• 제목/요약/키워드: Water surrogate

검색결과 66건 처리시간 0.033초

한강수질 평가를 위한 COD (화학적 산소 요구량) 모델 평가 (Chemical Oxygen Demand (COD) Model for the Assessment of Water Quality in the Han River, Korea)

  • Kim, Jae Hyoun;Jo, Jinnam
    • 한국환경보건학회지
    • /
    • 제42권4호
    • /
    • pp.280-292
    • /
    • 2016
  • Objectives: The objective of this study was to build COD regression models for the Han River and evaluate water quality. Methods: Water quality data sets for the dry season (as of January) during a four-year period (2012-2015) were collected from the database of the Han River automatic water quality monitoring stations. Statistical techniques, including combined genetic algorithm-multiple linear regression (GA-MLR) were used to build five-descriptor COD models. Multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis (CA) are useful tools for extracting meaningful information. Results: The $r^2$ of the best COD models provided significant high values (> 0.8) between 2012 and 2015. Total organic carbon (TOC) was a surrogate indicator for COD (as COD/TOC) with high reliability ($r^2=0.63$ in 2012, $r^2=0.75$ for 2013, $r^2=0.79$ for 2014 and $r^2=0.85$ for 2015). The ratios of COD/TOC were calculated as 2.08 in 2012, 1.79 in 2013, 1.52 and 1.45 in 2015, indicating that biodegradability in the water body of the Han River was being sustained, thereby further improving water quality. The BOD/COD ratio supported these findings. The cluster analysis revealed higher annual levels of microorganisms and phosphorous at stations along the Hangang-Seoul and Hantangang areas. Nevertheless, the overall water quality over the last four years showed an observable trend toward continuous improvement. These findings also suggest that non-point pollution control strategies should consider the influence of upstreams and downstreams to protect water quality in the Han River. Conclusion: This data analysis procedure provided an efficient and comprehensive tool to interpret complex water quality data matrices. Results from a trend analysis provided much important information about sources and parameters for Han River water quality management.

울산시 상수원수에서의 오존분해 특성 및 의약물질 분해 거동 연구 (Characteristic behaviors of ozone decomposition and oxidation of pharmaceuticals during ozonation of surface waters in Ulsan)

  • 이혜진;이홍신;이창하
    • 상하수도학회지
    • /
    • 제27권1호
    • /
    • pp.39-47
    • /
    • 2013
  • This study demonstrates the oxidative degradation of pharmaceutical compounds during ozonation of surface waters in Ulsan. Diclofenac, carbamazepine, bezafibrate, and ibuprofen were selected as surrogate pharmaceutical compounds, and ozonation experiments were performed using raw waters collected from the Sayeon Dam and the Hoeya Dam in Ulsan. Diclofenac and carbamazepine which have high reactivity with molecular ozone showed higher removal efficiencies than bezafibrate and ibuprofen during ozonation. The addition of tert-butanol, a hydroxyl radical scavenger, increased the removal efficiencies of diclofenac and carbamazepine by increasing the ozone exposure. However, the oxidation of bezafibrate and ibuprofen was inhibited by the presence of tert-butanol due to the suppression of the exposure to hydroxyl radical. The elimination of the selected pharmaceuticals could be successfully predicted by the kinetic model base on the $R_{ct}$ concept. Depending on the experimental condition, $R_{ct}$ values were determined to be $(1.54{\sim}3.32){\times}10^{-7}$ and $(1.19{\sim}3.04){\times}10^{-7}$ for the Sayeon Dam and the Hoeya Dam waters, respectively. Relatively high $R_{ct}$ values indicate that the conversion of $O_3$ into $^{\cdot}OH$ is more pronounced for surface waters in Ulsan compared to other water sources.

