• Bulletin of the Korean Chemical Society
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• v.16 no.11
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• pp.1028-1032
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• 1995

The structure and electronic properties of the Si(100) surface is studied using the atom superposition and electron delocalization method. The energy released when the symmetric dimer surface is reconstructed to form the buckled dimer surface with p(2X2) symmetry is calculated to be 0.99 eV per dimer in the case of ideal clean surfaces. This indicates that the surface dimer buckling is intrinsic from the viewpoint of thermodynamics. The relaxation energy, when water is adsorbed on the clean symmetric dimer surface to form the buckled dimer surface, is 2.25 eV per dimer for appropriate coverages. These results show that H2O molecule could induce a reconstruction of the surface structure through adsorption. The buckling of the surface dimer is, therefore, more favorable under the existence of water vapour. This conclusion supports the recently obtained experimental observations by Chander et al.

• 연구논문집
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• s.29
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• pp.5-15
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• 1999

Present study deals with performance analysis of an inert gas generator (IGG) which is to be used as an effective mean to suppress the fire. The IGG uses a turbo jet cycle gas turbine engine to generate inert gas for fire extinguishing. It is generally known that a lesser degree of oxygen content in the product of combustion will increase the effectiveness of fire suppressing. An inert gas generator system with water injection will bring advantages of suffocating and cooling effects which are considered as vital factors for fire extinguishing. As the inert gas is injected to the burning site, it lowers the oxygen content of the air surrounding the flame as well as reduces the temperature around the fire as the vapour in the inert gas evaporates during the time of spreading. Some important aspects of influencing parameters, such as, air excess coefficient. $\alpha$, compressor pressure ratio, $ pi_c$, air temperature before combustion chamber, $T_2$, gas temperature after combustion chamber, $T_3$, mass flow rate of water injection, $M_w$, etc., on the performance of IGG system are investigated. Calculations of total amount of water needed to reduce the turbine exit temperature to pre-set nozzle exit temperature employing a heat exchanger were made to compare the economics of the system. A heat exchanger with two step cooling by water and steam is considered to be better than water cooling only. Computer programs were developed to perform the cycle analysis of the IGG system and heat exchanger considered in the present study.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.10
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• pp.27-33
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• 2016

Military textiles with breathable waterproof materials are expanding as form of winter clothes. Waterproof moisture-permeable clothes are very important for soldiers to survive in cold weather operations because they prevent loss of body heat from the penetration of water into the human body. Korea military uses the water resistance and moisture permeability to test the performance of waterproof moisture-permeable materials. Moisture permeability is measured according to the amount of evaporated water vapor passing through a fabric under specified temperature and humidity by using acetic acid potassium presented in KS K 0594. However, the test procedure for measuring the moisture permeability in the standard is presented only briefly and the preparation procedures for the test in accredited testing institutions are applied differently, leading to significant deviation of the results. This paper compares the procedures of testing institutions and examines the factors that affect moisture permeability. Finally, we propose a procedure to reduce the deviation of results and apply the proposed procedure in testing institutions. Our analysis results with one-way ANOVA under significant level (0.05) confirm that the deviation of results is reduced.

• Journal of the Korean Chemical Society
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• v.23 no.5
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• pp.329-337
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• 1979

The water-vapour transmission ratios (WVTR) of the various commercial polymer films have been investigated at the constant pressure and relative humidity (RH). Water proofnesses, the reciprocals of WVTR for the various samples, were determined using a cup device and maintaining the sample films at a constant temperature ($40{\pm}1^{\circ}C$) and a constant R. H ($90{\pm}2%$) for 24 hours. The following order of the relative proofness was observed; oriented polypropyrene (O.PP) > high density polyethylene (HDPE, Inflation) > high density polyethylene (HDPE. T-die) > casted polypropylene (C. PP) > nonoriented polyester (N. PET) > low density polyethylene (LDPE) > oriented polyester (O. PET) > rigid polyvinyl chloride (Rigid PVC) > semirigid polyvinyl chloride (Semirigid PVC) > nonrigid polyvinyl chloride (Nonrigid PVC) > oriented nylon (O. Nylon) > nonoriented nylon (N. Nylon). And water proofness order was also observed to decrease with the temperature rising; HDPE (T-die) > C. PP > O. PET > LDPE > O. Nylon. The activation energies of LDPE, HDPE (T-die), C. PP, O. PET and O.Nylon films were 12.0, 11.1, 11.4, 11.7, 14.1 kcal/mole, respectively. The WVTR's of the films were increased with the polarity of polymer and the addition of plasticizer in PVC, decreased with the increase of the film thickness and mechanical orientation. The WVTR's of the laminated films O. PP/LDPE, N.Nylon/LDPE, C.PP/LDPE were also more dependent on the film thickness than the WVTR's of the single films.

• Journal of Korean Society of Forest Science
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• v.54 no.1
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• pp.36-40
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• 1981

with the chemical equilibrium formula by Hailwood and Horrobin, $$m=a{\cdot}((k_1k_2h)(1+k_1k_2h)^{-1}+(k_2h)_n-k_2h)^{-1})$$, based on absorption theory, monthly equilibrium moisture content(EMC) variations in southern Korea were predicted. The results were as follows: $$k_1=47370272{\cdot}10^{-7}+477345{\cdot}10^{-7}t-502775{\cdot}10^{-8}t^2$$ $$k_2=705940864{\cdot}10^{-9}+16979472{\cdot}10^{-10}t-555336{\cdot}10^{-11}t^2$$ $$w=2233848{\cdot}10^{-4}+694242{\cdot}10^{-6}+185328{\cdot}10^{-7}t^2$$ Here, it is temperature degrees in Celsius, k is the equilibria between hydrate water and dissolved water, k is the equilibria between dissolved water and the water vapour pressure surrounding atmosphere, w is the molecular weight of the polymer unit that forms the hydrate, h is the relative vapour pressure, And the formula was well agreed with the data when the constant values ${\alpha}$ were given to be 2200 in January, February, October, November and December, 1850 in March, April and May, 1920 June, July, August, and September seasonally.

