• Journal of Energy Engineering
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• v.25 no.1
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• pp.1-8
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• 2016

When the oil is produced in the low temperature environment, wax can be accumulated in petroleum production system(pipeline, riser) and causes problems such as pipeline stucking, disturbance of the oil production. These problems can be lead to time-consuming and economic losses for flow assurance. For prediction and mitigation of wax deposition, it is necessary to measure the Wax Appearance Temperature(WAT) which is a temperature when the wax crystals start to be formed. WAT standard measurement method of transparent oil has to determine the cloud point of sample to the naked eye and cannot be applied to continuous change of the temperature. In this study, wax behavior of transparent oil samples are recorded depending on temperature using Visualized WAT Measurement System. Also, WATs of transparent oil samples are measured by image processing and compared with the result of the standard method.

• Journal of Energy Engineering
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• v.24 no.2
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• pp.1-8
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• 2015

Wax deposition hinders oil flow assurance. Huge amount of money and time were required for mitigation of wax deposition in the oil field. For prediction and mitigation of wax deposition problem, Wax Appearance Temperature(WAT), which is the temperature at which the first wax crystals start to form, needs to be measured in advance. There is a standard method which is optical way to measure the WAT of transparent oil. However, standard method cannot be applied to opaque oil which is common produced oil in the field. In this study, WAT of three transparent oil samples were measured using heat flux variation analysis, viscosity variation analysis and density variation analysis, and compared with WAT measured by standard method. As a result, WAT measured by density variation analysis is the more reliable than heat flux variation analysis and viscosity variation analysis. WAT of two opaque oils were measured using density variation analysis.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.376-381
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• 2013

High molecular weight paraffinic waxes dissolved in oil phases can be precipitated when the surrounding temperature becomes lower than the wax appearance temperature (WAT). While the various methods of WAT determination have been developed, the determination of precipitated wax amount has not been comparably popular at temperatures below the WAT. It is important to predict how much solid wax content precipitates in temperature variance. The study develops the previous method which uses integrated areas determined at a wavenumber range of 735~715 $cm^{-1}$. This method uses two different wavenumber ranges, 735~715 $cm^{-1}$ and 1,402~1,324 $cm^{-1}$. The study shows how the method provides reliable data in the variety of applications regardless of FTIR spectral instability often occurred, such as volume reduction during cooling procedure and existence of emulsified water in oil phase.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.1
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• pp.185-194
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• 2012

Deepwater oil is becoming more attractive because most onshore and shallow water oil is developing or developed. With the on-going trend to deepwater oil developments, flow assurance problems which prevent oil flow from reservoir to processing facilities are becoming an issue because deposited material can be occurred in case oil is exposed to very different environment from reservoir. Wax deposition which is one of flow assurance problems can be a major technical and economic issue because it is very sensitive to temperature. In order to predict and mitigate wax problems, the precise measurement of wax appearance temperature (WAT) which is the starting temperature of wax precipitation is very important. Various methods have been suggested for WAT measurement of opaque oil because there is no standard method for opaque oil. In this study, the WAT of opaque oil samples was measured using viscosity measurement method, differential scanning calorimetry, filter plugging method, and pressurized filter plugging method. Wax deposition test and high temperature gas chromatography analysis were applied to verify measured WAT. As a result of study, the WAT of opaque oils was successfully measured and verified. If WAT measurement methods of opaque oil related to oil characteristics is systematized using the results of this study, it can be a valuable tool for WAT measurement of opaque oil and flow assurance related to wax deposition.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.10
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• pp.1333-1339
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• 2014

As the demand for petroleum resources increases, and oilfields on lands and in shallow-sea become exhausted, the areas for oil production are expanding to the deep sea and therefore technologies for flow assurance are coming into the highlight. In low temperature environment such as the deep sea, wax is accumulated and prevents stable oil production. Therefore, the development of flow assurance technologies is required. Wax is precipitated in crystalline form when the oil temperature decreases below the wax appearance temperature; it then accumulates on the inner walls of pipelines causing blockages. In particular, in subsea pipelines, which have a large surface contact area with the surrounding seawater, wax deposition problems are frequent. The internal tubular coating can effectively reduce wax deposition without pausing oil production when the coating is appropriately designed. This study carried out wax deposition tests on a number of internal tubular coatings under single flow conditions. The results were analyzed for the effects that the physical properties of the coatings had on wax deposition.