양전하 및 음전하 필터를 이용한 해수 중 Norovirus Surrogate의 회수 (Recovery of Norovirus Surrogate in Seawater using an Electropositive and Electronegative Filter)

  • 이희정;오은경;유홍식;신순범;손명진;정진이;김영목;윤호동
    • 한국수산과학회지
    • /
    • 제42권3호
    • /
    • pp.238-242
    • /
    • 2009
  • Recently coastal seawater has been contaminated by enteric viruses such as the norovirus via untreated groundwater globally. Accordingly, the consumption of molluscan shellfish from seawater that has been contaminated with fecal material has become an important issues. The levels of enteric viruses in seawater are low and recovery and concentration of the virus from large volumes of water is difficult. We compared the effectiveness of two representative method of concentrating virus using negatively and positively charged filters. The mean retention of seeded FCV by HAMF and NCCF was 48% and 78%, respectively. Overall, the recovery of NCCF was 43.3$\pm$11% better than that of HAMF. However, the eluate obtained by using beef extract solution in the NCCF procedure caused an inhibitory effect on the RT-PCR; therefore, it was necessary to employ a PCR inhibitor removal procedure. The HAMF eluate contained no PCR inhibitors, but HAMF was not an effective method of concentrating the virus from large volumes of natural seawater due to clogging.

유류오염토양 중 다환방향족탄화수소류(PAHs) 분석방법 연구 - US EPA 16종 PAHs를 중심으로 (Analytical Method of Polycyclic Aromatic Hydrocarbons (PAHs) in Petroleum Contaminated Soils - Focused on the 16 US EPA Priority PAHs)

  • 김지영;김동호;김태승;한진석;이재영;노회정
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제17권5호
    • /
    • pp.20-30
    • /
    • 2012
  • In case of analyzing PAHs (EPA 16 compounds) in oil-contaminated soils, the lump of peaks may occur because of the aliphatic and polar compounds in oil. This phenomenon is due to the lower accuracy of the analysis. To solve this problem, evaluation of application of silicagel-alumina multi-layer fraction was performed using standard substances and oil-contaminated soils. As a result of application of silicagel-alumina multi-layer fraction cleanup method using standard substances, recovery rates of surrogate standards (5 compounds including Naphthalene-d8) were 83~100% and those of target standards were 75~129%. These were to meet the target values (60~130%) in this study. When used 4% water-silicagel column analyze PAHs in oil-contaminated soils, Some problems were generated for quantitative analysis of PAHs; concentration of PAHs was underestimated due to an upward baseline of internal standard (recovery rate: less than 60%) and overestimated by the lump of peaks which were not purified (the biggest recovery rate: more than 400%). On the other hand, in case of silicagel-alumina multi-layer fraction cleanup method, recovery rate of surrogate standards were 61~101.6%. Therefore this cleanup method was considered a valid method to improve accuracy of analysis of PAHs in oil-contaminated soils.

낙동강 원수를 대상으로 Al염계 및 Fe염계 응집제를 이용한 고도응집의 적용 (Application of Enhanced Coagulation for Nakdong River Water Using Aluminium and Ferric Salt Coagulants)

  • 문신득;손희종;염훈식;최진택;정철우
    • 대한환경공학회지
    • /
    • 제34권9호
    • /
    • pp.590-596
    • /
    • 2012
  • 고도응집 공정은 DBP 전구물질인 NOM을 제거하는 최적기법이다. 본 연구에서는 낙동강 원수를 대상으로 $FeCl_3$, alum, PSOM 및 PACl 응집제를 대상으로 고도응집 공정의 적용시 가장 효과적인 응집제와 응집조건을 DOC, THMFP, HAAFP 및 제타전위 변화를 중심으로 평가하였다. 탁도 제거율은 고도응집을 적용시 기존응집에 비해 제거율의 상승은 없었으며, 일정 응집제 주입량 이상에서는 제거율이 더욱 저하되었으나 DOC, THMFP 및 HAAFP 제거율은 응집제 종류별로 기존응집에 비해 각각 13~18%, 9~18% 및 9~18% 정도 증가하였다. 응집 pH 변화에 따른 탁도 제거특성은 $FeCl_3$와 PACl이 pH 4~10 범위에서 비교적 높은 탁도 제거율을 나타내었고 alum과 PSOM의 경우는 pH 5~8의 범위에서 안정적인 제거율을 나타내었다. DOC는 4종의 응집제 모두 pH 5~7 범위에서 안정적인 제거율을 나타내었다. 고도응집 공정을 적용시 1 kDa 이하 및 10 kDa 이상의 용존 유기물질의 제거율은 각각 11~21% 및 16% 정도 기존응집 공정에 비해 증가하였으며, 소수성 및 친수성 유기물질의 제거율은 각각 27~38% 및 11~15% 정도 증가하였다. 낙동강 원수의 고도응집에 가장 효과적인 응집제로는 $FeCl_3$로 나타났으며, 다음으로 PSOM, PACl 및 alum 순이었다.

