• 제목/요약/키워드: Water solution

검색결과 6,580건 처리시간 0.028초

A Water-Soluble Polyimide Precursor: Synthesis and Characterization of Poly(amic acid) Salt

  • Lee, Myong-Hoon;Jun Yang
    • Macromolecular Research
    • /
    • 제12권3호
    • /
    • pp.263-268
    • /
    • 2004
  • We have synthesized a water-soluble polyimide precursor, poly(amic acid) amine salt (PAD), from pyromellitic dianhydride (PMDA), 4,4'-oxydianiline, and N,N -dimethylethanolamine (DMEA) and have investigated in detail its properties with respect to the degree of salt formation (D$\_$sf/). The maximum value of D$\_$sf/ we obtained upon precipitation of the precursor solution into acetone was 79%. We synthesized a PAD having a D$\_$sf/ of 100% (PAD100) by the solid state drying of an organic solution. The precursors showed different solubility depending on the D$\_$sf/ to make up to 4 wt% solutions in water containing a small amount of DMEA. PAD100 is completely soluble in pure water. We investigated the imidization behavior of PAD in aqueous solution using various spectroscopic methods, which revealed that PAD 100 has faster imidization kinetics relative to that of the poly(amic acid)-type precursors. The resulting polyimide films prepared from an aqueous precursor solution possess almost similar physical and thermal properties as those prepared from N-methyl-2-pyrrolidone(NMP) solution. Therefore, we have demonstrated that PAD can be used as a water-based precursor of polyimide; this procedure avoids the use of toxic organic solvents, such as NMP.

순환 관계에 의한 파랑분산식의 양해 (Explicit Solution of Wave Dispersion Equation Using Recursive Relation)

  • 이창훈;장호철
    • 대한토목학회논문집
    • /
    • 제28권1B호
    • /
    • pp.111-114
    • /
    • 2008
  • 파랑의 분산관계식에서 상대수심이 반복적으로 표현되는 순환 관계를 이용하여 파랑분산식의 양해를 개발하였다. 순환 관계를 이용한 해의 초기값으로 Eckart(1951), Hunt(1979)의 해와 심해와 천해에서의 해를 사용했다. 순환해 가운데 심해에서의 해를 초기값으로 사용한 해를 제외하고는 모두 참값으로 수렴하였다. 특히, Hunt의 해를 초기값으로 사용한 해는 다른 해보다 더 빠르게 수렴했다. 순환해는 휴대용 계산기를 사용하여 손 쉽고 빠르게 구할 수 있는 장점이 있다. 선형파의 변형을 예측하기 위하여 해석 해를 사용할 경우 파랑분산식의 양해를 사용해야 하는 데 본 연구에서 개발한 순환해를 사용하면 기존의 양해를 사용한 것보다 더 정확한 해석 해를 도출할 것이다.

전기방사 조건이 셀룰로오스 웹 형상에 미치는 영향 (Parametric Study on the Morphology of Electrospun Cellulose Web)

  • 정연수;정영진
    • 한국염색가공학회지
    • /
    • 제24권1호
    • /
    • pp.62-68
    • /
    • 2012
  • Cellulose was electrospun over water collector and the cellulose solution was prepared using N-methyl-morpholine N-oxide/water(nNMMO/$H_2O$). The morphology of electrospun cellulose was investigated by scanning electron microscopy (SEM). SEM images showed that the fiber formation depended on processing parameters such as solution concentration, applied electric field strength, solution feeding rate and temperature of water in coagulation bath. High concentration, low temperature of water bath, and low feeding rate were more favorable to obtain fiber morphology. All the variables affected on the fluidity of the cellulose solution and diffusion of NMMO. Low fluidity and fast diffuision of NMMO was critical for obtaining fiber morphology.

Effect of Coating Methods on the Properties of Poly(lactide)-coated Paperboard: Solution Coating vs. Thermo-compression Coating

  • Rhim, Jong-Whan
    • Food Science and Biotechnology
    • /
    • 제18권5호
    • /
    • pp.1155-1160
    • /
    • 2009
  • Poly(lactide) (PLA)-coated paperboards were prepared by solution coating and thermo-compression coating methods and their effect of coating on the packaging properties such as tensile, water resistance, water vapor barrier, and heat sealing properties was tested. Compared with uncoated control paperboard, tensile strength (TS) of PLA-coated paperboard increased profoundly (2.2-2.6 folds) with slight increase in elongation at break (E). Water absorptiveness (WA) of the paperboard decreased 74-170 folds and water vapor permeability (WVP) decreased 6.3-22.1 folds by coating with PLA, which indicates an increase in the hydrophobicity of the surface of paperboard. Compared with polyethylene (PE)-coated paperboard, both PLA-coated paperboard exhibited 2.3 time higher heat sealing strength. In addition, the PLA-coated paperboards showed equal or higher wet TS than PE-coated paperboard. All the test results showed that the paperboard coated by the thermo-compression coating method was similar to or better than those of coated by the solution coating method.

계면활성제 첨가수용액의 제빙에 관한 기초연구 (Study on Ice Making Behavior of Water Solution with Surfactant)

  • 박기원
    • 설비공학논문집
    • /
    • 제13권12호
    • /
    • pp.1175-1183
    • /
    • 2001
  • Recently, a great attention has been paid to the ice thermal storage system for the purpose of energy saving and reduction in peak electrical demand. In the present study, it has been investigated the freezing behavior of several kinds of water solutions with nonionic surfactant. In order to prevent ice blockage in a cooled pipe, the amount and wall adhesion behavior of ice of the test fluids were observed experimentally under different concentration of water solution with surfactant, temperature of cooled wall, and the shear velocity of test fluids. The results showed that the size of ice crystal became smaller at higher shear velocity at wall. And the lowest limit of wall adhesion of ice in water solution with surfactant was found at 230 W/$m^2$ of heat flux.

