali treatment increased the surface area of polyester fibers, so that the chance of contact between the fiber and dye molecules increased. In addition, the pores created on the surface of polyester fibers by alkali treatment might act as pathways for dye molecules into the polyester fibers.

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Development of the Gait Rehabilitation Equipment for Hemiplegic Patients after Stroke (편마비 환자를 위한 보행 재활기구 개발)

  • Nam, T.W.;Cho, J.M.;Kim, S.H.;Lim, J.H.
    • Journal of Biomedical Engineering Research
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    • v.27 no.5
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    • pp.245-249
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    • 2006
  • The aim of this study is to design and develop the gait rehabilitation equipment that judge patient's movement of his/her center of gravity using pressure sensors, and to aid hemiplegic patients to balance themselves using an automatic stepper that changes the patient's center of gravity. It is hard to bear the weight on the affected side for hemiplegic patients. The gait rehabilitation equipment detects the footing phase of hemiplegic patient during training and moves the unaffected footing side of the stepper up and moves the affected footing side down simultaneously so that the patient's center of gravity can shift from unaffected side to affected side. The gait rehabilitation system was developed and applied for hemiplegic patients during exercise. Eight hemiplegic patients and one normal adult were studied. The developed gait rehabilitation system could judge not only the normal adult's intention but also the patient's intention to move his/her center of gravity. Even though the most of hemiplegic patients exercised in automatic mode and a few hemiplegic patients exercised in manual mode, the developed gait rehabilitation system can aid the hemiplegic patients to train more easily.

Binding of Methylene Blue to two types of water soluble polymer and its removal by polyelectrolyte enhanced ultrafiltration

  • Mansour, Nadia Cheickh;Ouni, Hedia;Hafiane, Amor
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.87-94
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    • 2018
  • The interactions of water soluble polymers with dye are studied by ultrafiltration using a molecular weight cut off of 10 KDa regenerated cellulose ultrafiltration membrane. Two water-soluble polymers, namely Poly (Sodium-4 Styrenesulfonate) (PSS) and Poly (Vinyl Alcohol) (PVA) were selected for this study. The effects of process parameters, such as, polyelectrolyte concentrations, transmembrane pressure, ionic strength and pH of solution on dye retention and permeation flux were examined. PSS enhanced ultrafiltration achieved dye retention as high as 99% as a result of complexation between polyanion containing aromatic groups and cationic dye. This result was confirmed by the red shift. The retention of dye decreases as the salt concentration increases, a high retention was obtained at pH above 4. However, in case of PVA, relatively low retention (50%) was observed. Ionic strength and pH has no significant effect on the removal of MB. The permeate flux depended slightly on polyelectrolytes concentrations, transmembrane pressure, salt concentration and pH.

Nutritional Support for Neurocritically Ill Patients (신경계 중환자의 영양 집중 치료)

  • Jeong, Hae-Bong;Park, Soo-Hyun;Ryu, Ho Geol
    • Journal of Neurocritical Care
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    • v.11 no.2
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    • pp.71-80
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    • 2018
  • Nutritional assessment and support are often overlooked in the critically ill due to other urgent priorities. Unlike oxygenation, organ dysfunction, infection, or consciousness, there is no consensus of indicators. Making it difficult to evaluate the effectiveness of an intervention. Nevertheless, appropriate nutritional support in the critically ill has been associated with less morbidity and lower mortality. But, nutritional support has been considered an adjunct, for body weight maintenance and to help patients during the inflammatory phase of illness. Thus, it has been assigned a lower priority, compared to mechanical ventilation or hemodynamic stability. Recent findings have shown that nutritional support may prevent cellular injury due to oxidative stress and help strengthen the immune response. Large-scale randomized trials and clinical guidelines have shown a shift from nutritional support to nutritional therapy, with an emphasis on the importance of protein, minerals, vitamins, and trace elements. Nutrition is also important in neurocritically ill patients. Since there are few studies or recommendations with regard to the neurocritical population, the general recommendations for nutritional support should be applied.

Effects of a Bilateral upper Limb Training Program Using a Visual Feedback Method on Individuals with Chronic Stroke: A Pilot Clinical Trial

  • Kang, Dongheon;Park, Jiyoung;Choi, Chisun;Eun, Seon-Deok
    • International Journal of Contents
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    • v.17 no.2
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    • pp.20-31
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    • 2021
  • This study aimed to pilot test a newly developed bilateral upper limb rehabilitation training program for improving the upper limb function of individuals with chronic stroke using a visual feedback method. The double-group pretest-posttest design pilot study included 10 individuals with chronic stroke (age >50 years). The intervention (four weekly meetings) consisted of five upper limb training protocols (wrist extension; forearm supination and pronation; elbow extension and shoulder flexion; weight-bearing shift; and shoulder, elbow, and wrist complex movements). Upper limb movement function recovery was assessed with the FuglMeyer Assessment of the Upper Extremity, the Wolf Motor Function Test, the Trunk Control Test, the modified Ashworth Scale, and the visual analog scale at baseline, immediately after, and four weeks after the intervention. The Fatigue Severity Scale was also employed. The Fugl-Meyer Assessment of the Upper Extremity and Wolf Motor Function Test showed significant improvement in upper limb motor function. The Trunk Control Test results increased slightly, and the modified Ashworth Scale decreased slightly, without statistical significance. The visual analog scale scores showed a significant decrease and the Fatigue Severity Scale scores were moderate or low. The bilateral upper limb training program using the visual feedback method could result in slight upper limb function improvements in individuals with chronic stroke.