The Emerging Role of Fast MR Techniques in Traumatic Brain Injury

  • Yoo, Roh-Eul;Choi, Seung Hong
    • Investigative Magnetic Resonance Imaging
    • /
    • 제25권2호
    • /
    • pp.76-80
    • /
    • 2021
  • Post-concussion syndrome (PCS) following mild traumatic brain injury (mTBI) is a major factor that contributes to the increased socioeconomic burden caused by TBI. Myelin loss has been implicated in the development of PCS following mTBI. Diffusion tensor imaging (DTI), a traditional imaging modality for the evaluation of axonal and myelin integrity in mTBI, has intrinsic limitations, including its lack of specificity and its time-consuming and labor-intensive post-processing analysis. More recently, various fast MR techniques based on multicomponent relaxometry (MCR), including QRAPMASTER, mcDESPOT, and MDME sequences, have been developed. These MCR-based sequences can provide myelin water fraction/myelin volume fraction, a quantitative parameter more specific to myelin, which might serve as a surrogate marker of myelin volume, in a clinically feasible time. In this review, we summarize the clinical application of the MCR-based fast MR techniques in mTBI patients.

Machine learning models for predicting the compressive strength of concrete containing nano silica

  • Garg, Aman;Aggarwal, Paratibha;Aggarwal, Yogesh;Belarbi, M.O.;Chalak, H.D.;Tounsi, Abdelouahed;Gulia, Reeta
    • Computers and Concrete
    • /
    • 제30권1호
    • /
    • pp.33-42
    • /
    • 2022
  • Experimentally predicting the compressive strength (CS) of concrete (for a mix design) is a time-consuming and laborious process. The present study aims to propose surrogate models based on Support Vector Machine (SVM) and Gaussian Process Regression (GPR) machine learning techniques, which can predict the CS of concrete containing nano-silica. Content of cement, aggregates, nano-silica and its fineness, water-binder ratio, and the days at which strength has to be predicted are the input variables. The efficiency of the models is compared in terms of Correlation Coefficient (CC), Root Mean Square Error (RMSE), Variance Account For (VAF), Nash-Sutcliffe Efficiency (NSE), and RMSE to observation's standard deviation ratio (RSR). It has been observed that the SVM outperforms GPR in predicting the CS of the concrete containing nano-silica.

A New Lichen-Forming Fungus, Aspicilia humida, from a Forested Wetland in South Korea, with a Taxonomic Key for Aspicilioid Species of Korea

  • Lee, Beeyoung Gun;Shin, Hyun Tak;Hur, Jae-Seoun
    • Mycobiology
    • /
    • 제50권1호
    • /
    • pp.20-29
    • /
    • 2022
  • Aspicilia humida Lee is described as a new lichen-forming fungus from a wetland forest, South Korea. The new species is distinguishable from Aspicilia aquatica (Fr.) Körb., the most similar species, by the absence of prothallus, black disk without green color in water, olivebrown epihymenium, shorter hymenium, hymenium I + yellowish blue-green, wider paraphysial tips without a vivid pigment, smaller asci, smaller ascospores, and the presence of stictic acid. Molecular analyses employing internal transcribed spacer (ITS) and mitochondrial small subunit (mtSSU) sequences strongly support A. humida as a distinct species in the A. cinerea group. A surrogate key is provided to assist in the identification of all 28 aspicilioid species of Korea.