  • PDF

단효용 LiBr/물 흡수식 냉동사이클의 성능특성에 관한 연구 (A Study on Performance Characteristics of A Single Effect LiBr/Water Refrigeration Cycle)

  • 연제문;임삼택;오주원;이경우
    • 한국마린엔지니어링학회:학술대회논문집
    • /
    • 한국마린엔지니어링학회 2001년도 춘계학술대회 논문집
    • /
    • pp.95-99
    • /
    • 2001
  • As a way to use energy effectively, the present study is aimed at investigating the performance characteristics of a Single Effect LiBr/Water Absorption Refrigerator using a low temperature driving heat-source. It was carried out by changing the driving heat-source temperature, the cold water outlet temperature(the refrigeration load), the cooling water inlet temperature, and the weak solution flow rate and this study compares the performance characteristics of refrigerator against the existence and non-existence of the Recirculation of the Weak solution which is used as a method to improve the performance of refrigerator. In case of Recirculation of the weak solution, more improved the Refrigeration Capacity and COP was obtained, and these effects became more larger in the high temperature of driving heat-source and large quantity of solution.

  • PDF

흰쥐의 적출소장을 통한 물의 흡수에 관한 연구 (The Absorption of Water from the Isolated Small Intestine of the Rat)

  • 김종국;이범진
    • 약학회지
    • /
    • 제32권3호
    • /
    • pp.194-197
    • /
    • 1988
  • We measured the rate of water transfer across the isolated small intestine of the rat in Wiseman apparatus using tritiated water ($^3H_2O$) in drinking beverages such as electrolytes solution, fruit juice, carbonated water and barley water. Initial transfer rate of water using four beverages were determined: Electrolytes solution is the fastest and followed by barley water, carbonated water and fruit juice.

  • PDF

Effects of Waste Nutrient Solution on Growth of Chinese Cabbage (Brassica campestris L.) in Korea

  • Choi, Bong-Su;Lee, Sang-Soo;Ok, Yong-Sik
    • 한국환경농학회지
    • /
    • 제30권2호
    • /
    • pp.125-131
    • /
    • 2011
  • BACKGROUND: Reuse of waste nutrient solution for the cultivation of crops could lead to considerable conservation of water resources, plant nutrients, and water quality. Therefore, this study was conducted to evaluate the potential for reducing the use of chemical fertilizer in Chinese cabbage cultivation via the reuse of waste nutrient solution as an alternative irrigation resource. METHODS AND RESULTS: The nutrients supplied in the waste nutrient solution consisted of 1474.5, 1285.1, 991.6, and 872.6 mg/L for $K+$, ${NO_3}^-$, $Ca^{2+}$ and ${SO_4}^{2-}$, respectively. At 56 days after transplanting (DAT), the leaf length of Chinese cabbage plants irrigated with the waste nutrient solution treatment was significantly higher than that of plants irrigated using a conventional groundwater treatment. Additionally, the leaf width, fresh weight and dry weight of the plants irrigated with the waste nutrient solution were similar or greater than that of plants irrigated with a conventional treatment. Furthermore, the growth of plants treated with the waste nutrient solution +25% fertilizer was the highest among all tested treatments. CONCLUSION(s): These results indicate that the waste nutrient solution can be used as an alternate water resource for crop cultivation. In addition, it can contribute to reduce the fertilizer and to obtain the higher crop yield of Chinese cabbage.

방식도막에 있어서 물의 침투에 대한 전해질 용액의 영향 (Effect of Electrolyte Concentration on Water Permeation in Protective Coatings)

  • 박진환
    • 한국안전학회지
    • /
    • 제13권4호
    • /
    • pp.206-212
    • /
    • 1998
  • The water permeation in protective coatings, which may greatly influence the corrosion protective property of these coatings, was studied using the electrochemical impedance spectroscopy technique. During the absorption of water in protective coatings immersed in electrolyte solution, the change of coating capacitance with concentration of electrolyte was determined from impedance measurements. When water absorption or desorption of coatings occured by exposing the coatings to electrolyte solutions of different concentration, increase in impedance caused by desorption of water was found to be higher in the case of thicker film. The amount of water absorbed in coatings changed with concentration of electrolyte. The water taken up in coatings from the solution of lower electrolyte concentration was deserted by contact with the solution of higher concentration. The uptake of water in protective coatings varied depending on the type of coating ingredient especially binder.

  • PDF

나노사이즈 불화탄소수지 용액 농도에 따른 GDL 발수 코팅 (Water Repellent Coating of GDL with Different Concentration of Nano-sized PTFE Solution)

  • 정문국;송기세;조태환;최원경
    • 한국수소및신에너지학회논문집
    • /
    • 제20권4호
    • /
    • pp.323-330
    • /
    • 2009
  • Efficiency of a fuel cell is determined by the generated water. If water is not removed sufficiently, water will be accumulated at GDL, which causes flooding. Therefore, water control is regarded as a crucial factor to sustain fuel ell performance. In this study, PTFE coating on the surface of carbon paper was carried out to establish optimum process for hydrophobic treatment of GDL. Carbon paper was immersed at different concentrations of nano-sized PTFE coating solution. Their characteristics were analyzed systematically by FE-SEM, water contact angle, cyclic voltamogam, XRD and FT-IR. The quantitative correlation between the amount of coated-PTFE on a carbon paper and concentration of coating solution was carefully investigated. It is suggested that the amount of PTFE-coating on a carbon paper can be managed by means of controling concentration of coating solution.