• Fire Science and Engineering
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• v.25 no.1
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• pp.42-49
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• 2011

In the high temperature situation like in a fire, the high strength of concrete (HSC) has extreme danger named explosive spalling. It is assumed that the major cause of explosive spalling is water vapour pressure inside concrete. This paper examines the effect of the compressive strength and the moisture content on the initial occurrence of explosive spalling. For the effective experiment of the initial explosive spalling, the curve of ISO834 temperature profile is applied on the basis of 15 minute and 30 minute. As a result, the more increase the compressive strength and the moisture content, the more increase the occurrence and phenomenon of explosive spalling. This paper analyzes the territory of explosive spalling depending the compressive strength and the moisture content. The explosive spalling is not examined in the case of the compressive strength 50~100 MPa and the moisture content below 3% and the compressive strength over 100 MPa and the moisture content below 1%. Also, due to the HSC, which makes it more difficult to transport vapour and moisture, very high vapour-pressure may occur close to the surface, there is a greater risk that HSC spalls compared with normal strength concrete (NSC).

• Nuclear Engineering and Technology
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• v.52 no.3
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• pp.597-609
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• 2020

Accident Tolerant Fuels have been widely studied since the Fukushima-Daiichi accident in 2011 as one of the options on how to further enhance the safety of nuclear power plants. Deposition of protective coatings on nuclear fuel claddings has been considered as a near-term concept that will reduce the high-temperature oxidation rate and enhance accidental tolerance of the cladding while providing additional benefits during normal operation and transients. This study focuses on experimental testing of Zr-based alloys coated with Cr-based coatings using Physical Vapour Deposition. The results of long-term corrosion tests, as well as tests simulating postulated accidents, are presented. Zr-1%Nb alloy used as nuclear fuel cladding serves as a substrate and Cr, CrN, Cr_xN_y layers are deposited by unbalanced magnetron sputtering and reactive magnetron sputtering. The deposition procedures are optimized in order to improve coating properties. Coated as well as reference uncoated samples were experimentally tested. The presented results include standard long-term corrosion tests at 360℃ in WWER water chemistry, burst (creep) tests and mainly single and double-sided high-temperature steam oxidation tests between 1000 and 1400℃ related to postulated Loss-of-coolant accident and Design extension conditions. Coated and reference samples were characterized pre- and post-testing using mechanical testing (microhardness, ring compression test), Thermal Evolved Gas Analysis analysis (hydrogen, oxygen concentration), optical microscopy, scanning electron microscopy (EDS, WDS, EBSD) and X-ray diffraction.

• Textile Coloration and Finishing
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• v.27 no.2
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• pp.126-131
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• 2015

Silica-polyurethane hybrid breathable films were prepared and their breathabilities were assessed. Appropriately aggregated silica was prepared through sol-gel reaction of water glass and its particle size ranged 360~500nm. The polyurethane dispersion was prepared by the reaction of isophorone diisocyanate(IPDI) as diisocyanate and polytetramethylene glycol(PTMG) and dimethylol propionic acid(DMPA) as polyol, particle size ranging 30~120nm. The reaction between isocyanate and hydroxyl group to form urethane bonding was checked by the intensity of the stretch peak of isocyanate at $2270cm^{-1}$ in the FT-IR. The silica was incorporated into polyurethane dispersion and casted into film. It was shown that the incorporated silica(1~5wt.%) increased water vapour permeability of the films by 30~100%, and decreased the hydrostatic pressure by 10~40%. From the results, it could be concluded that the appropriate hybridization of silica can increase the breathability of polyurethane dispersion film, while minimizing the loss of hydrostatic pressure.

• Food Science of Animal Resources
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• v.18 no.4
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• pp.285-291
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• 1998

Adsorption isotherms of water vapour for infant formula milk powders manufactured by P. M. and N company in Korea were measured at temperatures between 20, 30 and 40$^{\circ}C$ using COST-90 modified method. Results showed that the isotherms were sigmoidal in shape. The adsorption isotherms of milk powder were depending on the temperature and products. The BET-model were applied and analyzed to compare the experimental value. It was found that the BET-model is fitted with measuring data. Sample P showed the lowest monolayer value and sample N showed the highest. Isosteric heat obtained upon application of BET-model was calculated in this field of temperature using the Clausius-Clapeyron equation. It is suggested that the usage of the BET-model to estimate the heat of water sorption in infant formula milk powder should be in agreement with the results from COST-90 project.

• Solar Energy
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• v.11 no.1
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• pp.78-86
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• 1991

Heat transfer characteristics of a rotating heat pipe have been studied numerically and experimentally with using water-ethanol mixture as working fluid. And triangular fins are attached inside the rotating heat pipe. Experimental results generally agreed with numerical results. According to increasing rpm and vapour pressure of the rotating heat pipe, the heat transfer rate increased. And also according to decreasing the concentration of ethanol, the heat transfer rate increased. In the case of using the pure ethanol as working fluid, the heat transfer rate was about 80% of using distilled water. The heat transfer rate and operating temperature difference of the rotating heat pipe was much influenced by ethanol concentration, and the optimum ethanol concentration was 0.2.