Spray Characteristics on the Electrostatic Rotating Bell Applicator

  • Im, Kyoung-Su;Lai, Ming-Chia;Yoon, Suck-Ju
    • Journal of Mechanical Science and Technology
    • /
    • 제17권12호
    • /
    • pp.2053-2065
    • /
    • 2003
  • The current trend in automotive finishing industry is to use more electrostatic rotating bell (ESRB) need space to their higher transfer efficiency. The flow physics related with the transfer efficiency is strongly influenced by operating parameters. In order to improve their high transfer efficiency without compromising the coating quality, a better understanding is necessary to the ESRB application of metallic basecoat painting for the automobile exterior. This paper presents the results from experimental investigation of the ESRB spray to apply water-borne painting. The visualization, the droplet size, and velocity measurements of the spray flow were conducted under the operating conditions such as liquid flow rate, shaping airflow rate, bell rotational speed, and electrostatic voltage setting. The optical techniques used in here were a microscopic and light sheet visualization by a copper vapor laser, and a phase Doppler particle analyzer (PDPA) system. Water was used as paint surrogate for simplicity. The results show that the bell rotating speed is the most important influencing parameter for atomization processes. Liquid flow rate and shaping airflow rate significantly influence the spray structure. Based on the microscopic visualization, the atomization process occurs in ligament breakup mode, which is one of three atomization modes in rotating atomizer. In the spray transport zone, droplets tend to distribute according to size with the larger drops on the outer periphery of spray. In addition, the results of present study provide detailed information on the paint spray structure and transfer processes.

대체모형 PCK를 이용한 극한홍수 예측 (Predicting extreme flood using a surrogate PCK model)

  • 김종호;쩐옥빈
    • 한국수자원학회:학술대회논문집
    • /
    • 한국수자원학회 2021년도 학술발표회
    • /
    • pp.291-291
    • /
    • 2021
  • 모형이 갖는 불확실성의 정량화나 매개변수의 최적화는 계산시간의 기하급수적인 증가를 가져온다. 계산시간의 효율성을 극대화할 수 있는 기법으로 최근 대체모형이 개발되었으며, 다양한 분야에서 적용되고 있다. 그러나 대체모형은 훈련된 데이터 공간에서 크게 벗어난 극한 사상를 정확하게 모의하기는 어려운 단점이 있다. 본 연구는 이와 같은 대체모형의 단점을 개선할 수 있는 새로운 PCK(polynomial chaos-krigging) 기법을 제시한다. PCK는 PCE(polynomial chaos expansion) 기법과 OK(ordinary krigging) 기법을 결합한 것이며, PCK의 효과는 기존의 PCE 및 OK 모형의 결과와 비교하여 입증하였다. 본 연구의 분석 결과는 다음과 같다. (1) PCK는 더 적은 수의 훈련 샘플만으로도 원래 모형을 더 정확하게 대체할 수 있다. (2) 원래 훈련 샘플보다 약 3배 더 큰 극한사상을 모의했을 때, PCE와 OK는 예측이 실패하였지만, PCK의 예측은 정확하였다. (3) 민감도 분석 결과 PCK의 매개변수 특성과 거동이 PCE 및 OK보다 원래 모형의 특성과 거동에 더 일치한다. 본 연구에서는 3개의 대체모형의 결과를 원래모형의 결과와 비교하였으며 그 적용성을 극한강우에 대해 검토하였다. 일반적으로 훈련 샘플의 범위와 비슷한 강우사상에 대해서는 모든 대체모형의 결과가 우수하였으나, 훈련 샘플의 범위에서 벗어난 극한 사상의 모의는 PCK만 적용이 가능하였다. 제안된 대체모형은 극한사상의 예측에 있어 기존 대체모형보다 매우 향상된 정확도를 제공함을 확인할 수 있었다.

  • PDF