• Elastomers and Composites
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• v.44 no.4
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• pp.397-400
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• 2009

Ozone caused the crack on the surface of a rubber article by oxidation of double bond at room temperature. Wax migrates to the surface of a rubber article and makes a physical barrier to prevent process of ozonation. We investigated change of molecular weight distribution of waxes in unfilled NR, SBR, and BR vulcanizates before and after aging at room temperature for 6 months. Migration and evaporation behaviors of wax in a rubber article at ambient conditions help understand a role of wax as an antidegradant and appearance contamination of a rubber article. The relative intensity distribution of n-alkanes of the NR specimen after the aging was shifted to higher molecular weight compared with the relative intensity distribution before the aging, while those of the SBR specimen before and after the aging did not show a big difference.

• Journal of the Korean Applied Science and Technology
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• v.34 no.3
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• pp.495-503
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• 2017

Wax components can be precipitated when surrounding temperature decreases below wax precipitation temperature (WAT). WAT as well as pour point are important characteristics to evaluate the behavior of waxy oils. In this study, qualitative and quantitative evaluations of waxes in waxy model oils were presented after determining WAT and pour point. In case of anhydrous waxy model oils, ASTM D2500 may be most useful to determine WAT because of the transparent nature of model oils. With same apparatus, ASTM D97 is also applicable to determine the pour point of waxy oils in a serial determination. In case of emulsified model oils, however, it is difficult to measure WAT because of its opaque nature. This study employed FTIR spectroscopy to determine wax precipitation temperature and discussed the effect of emulsion state regarding the values of WAT. Further study would be needed to conclude the effect of water contents to WAT values in case of emulsified waxy oil.

• Korean Journal of Agricultural Science
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• v.20 no.1
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• pp.9-17
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• 1993

Postharvest treatments such as polyethylene film wrapping, ethylene scrubber, and fruit coatings were compared to find a potential effect on the fruit quality in 'Fuji' apples during storage and simulated marketing. Polyethylene film wrapping appeared to be excellent in preventing weight loss during storage but fruits lost weight at a high rate when exposed to ambient temperature during simulated marketing. Also, surface cracking disorder was observed in parts of film-wrapped fruit under marketing condition after storage of 21 weeks. Ethylene scrubber effectively removed ethylene in polyetheylene bags but this effect reduced along with the increase of storage time. Although Prolong-treated fruits were good in appearance at 12-week storage, no beneficial effect was found on the inhibition of weight loss during storage as well as marketing. In addition, wax-like substances were accumulated on the surface after storage of 21 weeks, resulting in the reduction of marketability. Water soluble wax seemed highly effective on the inhibition of weight loss during storage and marketing. However, parts of fruit were severely injured probably due to the high concentration of wax. Undamaged fruit showed excellent appearance in shape and flesh quality even after 21 weeks of storage. Further study is required to find the proper concentration of wax.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2011.10a
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• pp.127-127
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• 2011

• Journal of the Korean Society of Marine Environment & Safety
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• v.8 no.2
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• pp.79-86
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• 2002

A heating cargo is solidified by several reasons during carriage. This study is to analyse a cargo accident which 811,202 US barrels of Nile Blend crude oil reamined solid In the tanks after discharge. There are some possibilities that low temperature of Beading cargo below cloud point and wax appearance temperature at loading time, heating interruption during voyage or discharging, and prohibition of crude oil washing during discharging might influence the cargo solidified. But we concluded that the defect of heating system would most affect the heating cargo solidified locally, and which blocked drain hole of bottom transverse and web frame and they obstruct flow of heating cargo in the tanks.